Phased Array Ultrasonic Method for Robotic Preload Measurement in Offshore Wind Turbine Bolted Connections.

This paper presents a novel approach for preload measurement of bolted connections, specifically tailored for offshore wind applications. The proposed method combines robotics, Phased Array Ultrasonic Testing (PAUT), nonlinear acoustoelasticity, and Finite Element Analysis (FEA). Acceptable defects, below a pre-defined size, are shown to have an impact on preload measurement, and therefore conducting simultaneous defect detection and preload measurement is discussed in this paper. The study demonstrates that even slight changes in the orientation of the ultrasonic transducer, the non-automated approach, can introduce a significant error of up to 140 MPa in bolt stress measurement and therefore a robotic approach is employed to achieve consistent and accurate measurements. Additionally, the study emphasises the significance of considering average preload for comparison with ultrasonic data, which is achieved through FEA simulations. The advantages of the proposed robotic PAUT method over single-element approaches are discussed, including the incorporation of nonlinearity, simultaneous defect detection and stress measurement, hardware and software adaptability, and notably, a substantial improvement in measurement accuracy. Based on the findings, the paper strongly recommends the adoption of the robotic PAUT approach for preload measurement, whilst acknowledging the required investment in hardware, software, and skilled personnel.

3D-Printed Polycaprolactone-Based Containing Calcium Zirconium Silicate: Bioactive Scaffold for Accelerating Bone Regeneration.

There is an essential clinical need to develop rapid process scaffolds to repair bone defects. The current research presented the development of calcium zirconium silicate/polycaprolactone for bone tissue engineering utilising melt extrusion-based 3D printing. Calcium zirconium silicate (CZS) nanoparticles were added to polycaprolactone (PCL) porous scaffolds to enhance their biological and mechanical properties, while the resulting properties were studied extensively. No significant difference was found in the melting point of the samples, while the crystallisation temperature points of the samples containing bioceramic increased from 36.1 to 40.2 °C. Thermal degradation commenced around 350 °C for all materials. According to our results, increasing the CZS content from 0 to 40 wt.% (PC40) in porous scaffolds (porosity about 55-62%) improved the compressive strength from 2.8 to 10.9 MPa. Furthermore, apatite formation ability in SBF solution increased significantly by enhancing the CZS percentage. According to MTT test results, the viability of MG63 cells improved remarkably (~29%) in PC40 compared to pure PCL. These findings suggest that a 3D-printed PCL/CZS composite scaffold can be fabricated successfully and shows great potential as an implantable material for bone tissue engineering applications.

Bioactive and Biodegradable Polycaprolactone-Based Nanocomposite for Bone Repair Applications.

This study investigated the relationship between the structure and mechanical properties of polycaprolactone (PCL) nanocomposites reinforced with baghdadite, a newly introduced bioactive agent. The baghdadite nanoparticles were synthesised using the sol-gel method and incorporated into PCL films using the solvent casting technique. The results showed that adding baghdadite to PCL improved the nanocomposites' tensile strength and elastic modulus, consistent with the results obtained from the prediction models of mechanical properties. The tensile strength increased from 16 to 21 MPa, and the elastic modulus enhanced from 149 to 194 MPa with fillers compared to test specimens without fillers. The thermal properties of the nanocomposites were also improved, with the degradation temperature increasing from 388 °C to 402 °C when 10% baghdadite was added to PCL. Furthermore, it was found that the nanocomposites containing baghdadite showed an apatite-like layer on their surfaces when exposed to simulated body solution (SBF) for 28 days, especially in the film containing 20% nanoparticles (PB20), which exhibited higher apatite density. The addition of baghdadite nanoparticles into pure PCL also improved the viability of MG63 cells, increasing the viability percentage on day five from 103 in PCL to 136 in PB20. Additionally, PB20 showed a favourable degradation rate in PBS solution, increasing mass loss from 2.63 to 4.08 per cent over four weeks. Overall, this study provides valuable insights into the structure-property relationships of biodegradable-bioactive nanocomposites, particularly those reinforced with new bioactive agents.

An eco-friendly, highly efficient, and transparent coating derived from guar gum and citric acid for flame retardant treatment of cotton fabrics.

A highly efficient, bio-ecofriendly, and transparent flame retardant (FR) for cotton fabric was developed and deposited onto the cellulose skeletal structure of cotton fabric through a one-pot sol-gel process. The flame retardant functional coating is composed of ammonium polyphosphate (APP), guar gum (GG), citric acid (CA), and a negligible amount of catalyst. Cotton fabrics were impregnated with different concentrations of ammonium polyphosphate and guar gum, with citric acid as a crosslinking agent. The overall crosslinking and grafting process was proven by FTIR and XPS. Based on the results, the designed coating exhibits over 90 % transmittance in the visible region. A 15 g/m2 flame-retardant coating induces excellent flame retardant efficiency at ultra-low flame-retardant concentrations of less than 6.25 wt%. Only a 5.25 wt% flame retardant concentration demonstrated condensed phase action, which resulted in 58.5 % and 73.6 % reductions in the pHRR and THR, respectively. Moreover, the limiting oxygen index (LOI) value showed a 74 % increase. The mechanical performance of FR coated cotton fibers was slightly reduced.

Development of an Injectable Shear-Thinning Nanocomposite Hydrogel for Cardiac Tissue Engineering.

Bone marrow-derived mesenchymal stem cells (MSCs) offer a promising therapeutic method for cardiac tissue regeneration. However, to monitor the fate of MSCs for tissue repair, a better stem cell delivery carrier is needed. Developing a unique injectable and shear-thinning dual cross-linked hybrid hydrogel for MSC delivery for cardiac tissue engineering is highly desirable. This hydrogel was synthesised using guest: host reaction based on alginate-cyclodextrin (Alg-CD) and adamantane-graphene oxide (Ad-GO). Here, the role of macromere concentration (10 and 12%) on the MSC function is discussed. Our hybrid hydrogels reveal a suitable oxygen pathway required for cell survival. However, this value is strongly dependent on the macromere concentrations, while the hydrogels with 12% macromere concentration (2DC12) significantly enhanced the oxygen permeability value (1.16-fold). Moreover, after two weeks of culture, rat MSCs (rMSCs) encapsulated in Alg-GO hydrogels expressed troponin T (TNT) and GATA4 markers. Noticeably, the 2DC12 hydrogels enhance rMSCs differentiation markers (1.30-times for TNT and 1.21-times for GATA4). Overall, our findings indicate that tuning the hydrogel compositions regulates the fate of encapsulated rMSCs within hydrogels. These outcomes may promote the advancement of new multifunctional platforms that consider the spatial and transient guidelines of undifferentiated cell destiny and capacity even after transplantation for heart tissue regeneration.

Electrospun Piezoelectric Polymer Nanofiber Layers for Enabling in Situ Measurement in High-Performance Composite Laminates.

This article highlights the effects from composite manufacturing parameters on fiber-reinforced composite laminates modified with layers of piezoelectric thermoplastic nanofibers and a conductive electrode layer. Such modifications have been used for enabling in situ deformation measurement in high-performance aerospace and renewable energy composites. Procedures for manufacturing high-performance composites are well-known and standardized. However, this does not imply that modifications via addition of functional layers (e.g., piezoelectric nanofibers) while following the same manufacturing procedures can lead to a successful multifunctional composite structure (e.g., for enabling in situ measurement). This article challenges success of internal embedment of piezoelectric nanofibers in standard manufacturing of high-performance composites via relying on composite process specifications and parameters only. It highlights that the process parameters must be revised for manufacturing of multifunctional composites. Several methods have been used to lay up and manufacture composites such as electrospinning the thermoplastic nanofibers, processing an inter digital electrode (IDE) made by conductive epoxy-graphene resin, and prepreg autoclave manufacturing aerospace grade laminates. The purpose of fabrication of IDE was to use a resin type (HexFlow RTM6) for the conductive layer similar to that used for the composite. Thereby, material mismatch is avoided and the structural integrity is sustained via mitigation of downgrading effects on the interlaminar properties. X-ray diffraction, Fourier transform infrared spectroscopy, energy dispersive X-ray spectroscopy, and scanning electron microscopy analyses have been carried out in the material characterization phase. Pulsed thermography and ultrasonic C-scanning were used for the localization of conductive resin embedded within the composite laminates. This study also provides recommendations for enabling internally embedded piezoelectricity (and thus health-monitoring capabilities) in high-performance composite laminates.