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2D transition metal dichalcogenides (TMDs) have garnered significant interest as cathode materials for aqueous zinc-ion batteries (AZIBs) due to their open transport channels and abundant Zn2+ intercalation sites. However, unmodified TMDs exhibit low electrochemical activity and poor kinetics owing to the high binding energy and large hydration radius of divalent Zn2+. To overcome these limitations, an interlayer engineering strategy is proposed where K+ is preintercalated into K-MoS2 nanosheets, which then undergo in situ growth on carbon nanospheres (denoted as K-MoS2@C nanoflowers). This strategy stimulates in-plane redox-active sites, expands the interlayer spacing (from 6.16 to 9.42 Å), and induces the formation of abundant MoS2 1T-phase. The K-MoS2@C cathode demonstrates excellent redox activity and fast kinetics, attributed to the potassium ions acting as a structural "stabilizer" and an electrostatic interaction "shield," accelerating charge transfer, promoting Zn2+ diffusion, and ensuring structural stability. Meanwhile, the carbon nanospheres serve as a 3D conductive network for Zn2+ and enhance the cathode's hydrophilicity. More significantly, the outstanding electrochemical performance of K-MoS2@C, along with its superior biocompatibility and degradability of its related components, can enable an implantable energy supply, providing novel opportunities for the application of transient electronics.
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The practical application of Li-S batteries is still severely restricted by poor cyclic performance caused by the intrinsic polysulfides shuttle effect, which is even more severe under the high-temperature condition owing to the inevitable increase of polysulfides' solubility and diffusion rate. Herein, tungsten-doped vanadium dioxide (W-VO2) micro-flowers are employed with first-order metal-insulator phase transition (MIT) property as a robust and multifunctional modification layer to hamper the shuttle effect and simultaneously improve the thermotolerance of the common separator. Tungsten doping significantly reduces the transition temperature from 68 to 35 °C of vanadium dioxide, which renders the W-VO2 easier to turn from the insulating monoclinic phase into the metallic rutile phase. The systematic experiments and theoretical analysis demonstrate that the temperature-induced in-suit MIT property endows the W-VO2 catalyst with strong chemisorption against polysulfides, low energy barrier for liquid-to-solid conversion, and outstanding diffusion kinetics of Li-ion under high temperatures. Benefiting from these advantages, the Li-S batteries with W-VO2 modified separator exhibit significantly improved rate and long-term cyclic performance under 50 °C. Remarkably, even at an elevated temperature (80 °C), they still exhibit superior electrochemical performance. This work opens a rewarding avenue to use phase-changing materials for high-temperature Li-S batteries.
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Topological materials carrying topological surface states (TSSs) have extraordinary carrier mobility and robustness, which provide a new platform for searching for efficient hydrogen evolution reaction (HER) electrocatalysts. However, the majority of these TSSs originate from the sp band of topological quantum catalysts rather than the d band. Here, based on the density functional theory calculation, it is reported a topological semimetal Pd3Sn carrying TSSs mainly derived from d orbital and proposed that optimizing surface state electrons of Pd3Sn by introduction heteroatoms (Ni) can promote hybridization between hydrogen atoms and electrons, thereby reducing the Gibbs free energy (ΔGH) of adsorbed hydrogen and improving its HER performance. Moreover, this is well verified by electrocatalytic experiment results, the Ni-doped Pd3Sn (Ni0.1Pd2.9Sn) show much lower overpotential (-29 mV vs RHE) and Tafel slope (17 mV dec-1) than Pd3Sn (-39 mV vs RHE, 25 mV dec-1) at a current density of 10 mA cm-2. Significantly, the Ni0.1Pd2.9Sn nanoparticles exhibit excellent stability for HER. The electrocatalytic activity of Ni0.1Pd2.9Sn nanoparticles is superior to that of commercial Pt. This work provides an accurate guide for manipulating surface state electrons to improve the HER performance of catalysts.
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Polysulfide shuttle effect and sluggish sulfur reaction kinetics severely impede the cycling stability and sulfur utilization of lithium-sulfur (Li-S) batteries. Modulating d-band electronic structures of molybdenum disulfide electrocatalysts via p/n doping is promising to boost polysulfide conversion and suppress polysulfide migration in lithium-sulfur batteries. Herein, p-type V-doped MoS2 (V-MoS2 ) and n-type Mn-doped MoS2 (Mn-MoS2 ) catalysts are well-designed. Experimental results and theoretical analyses reveal that both of them significantly increase the binding energy of polysulfides on the catalysts' surface and accelerate the sluggish conversion kinetics of sulfur species. Particularly, the p-type V-MoS2 catalyst exhibits a more obvious bidirectional catalytic effect. Electronic structure analysis further demonstrates that the superior anchoring and electrocatalytic activities are originated from the upward shift of the d-band center and the optimized electronic structure induced by duplex metal coupling. As a result, the Li-S batteries with V-MoS2 modified separator exhibit a high initial capacity of 1607.2 mAh g-1 at 0.2 C and excellent rate and cycling performance. Moreover, even at a high sulfur loading of 6.84 mg cm-2 , a favorable initial areal capacity of 8.98 mAh cm-2 is achieved at 0.1 C. This work may bring widespread attention to atomic engineering in catalyst design for high-performance Li-S batteries.
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Biodegradable implantable devices are of growing interest in biosensors and bioelectronics. One of the key unresolved challenges is the availability of power supply. To enable biodegradable energy-storage devices, herein, 2D heterostructured MoO3 -MoS2 nanosheet arrays are synthesized on water-soluble Mo foil, showing a high areal capacitance of 164.38 mF cm-2 (at 0.5 mA cm-2 ). Employing the MoO3 -MoS2 composite as electrodes of a symmetric supercapacitor, an asymmetric Zn-ion hybrid supercapacitor, and an Mg primary battery are demonstrated. Benefiting from the advantages of MoO3 -MoS2 heterostructure, the Zn-ion hybrid supercapacitors deliver a high areal capacitance (181.86 mF cm-2 at 0.5 mA cm-2 ) and energy density (30.56 µWh cm-2 ), and the Mg primary batteries provide a stable high output voltage (≈1.6 V) and a long working life in air/liquid environment. All of the used materials exhibit desirable biocompatibility, and these fabricated devices are also fully biodegradable. Demonstration experiments display their potential applications as biodegradable power sources for various electronic devices.
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Metal sulfides are often used as cathode materials for lithium-ion batteries (LIBs) owing to their high theoretical specific capacity; however, excessively fast capacity decay during charging/discharging and rapid shedding during cycling limits their practical application in batteries. In this study, we proposed a strategy using plasma treatment combined with the solvothermal method to prepare cobalt sulfide (Co1-xS)-carbon nanofibers (CNFs) composite. The plasma treatment could introduce oxygen-containing polar groups and defects, which could improve the hydrophilicity of the CNFs for the growth of the Co1-xS, thereby increasing the specific capacity of the composite electrode. The results show that the composite electrode present a high discharge specific capacity (839 mAh g-1at a current density of 100 mA g-1) and good cycle stability (the capacity retention rate almost 100% at 2000 mA g-1after 500 cycles), attributing to the high conductivity of the CNFs. This study proves the application of plasma treatment and simple vulcanization method in high-performance LIBs.
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Multivalent ion hybrid supercapacitors have been developed as the novel electrochemical energy storage systems due to their combined merits of high energy density and high power density. Nevertheless, there are still some challenges due to the limited understanding of the electrochemical behaviors of multivalent ions in the electrode materials, which greatly hinders the large scale applications of its based hybrid supercapacitors. Herein, the long-term electrochemical behaviors of MnO2 -based electrode in the divalent Mg2+ ions electrolyte are systematically studied and linked with the morphological and electronic evolution of MnO2 by cycling at different potential windows (spanning to 1.2 V). It reveals that the different potential windows result in the different electrochemical behaviors, which can be divided into two ranges (below and above -0.2 V). And, the electrode cycled at a potential window of 0-1.2 V delivers the highest capacitance of 967 F g-1 at a scan rate of 10 mV s-1 , in which the MnO2 is transformed into a uniformly distributed and nonagglomerated nanoflake morphology promoting the intercalation and deintercalation of Mg2+ ions. This study will enrich the understanding of the charge storage mechanism of multivalent ions and provide significant guidance on the performance improvement of the hybrid supercapacitors.
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Considering size effect and functionalized pore interaction dyes guests and MOFs hosts, 4-aminonaphthalimide was successfully introduced into the pore of LnMOF for the first time and constructed 4-ANAâLnMOF luminescent composites with excellent dual-emission properties. A series of temperature-dependent luminescence test results show that 4-ANAâGd4L3 can be used as a reversible ratiometric luminescent temperature sensor. The functional construction method provides ideas for the development of clear purpose novel dual-emission dyeâLnMOF ratiometric luminescent sensors.
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It was demonstrated that suitable interfaces between two materials can enhance the separation of photogenerated carriers. In this study, ZrO2/ZnO interfaces with type I structure were designed and prepared by the electrospinning technique. The obtained ZrO2/ZnO:Eu3+ (ZZOE) composites are highly porous in the form of nanobelts with width of 600-700 nm, comprising ZnO and ZrO2 nanocrystals, and the Eu doping can hinder the t-m phase transition of ZrO2. By tuning the annealing temperature, the inner stress and defects can be well controlled to improve the photoluminescence (PL) of the ZZOE porous nanobelts. Macro- and micro-PL spectra indicated that the body oxygen vacancies benefit the PL from Eu3+ ions, whereas the surficial ones do not. The optimal parameters for the preparation of ZZOE porous nanobelts were also investigated. Finally, a charge transfer mechanism was proposed to illuminate the PLs from the ZZOE porous nanobelts.
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Vertically stacked van der Waals heterostructures composed of compositionally different two-dimensional atomic layers give rise to interesting properties due to substantial interactions between the layers. However, these interactions can be easily obscured by the twisting of atomic layers or cross-contamination introduced by transfer processes, rendering their experimental demonstration challenging. Here, we explore the electronic structure and its strain dependence of stacked MoSe2/WSe2 heterostructures directly synthesized by chemical vapor deposition, which unambiguously reveal strong electronic coupling between the atomic layers. The direct and indirect band gaps (1.48 and 1.28 eV) of the heterostructures are measured to be lower than the band gaps of individual MoSe2 (1.50 eV) and WSe2 (1.60 eV) layers. Photoluminescence measurements further show that both the direct and indirect band gaps undergo redshifts with applied tensile strain to the heterostructures, with the change of the indirect gap being particularly more sensitive to strain. This demonstration of strain engineering in van der Waals heterostructures opens a new route toward fabricating flexible electronics.
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Nanostructured metal sulfides with excellent electrochemical activity and electrical conductivity are particularly promising for applications in high-performance energy storage devices. Here, we report on the facile synthesis of nanostructured CuS networks composed of interconnected nanoparticles as novel battery-type materials for asymmetric supercapacitors. We find that the CuS networks exhibit a high specific capacity of 49.8 mA g(-1) at a current density of 1 A g(-1), good rate capability and cycle stability. The superior performance could be attributed to the interconnected nanoparticles of CuS networks, which can facilitate electrolyte diffusion and provide fast electron pathways. Furthermore, an aqueous asymmetric supercapacitor has been assembled by using the CuS networks as the positive electrode and activated carbon as the negative electrode. The assembled device can work at a high operating voltage of 1.6 V and show a maximum energy density of 17.7 W h kg(-1) at a power density of 504 W kg(-1). This study indicates that the CuS networks have great potential for supercapacitor applications.
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An alternative routine is presented by constructing a novel architecture, conductive metal/transition oxide (Co@Co3O4) core-shell three-dimensional nano-network (3DN) by surface oxidating Co 3DN in situ, for high-performance electrochemical capacitors. It is found that the Co@Co3O4 core-shell 3DN consists of petal-like nanosheets with thickness of <10 nm interconnected forming a 3D porous nanostructure, which preserves the original morphology of Co 3DN well. X-ray photoelectron spectroscopy by polishing the specimen layer by layer reveals that the Co@Co3O4 nano-network is core-shell-like structure. In the application of electrochemical capacitors, the electrodes exhibit a high specific capacitance of 1049 F g(-1) at scan rate of 2 mV/s with capacitance retention of ~52.05% (546 F g(-1) at scan rate of 100 mV) and relative high areal mass density of 850 F g(-1) at areal mass of 3.52 mg/cm(2). It is believed that the good electrochemical behaviors mainly originate from its extremely high specific surface area and underneath core-Co "conductive network". The high specific surface area enables more electroactive sites for efficient Faradaic redox reactions and thus enhances ion and electron diffusion. The underneath core-Co "conductive network" enables an ultrafast electron transport.
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Porous Co3O4 nanonetworks (NNWs), converted from precursor CoOOH nanosheets, have been synthesized via a controllable chemical reaction route followed by calcination at 400 °C in air. The morphologies and microstructures of the precursor nanosheets and the final products were characterized by high-resolution transmission electron microscopy and X-ray diffraction, respectively. The growth mechanism of CoOOH nanosheets and the structural transformation processes of NNWs were investigated in detail. Significantly, the porous Co3O4 NNW based sensor showed an enhanced response to toluene gas at low concentration, which was mainly due to its porous neck-connected networks.
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Transition metal dichalcogenides (TMDs) have been widely studied as catalysts for lithium-sulfur batteries due to their good catalytic properties. However, their poor electronic conductivity leads to slow sulfur reduction reactions. Herein, a simple Zn2+ intercalation strategy was proposed to promote the phase transition from semiconducting 2H-phase to metallic 1T-phase of MoS2. Furthermore, the Zn2+ between layers can expand the interlayer spacing of MoS2 and serve as a charge transfer bridge to promote longitudinal transport along the c-axis of electrons. DFT calculations further prove that Zn-MoS2 possesses better charge transfer ability and stronger adsorption capacity. At the same time, Zn-MoS2 exhibits excellent redox electrocatalytic performance for the conversion and decomposition of polysulfides. As expected, the lithium-sulfur battery using Zn0.12MoS2-carbon nanofibers (CNFs) as the cathode has high specific capacity (1325 mAh g-1 at 0.1 C), excellent rate performance (698 mAh g-1 at 3 C), and outstanding cycle performance (it remains 604 mAh g-1 after 700 cycles with a decay rate of 0.045% per cycle). This study provides valuable insights for improving electrocatalytic performance of lithium-sulfur batteries.
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Layered double hydroxide (LDH) materials, despite their high theoretical capacity, exhibit significant performance degradation with increasing load due to their low conductivity. Simultaneously achieving both high capacity and high rate performance is challenging. Herein, we fabricated vertically aligned CuO nanowires in situ on the copper foam (CF) substrate by alkali-etching combined with the annealing process. Using this as a skeleton, electrochemical deposition technology was used to grow the amorphous α-phase CoNi-LDH nanosheets on its surface. Thanks to the high specific surface area of the CuO skeleton, ultrahigh loading (Ì16.36 mg cm-2) was obtained in the fabricated CF/CuO@CoNi-LDH electrode with the cactus-like hierarchical structure, which enhanced the charge transfer and ion diffusion dynamics. The CF/CuO@CoNi-LDH electrode achieved a good combination of high areal capacitance (33.5 F cm-2) and high rate performance (61% capacitance retention as the current density increases 50 times). The assembled asymmetric supercapacitor device demonstrated a maximum potential window of 0-1.6 V and an energy density of 1.7 mWh cm-2 at a power density of 4 mW cm-2. This work provides a feasible strategy for the design and fabrication of high-mass-loading LDH composites for electrochemical energy storage applications.
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Aqueous electrochemical energy storage devices (AEESDs) are considered one of the most promising candidates for large-scale energy storage infrastructure due to their high affordability and safety. Developing electrodes with the merits of high energy density and long lifespan remains a challenging issue toward the practical application of AEESDs. Research attempts at electrode materials, nanostructure configuration, and electronic engineering show the limitations due to the inherent contradictions associated with thicker electrodes and ion-accessible kinetics. Herein, we propose an intercalation chemistry engineering strategy to enhance the electrolyte ion (de)intercalation behaviors during the electrochemical charge-discharge. To validate this strategy, the prototypical model of a high-mass-loading MnO2-based electrode is used with controlled intercalation of Na+ and H2O. Theoretical and experimental results reveal that an optimal content of Na+ and H2O on the MnO2-based electrode exhibits superior electrochemical performance. Typically, the resultant electrode exhibits an impressive areal capacitance of 1551 mF/cm2 with a mass loading of 9.7 mg/cm2 (at 1 mA/cm2). Furthermore, the assembled full-cell with obtained MnO2-based electrode delivers a high energy density of 0.12 mWh/cm2 (at 20.02 mW/cm2) and ultra-high cycling stability with a capacitance retention percentage of 89.63 % (345 mF/cm2) even after 100,000 cycles (tested over 72 days).
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The Watson-Crick base-pairing with specificity and predictability makes DNA molecules suitable for building versatile nanoscale structures and devices, and the DNA origami method enables researchers to incorporate more complexities into DNA-based devices. Thermally controlled atomic force microscopy in combination with nanomechanical spectroscopy with forces controlled in the pico Newton (pN) range as a novel technique is introduced to directly investigate the kinetics of multistrand DNA hybridization events on DNA origami nanopores under defined isothermal conditions. For the synthesis of DNA nanostructures under isothermal conditions at 60 °C, a higher hybridization rate, fewer defects, and a higher stability are achieved compared to room-temperature studies. By quantifying the assembly times for filling pores in origami structures at several constant temperatures, the fill factors show a consistent exponential increase over time. Furthermore, the local hybridization rate can be accelerated by adding a higher concentration of the staples. The new insight gained on the kinetics of staple-scaffold hybridization on the synthesis of two dimensional DNA origami structures may open up new routes and ideas for designing DNA assembly systems with increased potential for their application.
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ADN/química , Nanoestructuras/química , Nanotecnología/métodos , Conformación de Ácido Nucleico , TemperaturaRESUMEN
TiO2/SnO2 branched heterojunction nanostructure with TiO2 branches on electrospun SnO2 nanofiber (B-SnO2 NF) networks serves as a model architecture for efficient self-powered UV photodetector based on a photoelectrochemical cell (PECC). The nanostructure simultaneously offers a low degree of charge recombination and a direct pathway for electron transport. Without correcting 64.5% loss of incident photons through light absorption and scattering by the F-doped tin oxide (FTO) glass, the incident power conversion efficiency reaches 14.7% at 330 nm, more than twice as large as the nanocrystalline TiO2 (TiO2 NC, 6.4%)-film based PECC. By connecting a PECC to an ammeter, the intensity of UV light is quantified using the output short-circuit photocurrent density (J(sc)) without a power source. Under UV irradiation, the self-powered UV photodetector exhibits a high responsivity of 0.6 A/W, a high on/off ratio of 4550, a rise time of 0.03 s and a decay time of 0.01 s for J(sc) signal. The excellent performance of the B-SnO2 NF-based PECC type self-powered photodetector will enable significant advancements for next-generation photodetection and photosensing applications.
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Nanoestructuras/química , Fotoquímica/métodos , Compuestos de Estaño/química , Titanio/químicaRESUMEN
Rechargeable aqueous zinc ion batteries (AZIBs) offer promising potential for large-scale energy storage systems due to their high affordability and safety. However, their practical applications are hindered by the undesired rate capability and cycling stability of the used cathode, attributed to sluggish ions kinetics during charge-discharge process. Herein, we propose an electric field balancing strategy to regulate the electrolyte ions behavior by constructing a ferroelectric interface on the cathode surface using a prototypical of MnO2-based cathode. An appropriate thickness coating of ferroelectric materials coating (i.e., ß-PVDF) on the MnO2 surface is theoretically and experimentally demonstrated to enhance the ion kinetics due to the optimized electrical distribution during electrochemical operations. Further comprehensive electrochemical mechanism studies reveal that the ferroelectric interface on the MnO2@ß-PVDF not only promotes the diffusion of Zn2+ but also reduces the electrochemical overpotential (17.6 mV), resulting in improved electrochemical reversibility and capacity performance. The resultant MnO2@ß-PVDF cathode exhibits the highest capacity of 277.6 mAh g-1 (at 0.1 A g-1) and capacity retention of 68.6% after 120 cycles, surpassing both the pristine MnO2 and non-ferroelectric materials coated MnO2 electrodes. This success presents a new approach to enhance the overall electrochemical performance of the cathodes for the practical application of AZIBs.
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The main challenge faced by the forthcoming human-computer interaction is that biological systems and electronic devices adopt two different information carriers, i.e., ions and electrons, respectively. To bridge the gap between these two systems, developing ion/electron-coupling devices for logic operation is a feasible and effective approach. Accordingly, herein a supercapacitor-based ionic diode (CAPode) that takes electrochemically amorphized molybdenum oxide as the working electrode is developed. Benefiting from its unique size and charge dual ion-sieving effects, the molybdenum oxide electrode exhibits a record-high rectification ratio of 136, which is over 10 times higher than those of reported systems. It also delivers an ultrahigh specific capacitance of 448 F gâ»1 and an excellent cycling stability of up to 20 000 cycles, greatly outperforming those of previous works. These excellent rectification capability and electrochemical performances allow the as-built CAPode to work well in AND and OR logic gates, validating great potential in ion/electron-coupling logic operations. More attractively, the superior biocompatibilities of molybdenum oxide and relevant constituent materials enable the constructed CAPode to be applied as bioelectronics without regard to biosafety, paving a new way toward forthcoming human-computer interaction.