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Kapok fiber (KF), with the characteristics of a natural hollow structure, light weight, and low density, can be used as acoustic and thermal insulation, buoyancy, adsorption, filling, and composite material. The flame-retardant treatment can expand the functionality and application of KF. In this work, the phosphorylation of KF using phytic acid (PA) in the presence of urea at a high temperature was used to enhance its flame retardancy. The phosphorylation reaction conditions were discussed, and the surface topography, thermal degradation, heat release, and combustion properties of phosphorylated KF were studied. The Fourier transform infrared spectroscopy and 31P solid-state nuclear magnetic resonance spectroscopy analyses confirmed the grafting of PA on cellulose by the formation of phosphate ester bonds. Due to the covalent binding of PA, phosphorylated KF exhibited good washing durability. The surface topography, Raman spectroscopy, thermogravimetric (TG), and microcalorimetry analyses revealed the excellent charring ability of phosphorylated KF. In the TG test in nitrogen, the char residue increased to 42.6% of phosphorylated KF from 8.3% of raw KF at 700 °C. In the vertical combustion, raw KF sheet was almost completely burned out within 30 s, while phosphorylated KF was very difficult to catch fire. In the microcalorimetry analysis, the heat release capacity and total heat release of phosphorylated KF decreased to 67 J/gâK and 3.9 kJ/g, respectively from 237 J/gâK and 18.1 kJ/g of raw KF. This work suggests that phosphorylated KF is an excellent flame-retardant material.
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Retardadores de Llama , Ácido Fítico , Fosforilación , Calor , Acústica , AdsorciónRESUMEN
The functionalization of microcrystalline cellulose (MCC) is an important strategy for broadening its application fields. In the present work, MCC was functionalized by phosphorylation reaction with phytic acid (PA) for enhanced flame retardancy. The conditions of phosphorylation reaction including PA concentration, MCC/PA weight ratio and temperature were discussed, and the thermal degradation, heat release and char-forming properties of the resulting PA modified MCC were studied by thermogravimetric analysis and pyrolysis combustion flow calorimetry. The PA modified MCC, which was prepared at 90 °C, 50%PA and 1:3 weight ratio of MCC to PA, exhibited early thermal dehydration with rapid char formation as well as low heat release capability. This work suggests a novel strategy for the phosphorylation of cellulose using PA and reveals that the PA phosphorylated MCC can act as a promising flame retardant material.
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Celulosa/química , Ácido Fítico/química , Celulosa/metabolismo , Retardadores de Llama , Calor , Estructura Molecular , Fosforilación , Espectroscopía Infrarroja por Transformada de Fourier/métodos , Temperatura , Textiles/análisis , Termogravimetría/métodosRESUMEN
In recent years, the serious influence of infectious diseases on public health and economy development has raised global awareness of the importance of medical textiles for preventing and curing injuries and diseases. The application of biomass molecules is a feasible and sustainable approach to design multipurpose medical materials. In this work, a novel cotton fiber with antibacterial, antioxidant, and drug delivery properties was prepared using gallic acid functionalized polylysine (GA-PL). GA-PL was synthesized by immobilizing GA onto PL using the carbodiimide coupling method. The content of GA immobilized onto PL was 117.9 mg/g. The as-prepared GA-PL was grafted onto oxidized cotton by means of the Schiff base reaction between the amino groups of GA-PL and the aldehyde groups of oxidized cotton. The content of GA-PL grafted onto cotton fiber was 205.1 mg/g. GA-PL grafted cotton fiber exhibited not only durable antibacterial and antioxidant activities but also good drug loading and releasing properties for acetylsalicylic acid. This work presents a novel, cleaner, and sustainable approach to prepare medical cotton fibers with bioactive and drug delivery properties.
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Fibra de Algodón , Ácido Gálico , Antibacterianos/farmacología , Antioxidantes/farmacología , PolilisinaRESUMEN
In the current pandemic scenario, sustainable green products particularly antiviral, antioxidant, and antibacterial in nature are gaining worldwide fame in almost every walk of life. Cassia obovata (C. obovata) has been valorized as a source of yellow natural dye for nylon dyeing. For the isolation of dye extracts and for surface tuning, nylon fabrics were treated with microwave rays up to 10 min. For getting new shades with good to excellent fastness characteristics, sustainable bio-mordants in comparison with chemical mordants have been used at 60 °C, 70 °C, and 80°C. It has been found that for getting effective colorant yield, acidic extract should be exposed to MW ray treatment up to 6 min, and for getting improved fastness rating, bio-mordants have given excellent color characteristics. Statistical optimization of dyeing variable shows that application of 40 mL of C. obovata acidic extract of RE of 6 pH containing 3 g/100 mL of salt when employed at 55 °C for 45 min has given excellent results onto irradiated nylon fabric (RNF). It is inferred that Cassia obovata has an excellent potential for coloration of surface-modified fabrics, where the application of low amount of bio-mordants under statistical optimized conditions has made process more ecological, economical, and sustainable.
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Cassia , Antraquinonas , Colorantes , TextilesRESUMEN
To prepare a novel highly photo-stable fluorescent chemosensor, curcumin was successfully immobilized to polyamidoamine dendrimer of zero (S1), first (S2) and second (S3) generations conjugated-UV absorber moieties. Chemical structure of synthesized chemosensors were well-analysed by FTIR, 1H-NMR, 13CNMR, elemental analysis, DSC and UV-vis techniques. Photo-physical characteristics and solvatochromism effect of three novel chemosensors in organic solvents with different dielectric constants ranged 2.21-37.78 were studied. The pH determination ability of S1, S2 and S3 in the range of 2-12 were also examined. Newly synthesized materials were employed for detection of different metal cations including Ag+, Ba2+, Cu2+, Ca2+, Cd2+, Fe3+, Hg2+, Ni2+, Pb2+ and Zn2+ and their possibility to apply as a cation chemosensor were evaluated. The results showed significant changes in their fluorescence intensity upon the different pHs and cations indicating their possibility to apply as a pH and metal cation chemosensor. Among the new chemosensors under study, S1 represented high sensitivity to pH in the range of 4-8 and high selectivity for Cu2+ over the other cations.
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Cotton has the shortcomings of having no antibacterial, antioxidant and ultraviolet (UV) protection properties, which are of great importance for health protection purposes. In the present study, grape seed extract (GSE) mainly composed of proanthocyanins (tannins) was employed to simultaneously import pale colors and the three aforementioned functions to cotton fabric. The tests on the application conditions of GSE showed that pH and GSE concentration had great impact on the color depth of cotton fabric, and the color hue of dyed fabric could be controlled in the absence of pH regulators due to the weakly acidic nature of GSE solution. The fabric dyed with 10%owf (on the weight of fabric) GSE exhibited an excellent inhibition effect towards Escherichia coli, whereas the one dyed with 20%owf GSE had high antioxidant activity of 97%. The fabric dyed with 5%owf GSE offered excellent UV protection. This study reveals that GSE can be used as a functional finishing agent for health protection in cotton textiles in addition to coloration capability.
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Fibra de Algodón , Extracto de Semillas de Uva/química , Proantocianidinas/química , Textiles , Antibacterianos/química , Antibacterianos/farmacología , Antioxidantes/química , Colorantes/farmacología , Escherichia coli/efectos de los fármacos , Gossypium , Concentración de Iones de Hidrógeno , Pruebas de Sensibilidad Microbiana , Taninos/química , Rayos UltravioletaRESUMEN
Polyamide fiber has the requirements for antioxidant and antibacterial properties when applied to produce functional textiles for heath care purposes. In this work, three natural flavonoids (baicalin, quercetin, and rutin) were used to simultaneously impart antioxidant and antibacterial functions to polyamide fiber using an adsorption technology. The relations of the chemical structures of flavonoids with their adsorption capability, adsorption mechanisms, and antioxidant and antibacterial activities were discussed. The Langmuir-Nernst adsorption model fitted the adsorption isotherms of the three flavonoids well. The adsorption kinetics of the three flavonoids conformed to the pseudo second-order kinetic model. Quercetin exhibited the highest affinity and adsorption capability, and imparted the highest antioxidant and antibacterial activities to polyamide fiber; and moreover, its antioxidant and antibacterial functions had good washing durability. This study demonstrates that the treatment using natural flavonoids is an effective way to exhance the health care functions of polyamide fiber.
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Natural bioactive compounds have received increasing attention in the functional modification of textiles. In this work, tannic acid was used to impart antibacterial and antioxidant functions to silk using an adsorption technique, and the adsorption properties of tannic acid on silk were studied. The adsorption quantity of tannic acid on silk increased with decreasing pH in the range of 3-7. The rates of the uptake of tannic acid by silk were well correlated to the pseudo-second-order kinetic model, and the calculated activation energy of adsorption was 93.49 kJ/mol. The equilibrium adsorption isotherms followed the Langmuir model. The adsorption rate and isotherm studies demonstrated that the chemical adsorption of tannic acid on silk occurred through the ion-ion interaction between tannic acid and silk. Tannic acid displayed good building-up properties on silk. The silk fabric treated with 0.5% tannic acid (relative to fabric weight) exhibited excellent and durable antibacterial properties. Moreover, the silk fabrics treated with 2% and 5% tannic acid had good and durable antioxidant properties. The treatment by tannic acid had less impact on the whiteness of the silk fabric. In summary, tannic acid can be used as a functional agent for preparing healthy and hygienic silk materials.
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Recently, there has been an increasing tendency towards the functionalization of silk using silver nanoparticles (AgNPs) to inhibit bacterial multiplication and disease spread. Considering environmental factors and sustainable development, the preparation of AgNPs using natural extracts is becoming a research hotspot. This study aims at fabricating colored and bioactive silk fabric using AgNPs synthesized by two representative flavonoids (quercetin and rutin). The effects of pH, temperature, and flavonoid concentration on the yield and particle size of AgNPs were studied. The color features and functionalities of the AgNPs-treated silk were also evaluated. The results showed that the AgNPs synthesized by quercetin were generated faster but displayed poorer size uniformity than those prepared by rutin. The as-prepared AgNPs showed good stability. The AgNPs prepared by rutin displayed a more uniform distribution on silk than those synthesized by quercetin. The antibacterial activity of AgNPs-treated silk remained over 90% against E. coli and S. aureus even after 30 washing cycles. The antioxidant activity of the treated silk gradually decreased during washing. The present research proposes a facile and eco-friendly method for the preparation of AgNPs-coated silk material using flavonoids, which can serve as hygiene-related and medical textile materials.
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In this work, the Maillard reaction of polyglutamic acid (PGA) and glucose (Glc) was studied, and its functional, polymeric, and colored products were used to dye silk fiber with the aim of imparting bioactivities to silk. The UVâ»Vis spectroscopic analysis, which was employed to monitor the reaction, revealed the rapid formation of yellowish-brown products at pH 12 and 90 °C, and the great impact of glucose content on the quantity of the products. The FT-IR analysis validated the formation of melanoidin colorants. The silk fiber dyed with the PGA/Glc reaction products at pH 3 displayed a yellowish-brown color, and had very good wash and rub fastness, but poor light fastness. The incorporation of the UV-absorbing moiety into the PGA/Glc reaction products enhanced their light stability. The SEM analysis revealed that the dyed silk fiber was covered by polymeric substances. The dyed silk exhibited durable antibacterial activity against Staphylococcus aureus and Escherichia coli, and good antioxidant activity. This research expands the application field of the Maillard reaction and provides a novel and eco-friendly approach to prepare the colored and bioactive silk materials.
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Recently, there is a growing trend towards the functionalization of silk through nanotechnology for the prevention of fiber damage from microbial attack and the enhancement of hygienic aspects. Considering sustainable development and environmental protection, the eco-friendly fabrication of silver nanoparticles (AgNPs)-modified silk using natural extracts has currently become a hot research area. This study presents a facile strategy for the fabrication of colorful and multifunctional silk fabric using biogenic AgNPs prepared by honeysuckle extract as natural reductant and stabilizing agents. The influences of pH and reactant concentrations on the AgNPs synthesis were investigated. The color characteristics and functionalities of AgNPs treated silk were evaluated. The results revealed that the particle size of AgNPs decreased with increasing pH. The diameter of AgNPs decreased with increasing amount of honeysuckle extract and reducing amount of silver nitrate. The transmission electron microscopy image showed that the AgNPs were spherical in shape with a narrow size distribution. The treated silk showed excellent antibacterial activities against E. coli and S. aureus, and certain antioxidant activity. Both of the antibacterial and antioxidant activities were well maintained even after 30 washing cycles. This work provides a sustainable and eco-friendly approach to the fabrication of AgNPs coated silk for colorful and long-term multifunctional textiles using honeysuckle extract.
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Antibacterianos/química , Antioxidantes/química , Lonicera/química , Nanopartículas del Metal/química , Seda/química , Antibacterianos/farmacología , Escherichia coli/efectos de los fármacos , Tecnología Química Verde , Concentración de Iones de Hidrógeno , Lonicera/metabolismo , Pruebas de Sensibilidad Microbiana , Microscopía Electrónica de Transmisión , Tamaño de la Partícula , Extractos Vegetales/química , Plata/química , Staphylococcus aureus/efectos de los fármacos , Difracción de Rayos XRESUMEN
Keratin from a variety of sources is one of the most abundant biopolymers. In livestock and textile industries, a large amount of rabbit hair waste is produced every year, and therefore it is of great significance to extract keratin from waste rabbit hair in terms of the treatment and utilization of wastes. In this study, a novel, eco-friendly and benign choline chloride/oxalic acid deep eutectic solvent at a molar ratio of 1:2 was applied to dissolve waste rabbit hair, and after dissolution keratin was separated by dialysis, filtration, and freeze-drying. The dissolution temperature effect was discussed, and the resulting keratin powder was characterized by X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy, protein electrophoresis, thermogravimetry and differential scanning calorimetry, and amino acid analysis. During the dissolution process, the α-helix structure of rabbit hair was deconstructed, and the disulfide bond linkages were broken. The solubility of rabbit hair was significantly enhanced by increasing dissolution temperature, and reached 88% at 120 °C. The keratin produced by dissolving at 120 °C displayed flaky powders after freeze-drying, and had a molecular weight ranging from 3.8 to 5.8 kDa with a high proportion of serine, glutamic acid, cysteine, leucine, and arginine. Such features of molecular weight and amino acid distribution provide more choices for the diverse applications of keratin materials.
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The application of biodegradable chitosan fiber for healthy and hygienic textiles is limited due to its poor acid resistance in wet processing and poor antioxidant activity. In order to prepare chitosan fiber with good acid resistance and high antioxidant activity, chitosan fiber was first crosslinked by a water-soluble aziridine crosslinker, and then dyed with natural lac dye consisting of polyphenolic anthraquinone compounds. The main application conditions and crosslinking mechanism of the aziridine crosslinker, the adsorption mechanism and building-up property of lac dye on the crosslinked fiber, and the effects of crosslinking and dyeing on the antioxidant and antibacterial activities of chitosan fiber were studied. The crosslinked fiber exhibited greatly reduced weight loss in acidic solution, and possessed excellent acid resistance. Lac dye displayed a very high adsorption capability on the crosslinked fiber and a high utilization rate under weakly acidic medium. The Langmuirâ»Nernst isotherm was the best model to describe the adsorption behavior of lac dye, and Langmuir adsorption had great contribution to total adsorption. Lac dyeing imparted good antioxidant activity to chitosan fiber. Crosslinking and dyeing had no impact on the good inherent antibacterial activity of chitosan fiber.
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There has been a phenomenal increase in the research and development of new health and hygiene-related textile products. This work reports a novel approach to develop antibacterial, antioxidant and UV-protective silk using an adsorption technique of baicalin (a bioactive ingredient from the root of Scutellaria baicalensis Georgi). Baicalin displayed high adsorption capability at pH2.75, contributing to the sufficient functionalities on silk. The equilibrium adsorption research showed that the Langmuir isotherm was able to describe the behavior of baicalin, indicating the electrostatic interactions between the ionized carboxyl groups in baicalin and the positively charged amino groups in silk. The treated silk with 2% owf (on the weight of fiber) baicalin exhibited excellent antioxidant activity, high antibacterial activities against Escherichia coli and Staphylococcus aureus, and very good ultraviolet protection ability comparable to that of the commercial benzotriazole ultraviolet absorber. The baicalin treatment had no obvious impact on the functional groups, crystal structure and surface morphology of silk. The functionalities of the treated silk obviously declined after first laundering cycle and slowly decreased in the following washing cycles. Encouraging results demonstrate that the baicalin-functionalized silk is a promising material for protective clothing and medical textiles.
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Materiales Biocompatibles/farmacología , Flavonoides/farmacología , Extractos Vegetales/farmacología , Scutellaria baicalensis/química , Rayos Ultravioleta , Adsorción , Animales , Antibacterianos/farmacología , Antioxidantes/farmacología , Electricidad , Escherichia coli/efectos de los fármacos , Flavonoides/química , Concentración de Iones de Hidrógeno , Pruebas de Sensibilidad Microbiana , Seda/química , Seda/ultraestructura , Espectrofotometría Ultravioleta , Espectroscopía Infrarroja por Transformada de Fourier , Staphylococcus aureus/efectos de los fármacos , Estrés Mecánico , Temperatura , Difracción de Rayos XRESUMEN
Bio-based phytic acid (PA) as a nontoxic naturally occurring compound is a promising prospect for flame-retardant (FR) modifications to polymers. In this work, PA was applied to wool fabric using an exhaustion technique, and the adsorption and FR properties of PA on wool fabric were studied. The flame retardancy of the treated wool fabrics depended greatly on the adsorption quantity of PA, which was related to the pH of treatment solution, immersing temperature and initial PA concentration. The Langmuir adsorption of PA took place due to electrostatic interactions between PA and wool fiber. The limiting oxygen index, vertical burning and pyrolysis combustion flow calorimetry tests revealed that the treated wool fabrics exhibited good flame retardancy. The measurements of the phosphorus content of the burned fabric residues and thermogravimetric analyses suggested that a significant condensed-phase FR action was applicable to the PA treated fabrics. PA treatment was found to have little adverse effect on the whiteness and mechanical performance of wool. Additionally, the washing resistance of the FR fabrics should be further improved.