Bromine-Functionalized Covalent Organic Frameworks for Efficient Triboelectric Nanogenerator.

Covalent organic frameworks (COFs) enable precise integration of various organic building blocks into porous skeletons through topology predesign. Here, we report the first example of COFs by integrating electron withdrawing bromine group onto the skeletons for triboelectric nanogenerators (TENG). The resulting framework exhibits high surface area and good crystallinity. Thus, the bromine functionalized COF has more regular aligned π columns and arrays over the skeleton than bare COFs, which in turn significantly enhances charge transport ability. As a result, bromine functionalized COFs showed higher electrical output performance at 5 Hz with a peak value of short circuit current density of 43.6 µA and output voltage of 416 V, which is 2 and 1.3 times higher than those of bare COFs (21.6 µA and 318 V), respectively. These results demonstrated that this strategy for engineering electron withdrawing groups on the skeleton could open a new aspect of COFs for developing TENG devices.

Patterned, morphing composites via maskless photo-click lithography.

Morphing materials, also known as smart materials are attracting increasing attention as sensors, actuators and in soft robotic applications. In this work bilayered morphing composites were created by exploiting the thiol-ene photoclick reaction via maskless digital light processing (DLP). This technique allows for gradients and patterns of near infrared (nIR)-triggered materials to be efficiently crosslinked to substrates, with suitable interfacial adhesion to realise complex morphing. Photo-thermally responsive composites are produced by DLP patterning of reduced graphene oxide-filled chitosan-methacrylamide (rGO-chitosan-MA) on thiolated polydimethylsiloxane substrates via thiol-ene photoclick reaction. Morphing composites with parallel striped patterns and box-like hinges were printed via DLP to realise self-rolling and self-folding behaviours. Bilayered structures, with gradient rGO-chitosan-MA thicknesses (2-8 µm), were produced by controlling the light intensity from the DLP device. These gradient bilayered structures enable photothermal-triggered gradient bending and morphing exemplified here by a "walking worm" and a kirigami-inspired "opening flower". Thermo-mechanical calculations were performed to estimate bending angles, and finite element analysis applied to simulate self-folding and bending. The difference between simulation and measurements is in the range 0.4-7.6%, giving confidence to the assumptions and simplifications applied in design.

Infusion Simulation of Graphene-Enhanced Resin in LCM for Thermal and Chemo-Rheological Analysis.

The present numerical study proposes a framework to determine the heat flow parameters-specific heat and thermal conductivity-of resin-graphene nanoplatelets (GNPs) (modified) as well as non-modified resin (with no GNPs). This is performed by evaluating the exothermic reaction which occurs during both the filling and post-filling stages of Liquid Composite Moulding (LCM). The proposed model uses ANSYS Fluent to solve the Stokes-Brinkman (momentum and mass), energy, and chemical species conservation equations to a describe nano-filled resin infusion, chemo-rheological changes, and heat release/transfer simultaneously on a Representative Volume Element (RVE). The transient Volume-of-Fluid (VOF) method is employed to track free-surface propagation (resin-air interface) throughout the computational domain. A User-Defined Function (UDF) is developed together with a User-Defined Scaler (UDS) to incorporate the heat generation (polymerisation), which is added as an extra source term into the energy equation. A separate UDF is used to capture intra-tow (microscopic) flow by adding a source term into the momentum equation. The numerical findings indicate that the incorporation of GNPs can accelerate the curing of the resin system due to the high thermal conductivity of the nanofiller. Furthermore, the model proves its capability in predicting the specific heat and thermal conductivity of the modified and non-modified resin systems utilising the computed heat of reaction data. The analysis shows an increase of ∼15% in the specific heat and thermal conductivity due to different mould temperatures applied (110-170 °C). This, furthermore, stresses the fact that the addition of GNPs (0.2 wt.%) improves the resin-specific heat by 3.68% and thermal conductivity by 58% in comparison to the non-modified thermoset resin. The numerical findings show a satisfactory agreement with and in the range of experimental data available in the literature.

A Biodegradable Stereo-Complexed Poly (Lactic Acid) Drinking Straw of High Heat Resistance and Performance.

Current biodegradable drinking straws suffer from poor heat resistance and rigidity when wet, causing user dissatisfaction. Here, a fully biodegradable straw formed by stereocomplexation of poly (lactic acid) (SC-PLA) is reported. Because of the unique strong interaction and high density of link chains between stereocomplex crystallites (over 70% crystallinity), SC-PLA straws outperform their counterparts on the market. This coupled with the advantages of simple processing (solution casting and annealing) and relatively low cost (~2.06 cents per straw) makes SC-PLA drinking straws a superior substitute for plastic ones. Commercially available PLLA straws lose almost 60% of their flexural strength when wet compared to less than 5% of the SC-PLA straws proposed in this study.

A Numerical Thermo-Chemo-Flow Analysis of Thermoset Resin Impregnation in LCM Processes.

This paper presents a numerical framework for modelling and simulating convection-diffusion-reaction flows in liquid composite moulding (LCM). The model is developed in ANSYS Fluent with customised user-defined-functions (UDFs), user-defined-scalar (UDS), and user-defined memory (UDM) codes to incorporate the cure kinetics and rheological characteristics of thermoset resin impregnation. The simulations were performed adopting volume-of-fluid (VOF)-a multiphase flow solution-based on finite volume method (FVM). The developed numerical approach solves Darcy's law, heat transfer, and chemical reactions in LCM process simultaneously. Thereby, the solution scheme shows its ability to provide information on flow-front, viscosity development, degree of cure, and rate of reaction at once unlike existing literature that commonly focuses on impregnation stage and cure stage in isolation. Furthermore, it allows online monitoring, controlled boundary conditions, and injection techniques (for design of manufacturing) during the mould filling and curing stages. To examine the validity of the model, a comparative analysis was carried out for a simple geometry, in that the numerical results indicate good agreement-3.4% difference in the degree of cure compared with previous research findings.

Enhancement of Output Performance of Triboelectric Nanogenerator by Switchable Stimuli in Metal-Organic Frameworks for Photocatalysis.

Precise control of the structure of crystalline materials is an efficient strategy to manipulate the fundamental performance of solids. In metal-organic framework (MOF) materials, this control can be realized by reversible cation-exchange through chemically driven changes in the crystalline state. Herein, we reported that the reversible structural transformations between an anionic Zn-MOF (1) and a topologically equivalent bimetallic Zn/Co-MOF (2) were accomplished. Both MOFs powders and their hybrid composites were used as positive electrode materials to assemble triboelectric nanogenerators (TENGs). The results demonstrated that the output performance of the Zn/Co-MOF-TENG was effectively improved because the introduction of Co ions makes electron transfer easier. Moreover, the output performance of the TENGs based on MOF@PVDF (PVDF = polyvinylidene fluoride) composite films showed that the Zn/Co-MOF@PVDF-TENG possessed much higher output than these corresponding film-based and MOF-based TENGs. As a practical application, the superior output of Zn/Co-MOF@PVDF-TENG was used to light an ultraviolet lamp plate for the [2 + 2] photochemical cycloaddition of organometallic macrocycles.

A Numerical Analysis of Resin Flow in Woven Fabrics: Effect of Local Tow Curvature on Dual-Scale Permeability.

Permeability is a crucial flow parameter in liquid composite moulding (LCM), which is required to predict fibre impregnation, void formation and resin back flow. This work investigates the dual-scale (micro- and meso-) nature of permeability during resin infusion into woven fabric by incorporating the intra tow flow where the degree of local tow curvature (tow/yarn undulation) is taken into account. The mesoscopic permeability of a dual-scale porous media in a unit cell is estimated using Darcy's law, where the Gebart analytical model is applied for the intra tow flow in longitudinal and transverse directions with respect to distinct fibre packing arrangements. The results suggest that for a low fibre volume fraction (≤42%), the degree of local curvature at the mesoscale can be neglected. However, for a high fibre volume fraction (>42%) and a higher fibre bundle curvature, the proposed model should be adopted, since the resin flow is affected by a mesoscopic tow curvature that could result in around 14% error in predicting permeability. It is shown that the permeability results of the current study are in good agreement with and in the range of the retrieved available experimental data from the literature.

Dielectric spectroscopy of Baijiu over 2-20 GHz using an open-ended coaxial probe.

The complex electric permittivity of Baijiu (one of the most consumed beverages) is measured over a frequency range of 2 to 20 GHz using a low-cost open-ended coaxial probe and a portable microwave analyzer. The Cole-Cole equation is used to fit the permittivity data, and the parameter values related are extracted using the particle swarm optimization. A linear relationship is obtained between these parameters and the alcohol by volume. A strong dependence of the permittivity on the alcohol content is also observed for other alcoholic drinks, including brandy and whisky. The study demonstrates that the microwave technique provides an efficient solution in the effort to determine the alcohol content and the principal component analysis is a powerful tool for the quick estimation of the dielectric properties. The sensor presented can contribute to efficient on-site quality control of alcoholic drinks. PRACTICAL APPLICATION: The microwave approach presented could offer an economical approach for the characterization of Baijiu and a general solution to the alcohol content determination for the alcoholic drinks industry.

Direct-Write Piezoelectric Transducers on Carbon-Fiber-Reinforced Polymer Structures for Exciting and Receiving Guided Ultrasonic Waves.

Advancements in the structural health monitoring (SHM) technology of composite materials are of paramount importance for early detection of critical damage. In this work, direct-write transducers (DWTs) were designed for the excitation and reception of selective ultrasonic guided waves and fabricated by spraying 25- [Formula: see text]-thick piezoelectric poly(vinylidene fluoride-co-trifluoroethylene) [P(VDF-TRFE)] coating with a comb-shaped electrode on carbon fiber-reinforced polymer (CFRP) plates. The characteristics and performance of the ultrasonic DWTs were benchmarked with the state-of-the-art devices, discrete lead zirconate titanate (PZT) ceramic transducers surface-mounted on the same CFRP plates. The DWTs exhibited improved Lamb wave mode excitation (A0 or S0 mode) relative to the discrete PZT transducers. Moreover, high signal-to-noise ratio was obtained by effectively canceling other modes and enhancing the directivity with the periodic comb-shaped electrode design of the DWTs, despite the smaller signal amplitudes. The enhanced directivity overcompensates for lower amplitude attenuation, making DWT a good candidate for locally monitoring critical stress hot spot regions in the CFRP structure prone to early damage initiation. It is shown that pairing a DWT sensor with a discrete PZT actuator could further achieve balanced performance in both wave mode selection and signal amplitudes, making this combination really attractive for ultrasonic SHM.

A Review of Piezoelectric and Magnetostrictive Biosensor Materials for Detection of COVID-19 and Other Viruses.

The spread of the severe acute respiratory syndrome coronavirus has changed the lives of people around the world with a huge impact on economies and societies. The development of wearable sensors that can continuously monitor the environment for viruses may become an important research area. Here, the state of the art of research on biosensor materials for virus detection is reviewed. A general description of the principles for virus detection is included, along with a critique of the experimental work dedicated to various virus sensors, and a summary of their detection limitations. The piezoelectric sensors used for the detection of human papilloma, vaccinia, dengue, Ebola, influenza A, human immunodeficiency, and hepatitis B viruses are examined in the first section; then the second part deals with magnetostrictive sensors for the detection of bacterial spores, proteins, and classical swine fever. In addition, progress related to early detection of COVID-19 (coronavirus disease 2019) is discussed in the final section, where remaining challenges in the field are also identified. It is believed that this review will guide material researchers in their future work of developing smart biosensors, which can further improve detection sensitivity in monitoring currently known and future virus threats.

Novel lactone-layered double hydroxide ionomer powders for bone tissue repair.

This article describes the use of a novel lactone-layered double hydroxide polymer network (PN), derived from a poly(lactide-co-caprolactone) copolymer, as a controlled ion-release agent for artificial bone tissue regeneration. The osteogenic cell culture Saos-2 is used as a test culture to investigate the PN's performance as an extracellular ion-release agent. The compelling performance of this PN is demonstrated in both growth and osteogenic media compared with a control of cells grown on tissue culture plastic (TCP) without PN. Firstly, the PNs released concentration of magnesium ions over time ranging from 10 to 60 mM after 24 hr, depending on the PN sample. After incubation of Saos-2 with the PN, while no difference was seen in cell number, there was significant upregulation of bone-related gene expression at 14 days-~5fold increase in Bone Morphogenetic Protein 2, ~3fold increase in osteopontin and ~2fold increase in collagen Type I. In addition, normalized alkaline phosphatase activity was seen to significantly increase by ~2fold with PN presence. A ~4fold increase in collagen Type I protein expression (via Gomori Trichrome Stain) was observed with PN presence. In addition, a ~4fold increase in phosphate deposits (as seen with Von Kossa staining analysis) was seen with PN presence. It is found that this novel PN material has a significant potential for bone tissue regeneration.

Cream roll-inspired advanced MnS/C composite for sodium-ion batteries: encapsulating MnS cream into hollow N,S-co-doped carbon rolls.

With advantages of high theoretical capacity and low cost, manganese sulfide (MnS) has become a potential electrode material for sodium-ion batteries (SIBs). However, complicated preparations and limited cycle life still hinder its application. Inspired by cream rolls in our daily life, a MnS/N,S-co-doped carbon tube (MnS/NSCT) composite with a 3D cross-linked tubular structure is prepared via an ultra-simple and low-cost method in this work. As the anode for SIBs, the cream roll-like MnS/NSCT composite has delivered the best electrochemical performance to date (the highest capacity of 550.6 mA h g-1 at 100 mA g-1, the highest capacity of 447.0 mA h g-1 after 1400 cycles at 1000 mA g-1, and the best rate performance of 319.8 mA h g-1 at 10 000 mA g-1). Besides, according to several in situ and ex situ techniques, the sodium storage mechanism of MnS/NSCTs is mainly from a conversion reaction, and the superior electrochemical performance of MnS/NSCTs is mainly attributed to the unique cream roll-like structure. More importantly, this simple method may be feasible for other anode materials, which will greatly promote the development of SIBs.

Vibration frequency analysis of three-layered cylinder shaped shell with effect of FGM central layer thickness.

In this research, vibration frequency analysis of three layered functionally graded material (FGM) cylinder-shaped shell is studied with FGM central layer and the internal and external layers are of homogenous material. Strain and curvature-displacement relations are taken from Sander's shell theory. The shell frequency equation is obtained by employing the Rayleigh Ritz method. Influence on natural frequencies (NFs) is observed for various thickness of the middle layer. The characteristics beam functions are used to estimate the dependence of axial modal. Results are obtained for thickness to radius ratios and length to radius ratios for different edge conditions. The validity of this method is checked for numerous results in the open literature.

Early Damage Detection in Composites during Fabrication and Mechanical Testing.

Fully integrated monitoring systems have shown promise in improving confidence in composite materials while reducing lifecycle costs. A distributed optical fibre sensor is embedded in a fibre reinforced composite laminate, to give three sensing regions at different levels through-the-thickness of the plate. This study follows the resin infusion process during fabrication of the composite, monitoring the development of strain in-situ and in real time, and to gain better understanding of the resin rheology during curing. Piezoelectric wafer active sensors and electrical strain gauges are bonded to the plate after fabrication. This is followed by progressive loading/unloading cycles of mechanical four point bending. The strain values obtained from the optical fibre are in good agreement with strain data collected by surface mounted strain gauges, while the sensing regions clearly indicate the development of compressive, neutral, and tensile strain. Acoustic emission event detection suggests the formation of matrix (resin) cracks, with measured damage event amplitudes in agreement with values reported in published literature on the subject. The Felicity ratio for each subsequent loading cycle is calculated to track the progression of damage in the material. The methodology developed here can be used to follow the full life cycle of a composite structure, from manufacture to end-of-life.

Thermal Diffusivity Mapping of Graphene Based Polymer Nanocomposites.

Nanoparticle dispersion is widely recognised as a challenge in polymer nanocomposites fabrication. The dispersion quality can affect the physical and thermomechanical properties of the material system. Qualitative transmission electronic microscopy, often cumbersome, remains as the 'gold standard' for dispersion characterisation. However, quantifying dispersion at macroscopic level remains a difficult task. This paper presents a quantitative dispersion characterisation method using non-contact infrared thermography mapping that measures the thermal diffusivity (α) of the graphene nanocomposite and relates α to a dispersion index. The main advantage of the proposed method is its ability to evaluate dispersion over a large area at reduced effort and cost, in addition to measuring the thermal properties of the system. The actual resolution of this thermal mapping reaches 200 µm per pixel giving an accurate picture of graphene nanoplatelets (GNP) dispersion. The post-dispersion treatment shows an improvement in directional thermal conductivity of the composite of up to 400% increase at 5 wt% of GNP. The Maxwell-Garnet effective medium approximation is proposed to estimate thermal conductivity that compare favourably to measured data. The development of a broadly applicable dispersion quantification method will provide a better understanding of reinforcement mechanisms and effect on performance of large scale composite structures.

Transverse Crack Detection in 3D Angle Interlock Glass Fibre Composites Using Acoustic Emission.

In addition to manufacturing cost and production rates, damage resistance has become a major issue for the composites industry. Three-dimensional (3D) woven composites have superior through-thickness properties compared to two-dimensional (2D) laminates, for example, improved impact damage resistance, high interlaminar fracture toughness and reduced notch sensitivity. The performance of 3D woven preforms is dependent on the fabric architecture, which is determined by the binding pattern. For this study, angle interlock (AI) structures with through-thickness binding were manufactured. The AI cracking simulation shows that the transverse component is the one that leads to transverse matrix cracking in the weft yarn under tensile loading. Monitoring of acoustic emission (AE) during mechanical loading is an effective tool in the study of damage processes in glass fiber-reinforced composites. Tests were performed with piezoelectric sensors bonded on a tensile specimen acting as passive receivers of AE signals. An experimental data has been generated which was useful to validate the multi-physics finite element method (MP-FEM), providing insight into the damage behaviour of novel 3D AI glass fibre composites. MP-FEM and experimental data showed that transverse crack generated a predominant flexural mode A0 and also a less energetic extensional mode S0.