1.
J Org Chem
; 80(18): 9314-20, 2015 Sep 18.
Artículo
en Inglés
| MEDLINE
| ID: mdl-26300494
RESUMEN
A transition-metal-free synthetic method of various ynones via decarboxylative alkynylation of α-keto acids is described. The reaction is carried out under mild conditions and exhibits remarkable tolerance of functional groups. The mechanism of a radical process is proposed in the reaction.