Gel Spinning of Polyacrylonitrile/Cellulose Nanocrystal Composite Fibers.

Polyacrylonitrile (PAN)/cellulose nanocrytal (CNC) fibers containing 0, 1, 5, and 10 wt % CNCs have been successfully produced by gel spinning. The rheological properties of solutions were investigated and the results showed that the complex viscosity and storage modulus of solutions were significantly affected by the presence of CNCs in the solution. Structure, morphology, mechanical properties and dynamic mechanical properties of these fibers have been investigated. Tensile modulus and strength increased from 14.5 to 19.6 GPa and from 624 to 709 MPa, respectively, as CNC loading increased from 0 to 10 wt %. Wide-angle X-ray diffraction results showed better PAN chain alignment and higher PAN crystallinity with the incorporation of CNCs.

Polyacrylonitrile fibers containing graphene oxide nanoribbons.

Graphene oxide nanoribbon (GONR) made by the oxidative unzipping of multiwalled carbon nanotube was dispersed in dimethylformamide and mixed with polyacrylonitrile (PAN) to fabricate continuous PAN/GONR composite fibers by gel spinning. Subsequently, PAN/GONR composite fibers were stabilized and carbonized in a batch process to fabricate composite carbon fibers. Structure, processing, and properties of the composite precursor and carbon fibers have been studied. This study shows that GONR can be used to make porous precursor and carbon fibers. In addition, GONR also shows the potential to make higher mechanical property carbon fibers than that achieved from PAN precursor only.

Microfibrous borate bioactive glass dressing sequesters bone-bound bisphosphonate in the presence of simulated body fluid.

Ion exchange occurs between borate bioactive glass and simulated body fluid. Borate bioactive glass dressings may be used for managing bisphosphonate-related osteonecrosis of the jaw through the formation of a complex incorporating leached calcium and borate ions and sequestered bone-bound bisphosphonates.