Dipolar collisions of polar molecules in the quantum regime.

Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range and spatially anisotropic. This is in stark contrast to the much studied dilute gases of ultracold atoms, which have isotropic and extremely short-range (or 'contact') interactions. Furthermore, the large electric dipole moment of polar molecules can be tuned using an external electric field; this has a range of applications such as the control of ultracold chemical reactions, the design of a platform for quantum information processing and the realization of novel quantum many-body systems. Despite intense experimental efforts aimed at observing the influence of dipoles on ultracold molecules, only recently have sufficiently high densities been achieved. Here we report the experimental observation of dipolar collisions in an ultracold molecular gas prepared close to quantum degeneracy. For modest values of an applied electric field, we observe a pronounced increase in the loss rate of fermionic potassium-rubidium molecules due to ultracold chemical reactions. We find that the loss rate has a steep power-law dependence on the induced electric dipole moment, and we show that this dependence can be understood in a relatively simple model based on quantum threshold laws for the scattering of fermionic polar molecules. In addition, we directly observe the spatial anisotropy of the dipolar interaction through measurements of the thermodynamics of the dipolar gas. These results demonstrate how the long-range dipolar interaction can be used for electric-field control of chemical reaction rates in an ultracold gas of polar molecules. Furthermore, the large loss rates in an applied electric field suggest that creating a long-lived ensemble of ultracold polar molecules may require confinement in a two-dimensional trap geometry to suppress the influence of the attractive, 'head-to-tail', dipolar interactions.

Controlling the hyperfine state of rovibronic ground-state polar molecules.

We report the preparation of a rovibronic ground-state molecular quantum gas in a single hyperfine state and, in particular, the absolute lowest quantum state. This addresses the last internal degree of freedom remaining after the recent production of a near quantum degenerate gas of molecules in their rovibronic ground state, and provides a crucial step towards full control over molecular quantum gases. We demonstrate a scheme that is general for bialkali polar molecules and allows the preparation of molecules in a single hyperfine state or in an arbitrary coherent superposition of hyperfine states. The scheme relies on electric-dipole, two-photon microwave transitions through rotationally excited states and makes use of electric nuclear quadrupole interactions to transfer molecular population between different hyperfine states.

A dipolar gas of ultracold molecules.

Ultracold polar molecular gases promise new directions and exciting applications in collisions and chemical reactions at ultralow energies, precision measurements, novel quantum phase transitions, and quantum information science. Here we briefly discuss key experimental requirements for observing strong dipole-dipole interactions in an ultracold dipolar gas of molecules. We then survey current experimental progress in the field with a focus on our recent work creating a near quantum degenerate gas of KRb polar molecules [Ni et al., Science, 2008, 322, 231].

An adaptable two-lens high-resolution objective for single-site resolved imaging of atoms in optical lattices.

In this paper, we present a high-resolution, simple, and versatile imaging system for single-site resolved imaging of atoms in optical lattices. The system, which relies on an adaptable infinite conjugate two-lens design, has a numerical aperture of 0.52, which can in the ideal case be further extended to 0.57. It is optimized for imaging on the sodium D2-line but allows us to tune the objective's diffraction limited performance between 400 nm and 1000 nm by changing the distance between the two lenses. Furthermore, the objective is designed to be integrated into a typical atomic physics vacuum apparatus where the operating distance can be large (>20 mm) and diffraction limited performance still needs to be achieved when imaging through thick vacuum windows (6 mm to 10 mm). Imaging gold nanoparticles, using a wavelength of 589 nm which corresponds to the D2-line of sodium atoms, we measure diffraction limited performance and a resolution corresponding to an Airy radius of less than 0.7 µm, enabling potential single-site resolution in the commonly used 532 nm optical lattice spacing.

Quantum-state controlled chemical reactions of ultracold potassium-rubidium molecules.

How does a chemical reaction proceed at ultralow temperatures? Can simple quantum mechanical rules such as quantum statistics, single partial-wave scattering, and quantum threshold laws provide a clear understanding of the molecular reactivity under a vanishing collision energy? Starting with an optically trapped near-quantum-degenerate gas of polar 40K87Rb molecules prepared in their absolute ground state, we report experimental evidence for exothermic atom-exchange chemical reactions. When these fermionic molecules were prepared in a single quantum state at a temperature of a few hundred nanokelvin, we observed p-wave-dominated quantum threshold collisions arising from tunneling through an angular momentum barrier followed by a short-range chemical reaction with a probability near unity. When these molecules were prepared in two different internal states or when molecules and atoms were brought together, the reaction rates were enhanced by a factor of 10 to 100 as a result of s-wave scattering, which does not have a centrifugal barrier. The measured rates agree with predicted universal loss rates related to the two-body van der Waals length.

Ultracold polar molecules near quantum degeneracy.

We report the creation and characterization of a near quantum-degenerate gas of polar 40K-87Rb molecules in their absolute rovibrational ground state. Starting from weakly bound heteronuclear KRb Feshbach molecules, we implement precise control of the molecular electronic, vibrational, and rotational degrees of freedom with phase-coherent laser fields. In particular, we coherently transfer these weakly bound molecules across a 125 THz frequency gap in a single step into the absolute rovibrational ground state of the electronic ground potential. Phase coherence between lasers involved in the transfer process is ensured by referencing the lasers to two single components of a phase-stabilized optical frequency comb. Using these methods, we prepare a dense gas of 4 x 10(4) polar molecules at a temperature below 400 nK. This fermionic molecular ensemble is close to quantum degeneracy and can be characterized by a degeneracy parameter of T/T(F) = 3. We have measured the molecular polarizability in an optical dipole trap where the trap lifetime gives clues to interesting decay mechanisms. Given the large measured dipole moment of the KRb molecules of 0.5 Debye, the study of quantum degenerate molecular gases interacting via strong dipolar interactions is now within experimental reach. PACS numbers: 37.10.Mn, 37.10.Pq.

Do mixtures of bosonic and fermionic atoms adiabatically heat up in optical lattices?

Mixtures of bosonic and fermionic atoms in optical lattices provide a promising arena to study strongly correlated systems. In experiments realizing such mixtures in the quantum-degenerate regime the temperature is a key parameter. We investigate the intrinsic heating and cooling effects due to an entropy-preserving raising of the optical lattice, identify the generic behavior valid for a wide range of parameters, and discuss it quantitatively for the recent experiments with 87Rb and 40K atoms. In the absence of a lattice, we treat the bosons in the Hartree-Fock-Bogoliubov-Popov approximation, including the fermions in a self-consistent mean-field interaction. In the presence of the full three-dimensional lattice, we use a strong coupling expansion. We find the temperature of the mixture in the lattice to be always higher than for the pure bosonic case, shedding light onto a key point in the analysis of recent experiments.

Collisional stability of fermionic Feshbach molecules.

Using a Feshbach resonance, we create ultracold fermionic molecules starting from a Bose-Fermi atom gas mixture. The resulting mixture of atoms and weakly bound molecules provides a rich system for studying few-body collisions because of the variety of atomic collision partners for molecules; either bosonic, fermionic, or distinguishable atoms. Inelastic loss of the molecules near the Feshbach resonance is dramatically affected by the quantum statistics of the colliding particles and the scattering length. In particular, we observe a molecule lifetime as long as 100 ms near the Feshbach resonance.

A high phase-space-density gas of polar molecules.

A quantum gas of ultracold polar molecules, with long-range and anisotropic interactions, not only would enable explorations of a large class of many-body physics phenomena but also could be used for quantum information processing. We report on the creation of an ultracold dense gas of potassium-rubidium (40K87Rb) polar molecules. Using a single step of STIRAP (stimulated Raman adiabatic passage) with two-frequency laser irradiation, we coherently transfer extremely weakly bound KRb molecules to the rovibrational ground state of either the triplet or the singlet electronic ground molecular potential. The polar molecular gas has a peak density of 10(12) per cubic centimeter and an expansion-determined translational temperature of 350 nanokelvin. The polar molecules have a permanent electric dipole moment, which we measure with Stark spectroscopy to be 0.052(2) Debye (1 Debye = 3.336 x 10(-30) coulomb-meters) for the triplet rovibrational ground state and 0.566(17) Debye for the singlet rovibrational ground state.

Tuning of heteronuclear interactions in a degenerate Fermi-Bose mixture.

We demonstrate tuning of interactions between fermionic 40K and bosonic 87Rb atoms by Feshbach resonances and access the complete phase diagram of the harmonically trapped mixture from phase separation to collapse. On the attractive side of the resonance, we observe a strongly enhanced mean-field energy of the condensate due to the mutual mean-field confinement, predicted by a Thomas-Fermi model. As we increase heteronuclear interactions beyond a threshold, we observe an induced collapse of the mixture. On the repulsive side of the resonance, we observe vertical phase separation of the mixture in the presence of the gravitational force, thus entering a completely unexplored part of the phase diagram of the mixture. In addition, we identify the 515 G resonance as p wave by its characteristic doublet structure.

Interaction-driven dynamics of 40K- 87Rb Fermion-Boson gas mixtures in the large-particle-number limit.

We have studied effects of interspecies attraction in a Fermi-Bose mixture over a large regime of particle numbers in the 40K-87Rb system. We report on the observation of a mean-field driven collapse at critical particle numbers of 1.2 x 10(6) 87Rb atoms in the condensate and 7.5 x 10(5) 40K atoms consistent with mean-field theory for a scattering length of aFB = -284a(0). For large overcritical particle numbers, we see evidence for revivals of the collapse. Part of our detailed study of the decay dynamics and mechanisms is a measurement of the (87Rb- 87Rb- 40K) three-body loss coefficient K3 = (2.8 +/- 1.1) x 10(-28) cm6/s, which is an important parameter for dynamical studies of the system.

Ultracold heteronuclear molecules in a 3D optical lattice.

We report on the creation of ultracold heteronuclear molecules assembled from fermionic 40K and bosonic 87Rb atoms in a 3D optical lattice. Molecules are produced at a heteronuclear Feshbach resonance on both the attractive and the repulsive sides of the resonance. We precisely determine the binding energy of the heteronuclear molecules from rf spectroscopy across the Feshbach resonance. We characterize the lifetime of the molecular sample as a function of magnetic field and measure lifetimes between 20 and 120 ms. The efficiency of molecule creation via rf association is measured and is found to decrease as expected for more deeply bound molecules.

Localization of bosonic atoms by fermionic impurities in a three-dimensional optical lattice.

We observe a localized phase of ultracold bosonic quantum gases in a 3-dimensional optical lattice induced by a small contribution of fermionic atoms acting as impurities in a Fermi-Bose quantum gas mixture. In particular, we study the dependence of this transition on the fermionic (40)K impurity concentration by a comparison to the corresponding superfluid to Mott-insulator transition in a pure bosonic (87)Rb gas and find a significant shift in the transition parameter. The observed shift is larger than expected based on a simple mean-field argument, which indicates that disorder-related effects play a significant role.