RESUMEN
Three prenylated flavonoids, dinklagins A, B and C identified, respectively, as (-)-6-(3,3-dimethylallyl)-7-hydroxy-6''', 6'''-dimethylchromeno-(4',3',2''',3''')-flavanone, (+)-5,4',5"xi-trihydroxy-6'',6''-dimethylchromano-(7,6,2'',3'')-flavone and (+)6-(2xi-hydroxy-3-methyl-3-butenyl)-5,7,4'-trihydroxyflavone were isolated from the twigs of Dorstenia dinklagei together with the known 6-prenylapigenin, 4-hydroxylonchocarpin, stipulin and 5,4'-dihydroxy-6'',6''-dimethylchromano-(7,6,2'',3'')-flavone. Their structures were determined on the basis of spectral data and by comparison with data reported in the literature and with authentic specimens for known compounds.
Asunto(s)
Flavanonas , Flavonoides/química , Flavonoides/aislamiento & purificación , Moraceae/química , Tallos de la Planta/química , Cromatografía , Espectroscopía de Resonancia Magnética , Estructura MolecularRESUMEN
Pycnanthus anglonensis is known for its medicinal value. This paper deals with a phytochemical investigation of this species, from which pycnangloside (1), a new cerebroside has been isolated. Its structure was determined by comprehensive analyses of its 1D and 2D NMR spectroscopic, and ESI mass spectrometric data. Four known compounds were also isolated and identified as biochanin A, formonentin, beta-sitosterol, and beta-sitosterol glucopyranoside.