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ACS Appl Mater Interfaces ; 15(18): 22532-22542, 2023 May 10.
Artículo en Inglés | MEDLINE | ID: mdl-37097086

RESUMEN

Hyperspectral infrared (IR) images contain a large amount of highly spatially resolved information about the chemical composition of a sample. However, the analysis of hyperspectral IR imaging data for complex heterogeneous systems can be challenging because of the spectroscopic and spatial complexity of the data. We implement a deep generative modeling approach using a ß-variational autoencoder to learn disentangled representations of the generative factors of variance in a data set of cross-linked polyethylene (PEX-a) pipe. We identify three distinct physicochemical factors of aging and degradation learned by the model and apply the trained model to high-resolution hyperspectral IR images of cross-sectional slices of unused virgin, used in-service, and cracked PEX-a pipe. By mapping the learned representations of aging and degradation to the IR images, we extract detailed information on the physicochemical changes that occur during aging, degradation, and cracking in PEX-a pipe. This study shows how representation learning by deep generative modeling can significantly enhance the analysis of high-resolution IR images of complex heterogeneous samples.

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