Plasmonic nanoparticle's anti-aggregation application in sensor development for water and wastewater analysis.

Colorimetric sensors have emerged as a powerful tool in the detection of water pollutants. Plasmonic nanoparticles use localized surface plasmon resonance (LSPR)-based colorimetric sensing. LSPR-based sensing can be accomplished through different strategies such as etching, growth, aggregation, and anti-aggregation. Based on these strategies, various sensors have been developed. This review focuses on the newly developed anti-aggregation-based strategy of plasmonic nanoparticles. Sensors based on this strategy have attracted increasing interest because of their exciting properties of high sensitivity, selectivity, and applicability. This review highlights LSPR-based anti-aggregation sensors, their classification, and role of plasmonic nanoparticles in these sensors for the detection of water pollutants. The anti-aggregation based sensing of major water pollutants such as heavy metal ions, anions, and small organic molecules has been summarized herein. This review also provides some personal insights into current challenges associated with anti-aggregation strategy of LSPR-based colorimetric sensors and proposes future research directions.

High Concentration of Sulphate Coupled with Climate Warming Generates Ecosystem Feedback Under Sub-Oxic Conditions at Sediment-Water Interface in the Ganga River.

Here, we quantified sediment phosphorus (P) release in relation to concentrations of dissolved oxygen (DO) and sulphate, and increase in temperature in a major river of India subjected to long-term human perturbations. We found a substantial increase in sediment P release, an ecosystem feedback, at higher concentrations of sulphate, more towards the lower end of DO concentrations. A 2°C warming increased sediment P release upto 25.21% and caused a drop in DO level by 16%. Our findings reconcile the observed sulphate-driven changes in sediment P release across systems, and provide first experimental evidence of warming-induced increases. Our results imply that aquatic ecosystems will undergo self-fertilizing effect as the planet warming interacts with other human perturbations. This has implications for eutrophication linkages and ecosystem functioning.