Manganese doped two-dimensional zinc ferrite thin films as chemiresistive trimethylamine gas sensors.

Trimethylamine (TMA) is highly toxic and can have lethal effects on living organisms. Detecting the presence of TMA in air is very important because, if the TMA level exceeds the OSHA (Occupational Safety and Health Administration) limit, it may harm the environment and endanger human life. Doping is an appropriate flexible way to change the electrical structures of metal oxide semiconductors (MOSs) and improve their ability to detect toxic gases. In this work, Mn-doped zinc ferrite thin film nanorods with agglomerated morphology were fabricated by a spray pyrolysis technique. For the first time, a comprehensive investigation was done on the gas sensing capabilities of Mn-doped ZnFe2O4 thin films. The findings showed that ZFM1 had the best gas sensing characteristics, with high sensitivity (S = 6.24), good selectivity, and quick recovery, towards 10 ppm TMA at ambient temperature. The alternate Mn-ZF sites are responsible for the rapid recovery because they can significantly increase the concentration of oxygen vacancies in the ZF crystal. 0.1 Mn doped ZnFe2O4 (ZFM1) thin film exhibits greatly enhanced gas sensing properties towards TMA, because of its high surface-to-volume ratio and rough surface with a small nanorod structure. The sensor's response to 10 ppm TMA was measured 13 weeks later for stability testing. The stability test results show that the coated ZFM1 film works well as a TMA gas sensor. This work shows that ZF thin films are effective in detecting TMA in the atmosphere.

Co-deposition of MoS2films by reactive sputtering and formation of tree-like structures.

Transition metal dichalcogenides (TMDCs) are versatile layered materials with potential applications ranging from optoelectronic devices to water splitting. Top-down fabrication methods such as exfoliation are not practical for a large-scale production of high-quality devices: a bottom-up approach such as sputtering, a low-temperature deposition method, is more suitable. However, due to its anisotropic nature, the growth mechanism of molybdenum disulfide (MoS2) via sputtering is complex and remains to be investigated in detail. In this paper, we study the growth of MoS2 films co-deposited by using a sulfur (S) hot-lip cell and a molybdenum (Mo) sputtering target via reactive sputtering. The impact of S partial pressure on the structure and morphology of MoS2films was systematically characterized, and it was observed that the growth is dominated by vertically-oriented sheets with horizontal branches, resulting in a tree-like structure. The growth front of the structures is ascribed to the anisotropic incorporation of adatoms with regards to the orientation of MoS2.

Dual Shield: Bifurcated Coating Analysis of Multilayered WO3/BiVO4/TiO2/NiOOH Photoanodes for Sustainable Solar-to-Hydrogen Generation from Challenging Waters.

The heterostructure WO3/BiVO4-based photoanodes have garnered significant interest for photoelectrochemical (PEC) solar-driven water splitting to produce hydrogen. However, challenges such as inadequate charge separation and photocorrosion significantly hinder their performance, limiting overall solar-to-hydrogen conversion efficiency. The incorporation of cocatalysts has shown promise in improving charge separation at the photoanode, yet mitigating photocorrosion remains a formidable challenge. Amorphous metal oxide-based passivation layers offer a potential solution to safeguard semiconductor catalysts. We examine the structural, surface morphological, and optical properties of two-step-integrated sputter and spray-coated TiO2 thin films and their integration onto WO3/BiVO4, both with and without NiOOH cocatalyst deposition. The J-V experiments reveal that the NiOOH cocatalyst enhances the photocurrent density of the WO3/BiVO4 photoanode in water splitting reactions from 2.81 to 3.87 mA/cm2. However, during prolonged operation, the photocurrent density degrades by 52%. In contrast, integrated sputter and spray-coated TiO2 passivation layer-coated WO3/BiVO4/NiOOH samples demonstrate a ∼88% enhancement in photocurrent density (5.3 mA/cm2) with minimal degradation, emphasizing the importance of a strategic coating protocol to sustain photocurrent generation. We further explore the feasibility of using natural mine wastewater as an electrolyte feedstock in PEC generation. Two-compartment PEC cells, utilizing both fresh water and metal mine wastewater feedstocks exhibit 66.6 and 74.2 µmol/h cm2 hydrogen generation, respectively. Intriguingly, the recovery of zinc (Zn2+) heavy metals on the cathode surface in the mine wastewater electrolyte is confirmed through surface morphology and elemental analysis. This work underscores the significance of passivation layer and cocatalyst coating methodologies in a sequential order to enhance charge separation and protect the photoanode from photocorrosion, contributing to sustainable hydrogen generation. Additionally, it suggests the potential of utilizing wastewater in electrolyzers as an alternative to freshwater resources.

Incompatibility of Pure SnO2 Thin Films for Room-Temperature Gas Sensing Application.

Despite the high sensitivity and selectivity, the high operating temperature required for activation energy of tin oxide (SnO2) still stands as a drawback for SnO2 based gas sensors. In this work, the SnO2 thin films were deposited through spray pyrolysis and were subjected to gas sensing at 27 °C (room temperature) towards different gases. The films exhibited a consistently low response of approximately 1 when tested to various VOCs. The type, concentration, and mobility of charge carriers were determined from the Hall measurements. The high carrier concentration accompanied by poor mobility and grain boundary scattering is supposed to hinder its performance at room temperature. The obtained film had spherical morphology, which lead to grain boundary scatterings and decreased the mobility of carriers.

A Novel Approach for Designing a Sub-Bandgap in CuGa(S,Te)2 Thin Films Assisted with Numerical Simulation of Solar Cell Devices for Photovoltaic Application.

As a well-explored chalcopyrite material, copper gallium sulfide CGS has been considered a potential material for solar cell absorber layers. However, its photovoltaic attributes still require to be improved. In this research, a novel chalcopyrite material, copper gallium sulfide telluride CGST, has been deposited and verified as a thin film absorber layer to fabricate high-efficiency solar cells by experimental testing and numerical simulations. The results display the intermediate band formation in CGST with incorporation of Fe ions. Electrical studies showed enhancement in mobility from 1.181 to 1.473 cm2 V-1 s-1 and conductivity from 2.182 to 5.952 S cm-1 for pure and 0.08 Fe-substituted thin films. The I-V curves display the photoresponse and ohmic nature of the deposited thin films, and the maximum photoresponsivity (0.109 A W-1) was observed for 0.08 Fe-substituted films. Theoretical simulation of the prepared solar cells was carried out using SCAPS-1D software, and the obtained efficiency displayed an increasing trend from 6.14 to 11.07% as the Fe concentration increased from 0.0 to 0.08. This variation in efficiency is attributed to the decrease in bandgap (2.51-1.94 eV) and the formation of an intermediate band in CGST with Fe substitution, which is evidenced in UV-vis spectroscopy. The above revealed results open the way to 0.08 Fe-substituted CGST as a promising candidate as a thin film absorber layer in solar photovoltaic technology.

Heme protein identified from scaly-foot gastropod can synthesize pyrite (FeS2) nanoparticles.

The scaly-foot gastropod (Chrysomallon squamiferum), which lives in the deep-sea zone of oceans around thermal vents, has a black shell and scales on the foot. Both the black shell and scales contain iron sulfide minerals such as greigite (Fe3S4) and pyrite (FeS2). Although pyrite nanoparticles can be used as materials for solar panels, it is difficult to synthesize stable and spherical nanoparticles in vitro. In this study, we extracted organic molecules that interact with nano-pyrite from the shell of the scaly-foot gastropod to develop a low-cost, eco-friendly method for pyrite nanoparticles synthesis. Myoglobin (csMG), a heme protein, was identified in the iron sulfide layer of the shell. We purified recombinant csMG (r-csMG) and demonstrated that r-csMG helped in the conversion of ferric ions, sulfide ions and sulfur into spherical shaped pyrite nanoparticles at 80°C. To reduce the effort and cost of production, we showed that commercially available myoglobin from Equus caballus (ecMG) also induced the in vitro synthesis of pyrite nanoparticles. Using structure-function experiments with digested peptides, we highlighted that the amino acid sequence of r-csMG peptides controlled the spherical shape of the nanoparticle while the hemin molecules, which the peptides interacted with, maintained the size of nanoparticles. Synthesized pyrite nanoparticles exhibited strong photoluminescence in the visible wavelength region, suggesting its potential application as a photovoltaic solar cell material. These results suggest that materials for solar cells can be produced at low cost and energy under eco-friendly conditions. STATEMENT OF SIGNIFICANCE: Pyrite is a highly promising material for photovoltaic devices because of its excellent optical, electrical, magnetic, and transport properties and high optical absorption coefficient. Almost all current pyrite synthesis methods use organic solvents at high temperature and pressure under reducing conditions. Synthesized pyrite nanoparticles are unstable and are difficult to use in devices. The scaly-foot gastropod can synthesize pyrite nanoparticles in vivo, meaning that pyrite nanoparticles can be generated in an aqueous environment at low temperature. In this study, we demonstrated the synthesis of pyrite nanoparticles using a heme protein identified in the iron sulfide layer of the scaly-foot gastropod shell. These results exemplify how natural products in organisms can inspire the innovation of new technology.