1.
Phys Chem Chem Phys
; 24(38): 23481-23489, 2022 Oct 05.
Artículo
en Inglés
| MEDLINE
| ID: mdl-36129047
RESUMEN
Orientational control within thin films is crucial for the preparation of organic field effect transistors (OFETs). The highly ordered liquid crystalline smectic E phase (SmE) is known as a powerful template for solution processed thin films. Here, we describe the synthesis and characterization of three novel azulene-thiophene hybrid materials. Liquid crystalline characterization showed the presence of wide SmE phases. Thin films were prepared by spin-coating at mesophase temperature. Due to the self-aligning properties of the SmE phase uniformly flat films with good molecular alignment were manufactured. Top contact bottom gate OFETs showed mobilities up to (3.3 ± 0.5) × 10-3 cm2 V-1 s-1.