1.
Chemistry
; 20(19): 5573-9, 2014 May 05.
Artículo
en Inglés
| MEDLINE
| ID: mdl-24729439
RESUMEN
The synthesis of arylboronic ester derivatives from aryl chlorides by using aryl(amino)boranes is described. Palladium-catalyzed coupling between aryl chlorides and diisopropylaminoborane leads to the formation of a CB bond under mild conditions. A wide range of functional groups are tolerated, making this method particularly useful for the borylation of functionalized aromatics.