RESUMEN
The melting behaviour of metal-organic frameworks (MOFs) has aroused significant research interest in the areas of materials science, condensed matter physics and chemical engineering. This work first introduces a novel method to fabricate a bimetallic MOF glass, through melt-quenching of the cobalt-based zeolitic imidazolate framework (ZIF) [ZIF-62(Co)] with an adsorbed ferric coordination complex. The high-temperature chemically reactive ZIF-62(Co) liquid facilitates the formation of coordinative bonds between Fe and imidazolate ligands, incorporating Fe nodes into the framework after quenching. The resultant Co-Fe bimetallic MOF glass therefore shows a significantly enhanced oxygen evolution reaction performance. The novel bimetallic MOF glass, when combined with the facile and scalable mechanochemical synthesis technique for both discrete powders and surface coatings on flexible substrates, enables significant opportunities for catalytic device assembly.
RESUMEN
OBJECTIVE: To study the chemical constituents of the ethyl ether extract of the Leptopus chineseis. METHODS: The chemical constituents were isolated by means of chromatography and identified by spectra data and physicochemical characters. RESULTS: Three compounds were isolated and identified as friedelane-2alpha, 3beta-diols (1), betulinic acid (2) and 3beta-O-trans-coumaroylbetulinic acid (3). CONCLUSION: The compounds are isolated from Leptopus chineseis for the first time.