Soil covering measure mitigates vanadium loss during short-term simulated rainfall in the vanadium titano-magnetite tailings reservoir.

Soil covering is an operative measure to decline pollutant release in tailings reservoirs and promote vegetation restoration, yet urgent research still needs to probe into pollutant leaching and migration in the artifact technology under extreme precipitation. Here, a soil column leaching experiment was designed to explore the migration and behaviors of vanadium (V) in the system of vanadium titano-magnetite tailings (VTMTs) covered by soils with different depths (5 cm, 10 cm, and 15 cm). Chemical fractions of V in the VTMTs and covered soils were analyzed to decipher the mechanisms underlying the V migration. We found a limited V leaching (0.26-0.52 µg/L, <0.01% of total V) in the columns during the experiments, and V in the VTMTs was not apt to be leached or migrate upward to the overlying soils. The soil volumes overlaid had nonsignificant effect on the V behaviors in the VTMTs (P > 0.05), because of the dominant and stable residual V (96.4% of total V) in the tailings. Although acid soluble V might be transformed to oxidizable V, it was resupplied by the fractions of weak-bound V in the solid phases during the leaching experiments. The mineral metal (hydr)oxides (e.g., aluminum, iron) determined the V behaviors in the VTMTs via absorption effect, and the high affinity of V to organic matters probably prevented its migration throughout the overlying soils. The results indicate that soil covering measure in the VTMTs reservoirs effectively reduces V migration or release from the tailings through leaching or upward migration, which provides a significant guidance for vegetation restoration in V-rich tailings reservoirs.

Effect of different industrial activities on soil heavy metal pollution, ecological risk, and health risk.

Soil heavy metal (Cr, Cu, Zn, Pb, Cd, V, As) concentrations in different areas were analyzed to investigate the effects of different industrial activities on heavy metal pollution status, potential ecological risk, and human health risk in Panzhihua. Our results showed that Cu and V enrichment in soil was due to ore smelting. Soil Cr accumulation was related to coal ore mining. Soil Cd, Zn, As, and Pb enrichment was attributed to high-temperature coal combustion. Under the effect of industrial activities, soils were moderately contaminated with Cd, uncontaminated to moderately contaminated with As and Zn, and uncontaminated with Cr, Cu, V, and Pb. Soil heavy metal potential ecological risk was considerable, and non-carcinogenic risks and carcinogenic risks of soil heavy metals were acceptable for adults but unacceptable for children. Thermal power generation was the dominated industrial activity that influence the soil heavy metal concentrations and environmental risks in Panzhihua, which posed considerable potential ecological risks and unacceptable heavy metal non-carcinogenic risks and As carcinogenic risk to both adults and children. This study indicates that industrial activities have great effects on heavy metal pollution, ecological risks, and health risk, and more attention should be paid to the ecological risk and health risks brought by thermal power generation.

Characteristics, Sources and Health Risk Assessment of Trace Metals in PM10 in Panzhihua, China.

Ambient PM10 air samples were collected at two industrial sites and one urban residential site in the mining city of Panzhihua, China, from April, 2014, to January, 2015. Mass concentrations of ten trace metals (As, Cd, Cr, Ni, Co, V, Mn, Cu, Pb, and Zn) in PM10 were determined by inductively coupled plasma-mass spectrometry. The results showed Zn, Pb, Cu, Mn and V were the most abundant elements from the industrial sites. Concentrations for Cd, Cr, Co, Ni, Mn and Cu at industrial sites greatly exceeded the air quality standards of the World Health Organization and the Chinese Ministry of Environmental Protection. Principal component analysis indicated that the main sources of the trace metals were steel smelting, fuel combustion, geological and mineral dust. Four different clusters of particles (i.e., mineral, calcium-containing, soot and aluminosilicate) were identified by scanning electron microscopy coupled with energy dispersive X-ray spectrometry. Chromium (Cr) was found to present the highest excess cancer risk, implying the potential for carcinogenic health effects in local inhabitants. Manganese (Mn) presented a non-carcinogenic health risk to children and adults, while the other metals were within acceptable limits.

Environmental protection measures mitigate Pb but not Cd accumulation in soils: Evidence from a 49-year soil chronosequence in an industrial and mining city in Southwest China.

To address severe soil Pb and Cd contamination from anthropogenic activities, governments have implemented various environmental management measures. However, the extent to which these measures have constrained Pb and Cd accumulation in industrial and mining city soils remains unclear. Here, we investigated Pb and Cd accumulation patterns in soils of Panzhihua City, Southwest China, and determined their dominant anthropogenic drivers using Pb and Cd isotopes. Pb accumulation initially slowed and then increased, while Cd showed a continuous acceleration. Traffic and coal-burning power generation were the dominant anthropogenic forcings for Pb and Cd accumulation in the soils, respectively. Environmental protection measures, particularly the ban on leaded gasoline, significantly reduced Pb accumulation by decreasing traffic-related Pb contributions to soils from 1980 to 2008. However, environmental management measures could not practically mitigate Cd accumulation in the soils owing to the high Cd content in consumed coal, poor efficiency of air pollutant control measures, and steep rise in coal-burning power generation. This study thus indicates the criticality of controlling Cd emissions from thermal power generation. Additionally, the challenges faced by small industrial and mining cities during economic transformation and environmental policy implementation warrant more attention.

Predicting soil cadmium uptake by plants in a tailings reservoir during 48-year vegetation restoration.

Plant uptake can reduce soil cadmium (Cd) pollution, while how to exactly predict plant Cd uptake in industrial or mining areas during vegetation restoration remains unexplored. Taking Heteropogon contortus as the object plant, we predicted plant Cd uptake in the Majiatian tailings reservoir during 48-year vegetation restoration by the methods of soil total Cd, DGT (diffusive gradients in thin films technique) and acetic acid (HAc) extraction. Meanwhile, we explored the effects of soil properties on the accuracy of the prediction. Total Cd concentrations in the soils exhibited a better prediction of plant Cd uptake relative to the methods of HAc extraction and DGT. However, the DGT method effectively predicted plant Cd uptake at low Cd supply (lower than 0.42 µg/L), probably because of the dominant diffusion limitation by plants. The prediction of plant Cd uptake by HAc extraction was improved when combined with soil pH. Our results indicate that with increasing external Cd inputs during the vegetation restoration, soil total Cd and traditional extraction method in combination with soil properties are effective ways to predict plant Cd uptake, especially when the Cd fractions cannot be measured by DGT. However, the DGT method works once plant Cd uptake dominated by diffusion limitation despite the interference in soil properties.

Vanadium accumulation mode of Heteropogon contortus and its driving factors in Majiatian tailing reservoir in Panzhihua, Southwestern China.

Native plants in metal pollution sites have great potentials for mine rehabilitation. In the presented work, we investigated Vanadium (V) concentrations of soils and plants (Heteropogon contortus) in Majiatian V-Ti magnetite tailing reservoir in Panzhihua, Southwestern China. The objectives were to explore the V accumulation mode of H. contortus and its driving factors, as well as the phytoremediation potential of H. contortus. As the results, H. contortus accumulated 37.53 mg/kg and 8.69 mg/kg of V in root and aerial part, respectively. With the increase of rehabilitation age, root V concentrations decreased, while aerial part V concentrations remained constant. The significant negative correlations between root V and soil V, acid-soluble V (VHAc) (P < 0.05) indicated that increasing soil V and VHAc concentrations drove the V accumulation mode of H. contortus. Soil properties had a little influence on the V accumulation mode of H. contortus. Therefore, H. contortus might be not the suitable plant extractant to remove V from mine tailing for its lower V accumulation capacity. On the other hand, it can tolerate high V stress through elimination and detoxification/isolation V. Furthermore, the settlement of H. contortus increased the content of soil organic matter and might thus improve the soil quality. The cover of H. contortus is also beneficial to reduce the dispersion of the tailings and prevent contaminating surrounding soil. Therefor it showed a great potential to serve as a pioneer plant in the remediation of V-rich tailing reservoirs and other V-contaminated sites with similar poor soil condition.

Contamination, sources and health risk of heavy metals in soil and dust from different functional areas in an industrial city of Panzhihua City, Southwest China.

The contamination of heavy metals in urban soil and dust is closely related to anthropogenic emissions, while to what extent the metal contamination varies among different functional areas in industrial cities remains unclear. In this study, the contamination and health risk of seven heavy metals in the soil and dust were assessed at different functional areas of Panzhihua City, Southwest China, and their sources were identified by the spatial divisions and Pb isotopes. The results showed that the contamination of V and Cr in the vanadium/steel plant (VsA) and the contamination of Cd, Pb and Zn in the iron-ore smelting (IsA) were significantly higher relative to other functional areas. The sources of the contaminated heavy metals in the soil and dust were mainly from smelting and manufacturing vanadium/steel products, coal combustion and traffic. Vanadium and Cr were the major metals primarily contributing to the noncarcinogenic and carcinogenic risks, despite the low contamination level of Cr. The results indicate that the VsA is the priority control area in the Panzhihua City, and besides V, more attention should be paid in the future to monitor Cr risk in the soil and dust because of its high contribution to the health risk.

Fingerprinting vanadium in soils based on speciation characteristics and isotope compositions.

Vanadium (V) can have toxic effects on human organs and physiological systems, yet tracing V sources remains challenging. Here, two methods were used for V source tracing in soil based on speciation characteristics and isotope compositions. According to the sequential extraction method of the European Communities Bureau of Reference (BCR), the analysis of speciation distributions offers a possible means of distinguishing V sources. Here, the isotope compositions of polluted soils around a coal-fired power plant and smelter in China were used to identify the sources of V. Significant V isotope variation (δ51V range = -0.74 ± 0.07; mean ± 2SD = -0.52 ± 0.05‰) was observed in the soil samples, attributed to coal-burning (Δ51VCoal-Fly ash 1 = -0.31 ± 0.05‰; mean ± 2SD; n = 1) and smelting processes (Δ51VSlag-Fly ash 2 = -0.31 ± 0.07‰; mean ± 2SD; n = 1). All of the soil V isotope ratios plotted within the range of end-member components corresponding to potential V contributors in the environment. Among these, δ51V ranged from -0.74 ± 0.07 to -0.55 ± 0.02‰ in topsoil, the average δ51V was -0.52 ± 0.05‰ in the deep soils, and the δ51V of the end-member components ranged from -0.52 ± 0.05 to -0.94 ± 0.11‰. The primary anthropogenic source of V in the topsoil was fly ash from coal-burning that was consistent with the BCR method results. Furthermore, the downward migration of V was identified in the soil profile adjacent to the smelting plant, and V in the deep soils was dominated by natural sources relative to anthropogenic sources in the surface soils.

Tracing Pb and Possible Correlated Cd Contamination in Soils by Using Lead Isotopic Compositions.

Concentrations of Pb and Cd in topsoil from 24 locations along the Baguan River near a smelting dump in west Panzhihua were measured using ICP-MS to examine the spatial distributions of these toxic heavy metals. Twenty-one profile samples, 7 from each of 3 locations down to 80 cm, were also analyzed to establish background levels and Pb - Cd correlations. Lead isotopic ratios in all 45 samples and potential sources of soil contamination were determined using MC-ICP-MS. Contamination levels of Pb and Cd in soils from both sides of the river ranged from low to moderate, and the concentrations of Pb and Cd exhibited highly correlated behavior. Results of an isotope-tracer technique determined the number of end-member contaminants and background compositions contributing to the compositions of topsoils. Results of a binary mixing model indicated that contaminants in upslope soils from relatively higher elevations were coal and derivative products, and that these soils are isotopically distinct from downslope soils. Contaminants in downslope soils were slag and derivative products from V processing. Results demonstrate the use of Pb isotopic tracers in low-to-moderate contaminant levels to predict potential sources and Pb is a viable surrogate to trace potential Cd contamination in Panzhihua region.

Transformations of 2-line ferrihydrite and its effect on cadmium adsorption.

In this study, 2LFh was synthesized, and the effects of 2LFh synthesis in the laboratory as well as its synthetic products' mineral crystal phase changes during high temperature aging process caused by Ca2+, Mg2+, and Cl- were also studied. In addition, the Cd2+ adsorption effects of the products above with different pH values and different Cd2+ concentrations were studied in this experiment. The results showed that the existence of Ca2+ had no significant effect on the synthesis and aging of 2LFh. However, in the presence of Mg2+ and Cl-, the akaganeite could be found in the synthetic material, and with the increase of the ion concentration, the crystallinity of the formed akaganeite was higher. And akaganeite had a significant inhibitory effect on the aging of 2LFh, causing the Cd2+adsorption effect of 2LFh after aging was better than that of pure 2LFh. The adsorption and removal rates of Cd2+ in Fh2 series and Fh2-200 series were increased with the increase of initial concentration. With the increase of pH, the adsorption capacity and removal rate were increased, and the removal rate reached nearly 100% when pH value is ranging from 10 to 11. The isothermal adsorption experiment showed that the isothermal adsorption process of Cd2+ in Fh2 series and Fh2-200 series was in accordance with the Freundlich model. The affinity coefficient (Kf) of the Freundlich model of Fh2-200 series arranged in descending order is Fh2-200-Mgs> Fh2-200-Cas> Fh2-200s, showing that the Cd2+ adsorption capacity of Fh2-200 was relatively weak, while that of Fh2-200-Ca series and Fh2-200-Mg series was relatively strong, which was confirmed by the experimental results.