A Precise and Stable Space-Based Time System for Navigation in Smart Cities.

The high-accuracy and high-stability space-based time system is necessary for satellite navigation systems to achieve high quality of service (QoS) on navigation and positioning in smart city applications. This paper proposes a precise and high-stability space-based time system established under the autonomous time scale of navigation satellites. The generation, maintenance, and transfer of high-precision space-based time references are researched. A centralized time comparison method based on the ALGOS algorithm conducts the two-way time comparison of the inter-satellite link. Specifically, using the relative clock difference observations of all links between satellites for a certain period of time, the clock difference, clock speed, and clock drift parameters of n-1 stars in a constellation of n stars relative to the same reference can be estimated simultaneously. Simulations are conducted on real collected data from the Beidou navigation systems when providing services to smart cities around the world. The simulation results show the high accuracy and stability of the proposed space-based time system under the autonomous time scale reference. Moreover, the clock offset monitoring arc coverage is much higher than the satellite clock offset obtained by the direct observation of the satellite and the anchor station. It proves the efficiency of the proposed space-based time system to be used for satellite clock offset modeling and prediction.

The Importance of Nonequilibrium to Equilibrium Transition Pathways for the Efficiency and Stability of Organic Solar Cells.

Controlled morphology of solution-processed thin films have realized impressive achievements for non-fullerene acceptor (NFA)-based organic solar cells (OSCs). Given the large set of donor-acceptor pairs, employing various processing conditions to realize optimal morphology for high efficiency and stable OSCs is a strenuous task. Therefore, comprehensive correlations between processing conditions and morphology evolution pathways have to be developed for efficient performance and stability of devices. Within the framework of the blend system, crystallization transitions of NFA molecules are tracked utilizing the first heating scan of differential scanning calorimeter (DSC) measurement correlating with respective morphology evolution of blend films. Real-time dynamics measurements and morphology characterizations are combined to provide optimal morphology transition pathways as NFA molecules are shown to be released from the mixed-phase to form balanced ordered packing with variant processing conditions. Polymer:NFA films are fabricated using blade coating incorporating solvent additive or thermal annealing as processing conditions as a correlation is formulated between performance and stability of solar cells with morphology transition pathways. This work demonstrates the significance of processing condition-controlled transition pathways for the realization of optimal morphology leading to superior OSC devices.

The Design and Maintenance of Low-Orbit Navigation Constellation for Traffic Control in a Smart City.

The traffic control issue in the smart city scenario gives rise to the higher requirements of Global Navigation Satellite System (GNSS) services, especially in terms of navigation accuracy, together with coverage continuity, and multiplicity. The dense urban environment leads to higher elevation angles for navigation in such areas, which requires a lower altitude of the constellation, as well as a larger number of satellites. In the existing literature, the design and maintenance of the Low Earth Orbit (LEO) navigation constellation that fulfills the requirements of the smart city are not provided. Hence, based on the requirements and constraints of the smart city scenario, this article studies the relation between orbital height, user elevation angle, and coverage. It designs the configuration of an LEO navigation constellation that not only achieves global sensing coverage, but also provides a continuous lane-level navigation service with multiple coverages for the key area. In addition, considering the atmospheric drag in low orbits and the constraint of satellite power and attitude control, a method is proposed by rotating solar panels to change the effective frontal area of the satellite to achieve relative configuration maintenance of the LEO constellation. The results show that the LEO navigation constellation has a 0 s revisit time in five chosen smart cities, and each city has more than four-times coverage every second; the Geographic Dilution of Precision (GDOP) values of five cities are smaller than 0.47. The average navigation accuracy of five cities is 2.01. With the conduction of the one-year station-keeping simulation, the phase deviation of two satellites is less than 0.6° and it gradually converges to 0.1°, where the semi-major axis deviation is less than 80 m. With our proposed method, the active station-keeping control is not needed in one year, and the fuel consumption can be reduced. Finally, the continuity of the navigation service can be assured.

Research on the Coordinate Attention Mechanism Fuse in a YOLOv5 Deep Learning Detector for the SAR Ship Detection Task.

The real-time performance of ship detection is an important index in the marine remote sensing detection task. Due to the computing resources on the satellite being limited by the solar array size and the radiation-resistant electronic components, information extraction tasks are usually implemented after the image is transmitted to the ground. However, in recent years, the one-stage based target detector such as the You Only Look Once Version 5 (YOLOv5) deep learning framework shows powerful performance while being lightweight, and it provides an implementation scheme for on-orbit reasoning to shorten the time delay of ship detention. Optimizing the lightweight model has important research significance for SAR image onboard processing. In this paper, we studied the fusion problem of two lightweight models which are the Coordinate Attention (CA) mechanism module and the YOLOv5 detector. We propose a novel lightweight end-to-end object detection framework fused with a CA module in the backbone of a suitable position: YOLO Coordinate Attention SAR Ship (YOLO-CASS), for the SAR ship target detection task. The experimental results on the SSDD synthetic aperture radar (SAR) remote sensing imagery indicate that our method shows significant gains in both efficiency and performance, and it has the potential to be developed into onboard processing in the SAR satellite platform. The techniques we explored provide a solution to improve the performance of the lightweight deep learning-based object detection framework.

Intermolecular Interaction Control Enables Co-optimization of Efficiency, Deformability, Mechanical and Thermal Stability of Stretchable Organic Solar Cells.

Promoting efficiency, deformability, and life expectancy of stretchable organic solar cells (OSCs) have always been key concerns that researchers are committed to solving. However, how to improve them simultaneously remains challenging, as morphology parameters, such as ordered molecular arrangement, beneficial for highly efficient devices actually limits mechanical stability and deformability. In this study, the unfavorable trade-off among these properties has been reconciled in an all-polymer model system utilizing a mechanically deformable guest component. The success of this strategy stems from introducing a highly ductile component without compromising the pristine optimized morphology. Preferable interaction between two donors can maintain the fiber-like structure while enhancing the photocurrent to improve efficiency. Morphology evolution detected via grazing incidence X-ray scattering and in situ UV-vis absorption spectra during stretching have verified the critical role of strengthened interaction on stabilizing morphology against external forces. The strengthened interaction also benefits thermal stability, enabling the ternary films with small efficiency degradation after heating 1500 h under 80 °C. This work highlights the effect of morphology evolution on mechanical stability and provides new insights from the view of intermolecular interaction to fabricate highly efficient, stable, and stretchable/wearable OSCs.

Case study on synergistic development strategy of cross-border e-commerce and logistics: An empirically model estimation.

This study investigates the dynamic relationship between cross-border e-commerce and logistics co-development strategies within the context of small and medium-sized enterprises (SMEs) in China. The primary objective is to formulate an empirical model capable of estimating the utility and flexibility of cross-border e-commerce logistics, specifically focusing on its role in achieving competitive advantage for SMEs. The research employs a comprehensive approach, considering various factors that influence the formulation and implementation of cross-border e-commerce logistics strategies. Factors such as scale, quality, potential, and infrastructure are scrutinized to provide a nuanced understanding of the dynamic interplay. Real-world data is analyzed using advanced statistical techniques to derive meaningful insights. The data of CBEC and logistics planning in Guangdong from 2013 to 2018 was used as a case example to demonstrate its and flexibility and usefulness of empirically proposed model estimation and develop a holistic indicator system for the evaluation of the synergistic development of CBEC and logistics. This research focus on the modelling of the CBEC for the synergistic effect analysis and evaluate the usefulness and flexibility of CBEC to achieve competitive advantage. The study aims to uncover insights into the most effective approaches for Chinese SMEs in navigating the landscape of cross-border e-commerce. By examining the results derived from the empirical model, the research sheds light on the impact of cross-border e-commerce logistics on competitive advantage. The findings contribute to a deeper understanding of how SMEs can strategically position themselves in the cross-border e-commerce arena. Through the analysis of real-world data and the application of advanced statistical methods, this research offers valuable insights for Chinese SMEs. The insights generated from the study not only illuminate the intricacies of cross-border e-commerce logistics but also provide practical recommendations to reduce associated costs. Ultimately, the study aims to equip SMEs with the knowledge necessary to thrive in the evolving landscape of cross-border e-commerce.

Kinetics Manipulation Enables High-Performance Thick Ternary Organic Solar Cells via R2R-Compatible Slot-Die Coating.

Power conversion efficiency (PCE) of organic solar cells (OSCs) has crossed the 18% mark for OSCs, which are largely fabricated by spin-coating, and the optimal photoactive thickness is limited to 100 nm. To increase reproducibility of results with industrial roll-to-roll (R2R) processing, slot-die coating coupled with a ternary strategy for optimal performance of large-area, thick OSCs is used. Based on miscibility differences, a highly crystalline molecule, BTR-Cl, is incorporated, and the phase-separation kinetics of the D18:Y6 film is regulated. BTR-Cl provides an early liquid-liquid phase separation and early aggregation of Y6, which slightly improves the molecular crystallinity and vertical phase separation of the ternary blends, resulting in high PCEs of 17.2% and 15.5% for photoactive films with thicknesses of 110 and 300 nm, respectively. The ternary design strategy for large-area and thick films is further used to fabricate high-efficiency flexible devices, which promises reproducibility of the lab results from slot-die coating to industrial R2R manufacturing.

Nonhalogenated Dual-Slot-Die Processing Enables High-Efficiency Organic Solar Cells.

Organic solar cells (OSCs) are promising candidates for next-generation photovoltaic technologies, with their power conversion efficiencies (PCEs) reaching 19%. However, the typically used spin-coating method, toxic halogenated processing solvents, and the conventional bulk-heterojunction (BHJ), which causes excessive charge recombination, hamper the commercialization and further efficiency promotion of OSCs. Here, a simple but effective dual-slot-die sequential processing (DSDS) strategy is proposed to address the above issues by achieving a continuous solution supply, avoiding the solubility limit of the nonhalogen solvents, and creating a graded-BHJ morphology. As a result, an excellent PCE of 17.07% is obtained with the device processed with o-xylene in an open-air environment with no post-treatment required, while a PCE of over 14% is preserved in a wide range of active-layer thickness. The unique film-formation mechanism is further identified during the DSDS processing, which suggests the formation of the graded-BHJ morphology by the mutual diffusion between the donor and acceptor and the subsequent progressive aggregation. The graded-BHJ structure leads to improved charge transport, inhibited charge recombination, and thus an excellent PCE. Therefore, the newly developed DSDS approach can effectively contribute to the realm of high-efficiency and eco-friendly OSCs, which can also possibly be generalized to other organic photoelectric devices.

Different Morphology Dependence for Efficient Indoor Organic Photovoltaics: The Role of the Leakage Current and Recombination Losses.

Efficient indoor organic photovoltaics (OPVs) have attracted strong attention for their application in indoor electronic devices. However, the route to optimal photoactive film morphology toward high-performance indoor devices has remained obscure. The leakage current dominated by morphology exerts distinguishing influence on the performance under different illuminations. We have demonstrated that morphology reoptimization plays an important role in indoor OPVs, and their optimal structural features are different from what we laid out for outdoor devices. For indoor OPVs, in order to facilitate low leakage current, it is essential to enhance the crystallinity, phase separation, and domain purity, as well as keeping small surface roughness of the active layer. Furthermore, considering the reduced bimolecular recombination at low light intensity, we have shown that PM6:M36-based indoor devices can work effectively with a large ratio of the donor and acceptor. Our work correlating structure-performance relation and the route to optimal morphology outlines the control over device leakage current and recombination losses boosting the progress of efficient indoor OPVs.

Significance of Dopant/Component Miscibility to Efficient N-Doping in Polymer Solar Cells.

The uncertain dopant location in the bulk heterojunction (BHJ) film hinders the wide application of molecular doping in polymer solar cells (PSCs) as is in other organic devices. It is known that the interaction between the dopant and component governs the dopant distribution in the BHJ film and thus largely controls the effectiveness of molecular doping. After excluding the strong dopant/component interaction by forming the charge-transfer complex in the solution, we estimate the dopant/component miscibility by calculating the difference of Hansen's total solubility parameters (△δi-Hansen) and prove its correctness by contact angle measurements, and two model systems of poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophe-2-yl)-benzo[1,2-b:4,5-b']dithiophene))-alt-(5,5-(1',3'-di-2-thienyl-5',7'-bis(2-ethylhexyl)benzo[1',2'-c:4',5'-c']dithiophene-4,8-dione))] (PBDB-T)/poly{[N,N'-bis(2-octyldodecyl)-naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)} (N2200) and poly[4,8-bis(5-(2-ethylhexyl)-thiophene-2-yl)benzo[1,2-b;4,5-b']dithiophene-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene-)-2-carboxylate-2-6-diyl]] (PCE10)/N2200 are selected to reveal the miscibility-photovoltaic performance relations. Only the material combination with large △δi-Hansen between the n-dopant (4-(1,3-dimethyl-2,3-dihydro-1H-benzoimidazol-2-yl)phenyl)dimethylamine (N-DMBI) and the donor polymer achieves enhanced photovoltaic performance. After that, we examine the doped morphology of polymer blends. Since the polymers' crystallizations are negatively affected by N-DMBI addition, we ensure the significance of n-doping on the enhanced device performance. Besides the dopant/polymer interaction, the solvent/polymer and solvent/dopant interactions are also considered to evaluate the kinetic effect on N-DMBI distribution by drawing the ternary phase diagram. We conclude that the kinetic morphological evolution does not change the miscibility-governed N-DMBI distribution in the BHJ film. Finally, we provide a direct relationship between the N-DMBI position and the device property by fabricating the bilayer devices. The enhancement of photovoltaic performances is observed in both material systems only if the N-DMBI distributes in N2200. Our work outlines a basis for using the dopant/component interaction and ternary phase diagram to predict the dopant distribution before extensive experiments. It significantly reduces the trial-and-error work and increases the reliability of molecularly doped PSCs.

Probe and Control of the Tiny Amounts of Dopants in BHJ Film Enable Higher Performance of Polymer Solar Cells.

To achieve efficient doping in polymer solar cells (PSCs), the dopant needs to be selectively located in the binary components of a bulk heterojunction (BHJ) film according to its polarity. The rarely studied n-type dopant is thoroughly examined in a simplified planar heterojunction (PHJ) device to address its favored location in the active layer. Results show that the n-dopant distribution in the acceptor layer or at the donor/acceptor interface produces enhanced device performance, whereas it harms the device when located in the donor layer. Based on the results, the benefit of n-type doping is then transferred to the highly efficient BHJ devices via a sequential coating procedure. The performance improvement is closely linked to the variations in the dopant's location in the BHJ film, which is carefully examined by the synchrotron techniques with delicate chemical sensitivity. More interestingly, the sequential coating procedure can be easily extended to the p-doped device only by changing the dopant's polarity in the middle layer. These findings pave the way for ambipolar doping in PSCs and enable performance improvement by molecular doping within the expectations.

Organic photovoltaic cell with 17% efficiency and superior processability.

The development of organic photoactive materials, especially the newly emerging non-fullerene electron acceptors (NFAs), has enabled rapid progress in organic photovoltaic (OPV) cells in recent years. Although the power conversion efficiencies (PCEs) of the top-performance OPV cells have surpassed 16%, the devices are usually fabricated via a spin-coating method and are not suitable for large-area production. Here, we demonstrate that the fine-modification of the flexible side chains of NFAs can yield 17% PCE for OPV cells. More crucially, as the optimal NFA has a suitable solubility and thus a desirable morphology, the high efficiencies of spin-coated devices can be maintained when using scalable blade-coating processing technology. Our results suggest that optimization of the chemical structures of the OPV materials can improve device performance. This has great significance in larger-area production technologies that provide important scientific insights for the commercialization of OPV cells.

Hot Hydrocarbon-Solvent Slot-Die Coating Enables High-Efficiency Organic Solar Cells with Temperature-Dependent Aggregation Behavior.

Organic solar cells (OSCs) have made rapid progress in terms of their development as a sustainable energy source. However, record-breaking devices have not shown compatibility with large-scale production via solution processing in particular due to the use of halogenated environment-threatening solvents. Here, slot-die fabrication with processing involving hydrocarbon-based solvents is used to realize highly efficient and environmentally friendly OSCs. Highly compatible slot-die coating with roll-to-roll processing using halogenated (chlorobenzene (CB)) and hydrocarbon solvents (1,2,4-trimethylbenzene (TMB) and ortho-xylene (o-XY)) is used to fabricate photoactive films. Controlled solution and substrate temperatures enable similar aggregation states in the solution and similar kinetics processes during film formation. The optimized blend film nanostructures for different solvents in the highly efficient PM6:Y6 blend is adopted to show a similar morphology, which results in device efficiencies of 15.2%, 15.4%, and 15.6% for CB, TMB, and o-XY solvents. This approach is successfully extended to other donor-acceptor combinations to demonstrate the excellent universality of this method. The results combine a method to optimize the aggregation state and film formation kinetics with the fabrication of OSCs with environmentally friendly solvents by slot-die coating, which is a critical finding for the future development of OSCs in terms of their scalable production and high-performance.

Efficient and thermally stable organic solar cells based on small molecule donor and polymer acceptor.

Efficient organic solar cells (OSCs) often use combination of polymer donor and small molecule acceptor. Herein we demonstrate efficient and thermally stable OSCs with combination of small molecule donor and polymer acceptor, which is expected to expand the research field of OSCs. Typical small molecule donors show strong intermolecular interactions and high crystallinity, and consequently do not match polymer acceptors because of large-size phase separation. We develop a small molecule donor with suppressed π-π stacking between molecular backbones by introducing large steric hindrance. As the result, the OSC exhibits small-size phase separation in the active layer and shows a power conversion efficiency of 8.0%. Moreover, this OSC exhibits much improved thermal stability, i.e. maintaining 89% of its initial efficiency after thermal annealing the active layer at 180 °C for 7 days. These results indicate a different kind of efficient and stable OSCs.

Processing-Friendly Slot-Die-Cast Nonfullerene Organic Solar Cells with Optimized Morphology.

The power conversion efficiencies (PCEs) of spin-coated organic solar cells (OSCs) have increased rapidly in recent years. However, spin-coating shows poor reproducibility for large-scale production. Slot-die coating, a lab-scale version of roll-to-roll fabrication, has been considered as the most suitable technique for the production of future large-area commercial devices. For this, the highly efficient slot-die-fabricated devices are required to approach the performance of spin-cast OSCs. We present here, a nonfullerene OSC device utilizing the PBDB-T/i-IEICO-4F blend, fabricated by slot-die coating without post-treatment in the ambient conditions. The device showed an impressive PCE of 12.5%, which is one of the highest reported performance for slot-die-coated OSC devices. Compared to the spin-coated and blade-coated films with optimized thermal annealing time, the films fabricated by slot-die coating (without any treatment) exhibit not only the highest degree of crystallinity and face-on orientation but also the smallest domain size and the purest phase toward enhanced and balanced carrier mobilities. An enhanced excited-state charge generation has been attributed to transient charge kinetics using ultrafast spectroscopic signatures. The optimized slot-die-coated devices exhibit excellent tolerance for the increased thickness of the photoactive layer, attributing to favorable molecular packing. We used slot-die coating as a simple fabrication technique, which is capable of yielding highly efficient OSCs.

Blade-Cast Nonfullerene Organic Solar Cells in Air with Excellent Morphology, Efficiency, and Stability.

Blade-coating serving as a prototype tool for slot-die coating can be very compatible with large-area roll-to-roll coating. Using blade-coating in an ambient environment, an average power conversion efficiency (PCE) of 10.03% is achieved in nonfullerene organic solar cells, which is higher than that of the optimal spin-coated device with a PCE of 9.41%. It is demonstrated that blade-coating can induce a higher degree of molecular packing for both conjugated polymer donors and small-molecular acceptors as it helps to produce a seeding film containing numerous crystal grains, subsequently providing nucleation sites for the residual solution when the motion of the blade exposes a liquid front. Due to this effect, blade-coating can partially replace the role of the additive 1,8-diiodooctane (DIO) and thus achieves the optimized morphology with fewer additives. Moreover, it is found that the blade-coated film with 0.25% DIO possesses not only a smaller domain size but also higher domain purity, suggesting more D/A (donor/acceptor) interfaces and a purer phase domain as compared to the spin-coated film with 1% DIO. Encouragingly, the blade-coated device with less DIO (0.25%) exhibits much better stability than the spin-coated device with 1% DIO, showing excellent prospects.

Achieving Balanced Crystallinity of Donor and Acceptor by Combining Blade-Coating and Ternary Strategies in Organic Solar Cells.

As a prototype tool for slot-die coating, blade-coating exhibits excellent compatibility with large-area roll-to-roll coating. A ternary organic solar cell based on PBDB-T:PTB7-Th:FOIC blends is fabricated by blade-coating and exhibits a power conversion efficiency of 12.02%, which is one of the highest values for the printed organic solar cells in ambient environment. It is demonstrated that blade-coating can enhance crystallization of these three materials, but the degree of induction is different (FOIC > PBDB-T > PTB7-Th). Thus, the blade-coated PBDB-T:FOIC device presents much higher electron mobility than hole mobility due to the very high crystallinity of FOIC. Upon the addition of PTB7-Th into the blade-coated PBDB-T:FOIC blends, the crystallinity of FOIC decreases together with the corresponding electron mobility, due to the better miscibility between PTB7-Th and FOIC. The ternary strategy not only maintains the well-matched crystallinity and mobilities, but also increases the photocurrent with complementary light absorption as well as the Förster resonant energy transfer. Furthermore, small domains with homogeneously distributed nanofibers are observed in favor of the exciton dissociation and charge transport. This combination of blade-coating and ternary strategies exhibits excellent synergistic effect in optimizing morphology, showing great potential in the large-area fabrication of highly efficient organic solar cells.