Visible-light driven excellent photocatalytic degradation of ofloxacin antibiotic using BiFeO3 nanoparticles.

The extensive exploration of multiferroic materials for degradation of contaminants and environmental remediation is promptly strengthened because of their distinct applications. BiFeO3, a prominent class of multiferroics, have received immense attention in recent times. Present study reports the synthesis of a highly crystalline BiFeO3 via facile combustion method. The prepared catalyst was characterized using different techniques like XRD, FTIR, FESEM, EDS, XPS, DRS and PL. From DRS results, the energy band gap of BiFeO3 was computed as 2.1 eV which was suitable enough for its exploration as a visible light photocatalyst. Therefore, BiFeO3 was efficiently utilized for the degradation of ofloxacin drug under the exposure of visible light. The obtained results depicted 80% ofloxacin degradation under optimized conditions (pH 8, 0.5 g/L catalyst dose and 10 mg/L drug concentration) in 180 min. Pseudo first order kinetics was followed with rate constant 0.0097 min-1, as inferred from the kinetic studies. Furthermore, 64% TOC reduction was attained by utilizing the prepared catalyst under optimum conditions. Additionally, the photocatalytic experiments showed excellent degradation efficiency even after five cycles which demonstrated good stability of the fabricated catalyst.

Production and characterization of anthocyanin-rich beer from black wheat by an efficient isolate Saccharomyces cerevisiae CMS12.

Beer is the world's third most popular fermented beverage. It is typically made from malted barley. Tropical countries must import barley from temperate countries for brewing, which is an expensive process. Therefore, it is critical to investigate alternative possible substrates for beer production in order to meet the growing demand for high-nutritional-quality beer. The current study involves the creation of a fermented beverage from anthocyanin-rich black wheat with the help of yeast, Saccharomyces cerevisiae CMS12, isolated from fruit waste. Characterization (UV, HPLC, NMR, FTIR, and ICPMS) was then performed, as well as a comparative study with white (amber) wheat beer. Further, process parameters optimization included initial sugar concentration, inoculum size, and pH. Black wheat wort contained 568 mg GAE/L total phenolic content, 4.67 mg/L anthocyanin concentration, 6.8% (v/v) alcohol content, and a pH of 4.04. The sensory analysis revealed that black wheat beer was more acceptable than white wheat beer. The developed fermented beverage has enormous commercialization potential.

Potential cocoa butter substitute derived from mango seed kernel.

The present finding provides a new cocoa butter substitute in confectionary, which is derived from mango by-product (mango seed kernel). The study involves physicochemical characterization and the use of GCMS, FTIR, SEM, TGA, and NMR to prove that mango seed kernel derived fat is a good substitute for cocoa butter. Its texture, organoleptic properties and rancidity were also investigated. Its properties were similar to cocoa butter, with respect to palmitic, oleic, and stearic acids, and it had the ability to substitute 80 per cent of dark chocolate preparation for chocolate substitute. This recently developed cocoa substitute has the potential to address the global problem of cocoa butter scarcity, which is being exacerbated by rising population and improving economies.

The role of particulate matter in reduced visibility and anionic composition of winter fog: a case study for Amritsar city.

Severe fog events during winter months in India are a serious concern due to the higher incidence of road accidents, flight delays and increased occurrence of respiratory diseases. The present paper is an attempt to study the twenty fog samples collected from the rooftop of an academic building of Guru Nanak Dev University, Amritsar, India from November 2017 to January 2018. Fog samples were analysed for various parameters viz. pH, electrical conductivity (EC), chloride (Cl-), nitrate (NO3 -) and sulphate (SO4 2-) levels. The pH, EC, and Cl-, NO3 - and SO4 2- levels in the fog samples were estimated as 6.3-7.9, 240-790 µS cm-1, 108-2025 µeq L-1, 105-836 µeq L-1 and 822-5642 µeq L-1, respectively. It was noticed that sulphate was the dominant anion in fog samples. The SO4 2- to NO3 - molar ratio in the fog was estimated as 7.6 which suggests the burning of fossil fuel as the major pollutant from vehicular exhausts. Multiple regression analysis was performed to evaluate the effect of PM2.5/PM10 ratio and relative humidity (RH) on visibility. A box-cox plot of power transformation produced better model fitting, employing a square root transformation of the visibility which indicated that the PM2.5/PM10 and RH have an exponential effect on visibility.

Improved levulinic acid production from agri-residue biomass in biphasic solvent system through synergistic catalytic effect of acid and products.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.