1.
J Am Chem Soc
; 143(11): 4112-4118, 2021 03 24.
Artículo
en Inglés
| MEDLINE
| ID: mdl-33709701
RESUMEN
The stereospecific, substrate (nitrogen source)-controlled intermolecular anti- and syn-1,2-diaminations of unactivated alkenes using the same catalysis (an iodine catalyst) is reported. The combined use of the two potential methods provides access to all of the disastereomeric forms of 1,2-diamines in spite of the availability of E- and Z-alkenes, and the resulting products can be readily converted into free vicinal diamines.