Bevel-edge epitaxy of ferroelectric rhombohedral boron nitride single crystal.

Within the family of two-dimensional dielectrics, rhombohedral boron nitride (rBN) is considerably promising owing to having not only the superior properties of hexagonal boron nitride1-4-including low permittivity and dissipation, strong electrical insulation, good chemical stability, high thermal conductivity and atomic flatness without dangling bonds-but also useful optical nonlinearity and interfacial ferroelectricity originating from the broken in-plane and out-of-plane centrosymmetry5-23. However, the preparation of large-sized single-crystal rBN layers remains a challenge24-26, owing to the requisite unprecedented growth controls to coordinate the lattice orientation of each layer and the sliding vector of every interface. Here we report a facile methodology using bevel-edge epitaxy to prepare centimetre-sized single-crystal rBN layers with exact interlayer ABC stacking on a vicinal nickel surface. We realized successful accurate fabrication over a single-crystal nickel substrate with bunched step edges of the terrace facet (100) at the bevel facet (110), which simultaneously guided the consistent boron-nitrogen bond orientation in each BN layer and the rhombohedral stacking of BN layers via nucleation near each bevel facet. The pure rhombohedral phase of the as-grown BN layers was verified, and consequently showed robust, homogeneous and switchable ferroelectricity with a high Curie temperature. Our work provides an effective route for accurate stacking-controlled growth of single-crystal two-dimensional layers and presents a foundation for applicable multifunctional devices based on stacked two-dimensional materials.

Co, N co-doped porous carbon-based nanozyme as an oxidase mimic for fluorescence and colorimetric biosensing of butyrylcholinesterase activity.

A Co, N co-doped porous carbon-based nanozyme (Co-N-C nanozyme) has been fabricated. Taking advantages of the excellent oxidase catalytic activity and significant stability of Co-N-C nanozyme, we propose a fluorescence and colorimetric system based on Co-N-C nanozyme and red-emitting carbon quantum dots (RCDs) for butyrylcholinesterase (BChE) sensing. As the chromogenic substrate 3,3',5,5'-tetramethylbenzidine (TMB) was catalyzed and oxidized by Co-N-C nanozyme, the generated oxTMB had a new absorption peak at 652 nm, which resulted in the significant quenching of the fluorescence of the carbon quantum dots at 610 nm. Under the catalysis of BChE, thiocholine was generated from the hydrolysis of S-butyrylthiocholine iodide (BTCh), and the as-generated thiocholine effectively inhibited the oxidation of TMB catalyzed by Co-N-C nanozyme, leading to a decrease of the absorption of oxTMB at 652 nm and effective fluorescence recovery of RCDs. By measuring the absorbance of produced oxTMB at 652 nm and the fluorescence of RCDs at 610 nm, the fluorescence and colorimetric system both exhibited an outstanding linear response to the activity of BChE in the range 0.5 to 40 U L-1, with a detection limit of 0.16 U L-1 and 0.21 U L-1, respectively. Furthermore, this established dual-channel biosensing strategy has been successfully applied to the determination of BChE in human serum samples. The present work has effectively expanded the development and application of nanozyme in biosensing.

Evaluation of an anti-parasitic compound extracted from Streptomyces sp. HL-2-14 against fish parasite Ichthyophthirius multifiliis.

The present study was conducted to evaluate the anti-parasitic activity of a pure compound from Streptomyces sp. HL-2-14 against fish parasite Ichthyophthirius multifiliis, and elucidate its chemical structure. By electron ionization mass spectrometry (ESI-MS) and nuclear magnetic resonance spectrum (1H NMR and 13C NMR), the compound was identified as amphotericin B (AmB). The in vitro trials revealed that AmB can effectively kill the theronts and tomonts of I. multifiliis with the median lethal concentration (LC50) of 0·8 mg L-1 at 30 min for the theronts and 4·3 mg L-1 at 2 h for the tomonts, respectively. AmB at 5 mg L-1 significantly reduced I. multifiliis infectivity prevalence and intensity on grass carp (Ctenopharyngodon idella), and consequently decreased fish mortality, from 100% in control group to 30% in treated group. The 72 h acute toxicity (LC50) of AmB on grass carp was 20·6 mg L-1, but fish mortality was occurred when exposure to 13·0 mg L-1. These results indicated that AmB was effective in the therapy of I. multifiliis infection, but the safety concentration margin is relatively narrow. Further efforts aiming to decrease the toxicity and improve the therapeutic profile remain to be needed.

Research Progress in the Preparation of Transition Metal Sulfide Materials and Their Supercapacitor Performance.

Transition metal sulfides are widely used in supercapacitor electrode materials and exhibit excellent performance because of their rich variety, low price, and high theoretical specific capacity. At present, the main methods to prepare transition metal sulfides include the hydrothermal method and the electrochemical method. In order to further improve their electrochemical performance, two aspects can be addressed. Firstly, by controllable synthesis of nanomaterials, porous structures and large surface areas can be achieved, thereby improving ion transport efficiency. Secondly, by combining transition metal sulfides with other energy storage materials, such as carbon materials and metal oxides, the synergy between different materials can be fully utilized. However, future research still needs to address some challenges. In order to guide further in-depth research, it is necessary to combine the current research-derived knowledge and propose a direction for future development of transition metal sulfide electrode materials.

Two-Dimensional Ultrahigh Unconventional Piezoelectricity Driven by Charge Screening.

In the past decade, piezoelectricity has been explored in a series of two-dimensional (2D) materials for nanoelectromechanical applications, while their piezoelectric coefficients are mostly much lower than those of prevalent piezoceramics. In this paper, we propose an unconventional approach of inducing 2D ultrahigh piezoelectricity dominated by charge screening instead of lattice distortion and show the first-principles evidence of such piezoelectricity in a series of 2D van der Waals bilayers, where the bandgap can be remarkably tuned via applying a moderate vertical pressure. Their polarizations can switch between the screened and unscreened state by a pressure-driven metal-insulator transition, which can be realized via tuning interlayer hybridization or inhomogeneous electrostatic potential by substrate layer to change the band splitting or tuning the relative energy shift between bands utilizing the vertical polarization of the substrate layer. Such 2D piezoelectric coefficients can be unprecedented and orders of magnitude higher than those of previously studied monolayer piezoelectrics, and their high efficiency of energy harvesting in nanogenerators can be expected.

Research Progress in Fluid Energy Collection Based on Friction Nanogenerators.

In recent decades, the development of electronic technology has provided opportunities for the Internet of Things, biomedicine, and energy harvesting. One of the challenges of the Internet of Things in the electrification era is energy supply. Centralized energy supply has been tested over hundreds of years of history, and its advantages such as ideal output power and stable performance are obvious, but it cannot meet the specific needs of the Internet of Things, and distributed energy supply also has a large demand. Since the invention of nanogenerators, another promising solution for fluid energy harvesting has been opened up. The triboelectric nanogenerator is an emerging platform technology for electromechanical energy conversion, which can realize the collection of fluid energy such as wind energy and wave energy. In this paper, we first introduce the fundamentals of triboelectric nanogenerators and their applications in wind and wave energy harvesting devices. We then discuss the methods of device optimization in the next development of TENG and conclude by considering the future prospects and challenges for triboelectric nanogenerator harvesting devices.

Research Progress on the Application of Triboelectric Nanogenerators for Wind Energy Collection.

The escalating global energy demand necessitates the exploration of renewable energy sources, with wind energy emerging as a crucial and widely available resource. With wind energy exhibiting a vast potential of approximately 1010 kw/a per year, about ten times that of global hydroelectric power generation, its efficient conversion and utilization hold the promise of mitigating the pressing energy crisis and replacing the dominant reliance on fossil fuels. In recent years, Triboelectric Nanogenerators (TENGs) have emerged as novel and efficient means of capturing wind energy. This paper provides a comprehensive summary of the fundamental principles governing four basic working modes of TENGs, elucidating the structures and operational mechanisms of various models employed in wind energy harvesting. Furthermore, it highlights the significance of two major TENG configurations, namely, the vertical touch-separation pattern structure and the independent layer pattern for wind energy collection, emphasizing their respective advantages. Furthermore, the study briefly discusses the current strengths of nano-friction power generation in wind energy harvesting while acknowledging the existing challenges pertaining to device design, durability, operation, and maintenance. The review concludes by presenting potential research directions and prospects for triboelectric nanogenerators generation in the realm of wind energy, offering valuable insights for researchers and scholars in the field.

Triboelectric Nanogenerators for Efficient Low-Frequency Ocean Wave Energy Harvesting with Swinging Boat Configuration.

To reach ocean resources, sea activities and marine equipment variety are increasing, requiring offshore energy supply. Marine wave energy, the marine renewable energy with the most potential, offers massive energy storage and great energy density. This research proposes a swinging boat-type triboelectric nanogenerator concept for low-frequency wave energy collection. Triboelectric electronanogenerators with electrodes and a nylon roller make up the swinging boat-type triboelectric nanogenerator (ST-TENG). COMSOL electrostatic simulations and power generation concepts of independent layer and vertical contact separation modes of operation explain the device functionality. By rolling the drum at the bottom of the integrated boat-like device, it is possible to capture wave energy and convert it into electrical energy. Based on it, the ST load, TENG charging, and device stability are evaluated. According to the findings, the maximum instantaneous power of the TENG in the contact separation and independent layer modes reaches 246 W and 112.5 µW at matched loads of 40 MΩ and 200 MΩ, respectively. Additionally, the ST-TENG can retain the usual functioning of the electronic watch for 45 s while charging a 33 µF capacitor to 3 V in 320 s. Long-term low-frequency wave energy collection is possible with the device. The ST-TENG develops novel methods for large-scale blue energy collection and maritime equipment power.