Constructing a 3D Zinc Anode Exposing the Zn(002) Plane for Ultralong Life Zinc-Ion Batteries.

The limited lifespan of aqueous Zn-ion batteries (ZIBs) is primarily attributed to the irreversible issues associated with the Zn anode, including dendrite growth, hydrogen evolution, and side reactions. Herein, a 3D Zn anode exposing Zn(002) crystal planes (3D-Zn(002) anode) is first constructed by an electrostripping method in KNO3 solution. Experiments and theoretical calculations indicate that the priority adsorption of KNO3 on Zn(100) and Zn(101) planes decreases the dissolution energy of Zn atoms, thereby exposing more Zn(002) planes. The 3D-Zn(002) anode effectively regulates ion flux to realize the uniform nucleation of Zn2+. Moreover, it can inhibit water-induced formation of side-products and hydrogen evolution reaction. Consequently, the 3D-Zn(002) symmetrical cell exhibits an exceptionally long lifespan surpassing 6000 h at 5.0 mA cm-2 with a capacity of 1.0 mAh cm-2, and enduring 8500 cycles at 30 mA cm-2 with a capacity of 1.0 mAh cm-2. Besides, when NH4V4O10 is used as the cathode, the 3D-Zn(002)//NH4V4O10 full cell shows stable cycling performance with a capacity retention rate of 75.7% after 4000 cycles at 5.0 A g-1. This study proposes a feasible method employing a 3D-Zn(002) anode for enhancing the cycling durability of ZIBs.

Constructing Built-In Electric Field in NiCo2O4-CeO2 Heterostructures to Regulate Li2O2 Formation Routes at High Current Densities.

Developing catalysts with suitable adsorption energy for oxygen-containing intermediates and elucidating their internal structure-performance relationships are essential for the commercialization of Li-O2 batteries (LOBs), especially under high current densities. Herein, NiCo2O4-CeO2 heterostructure with a spontaneous built-in electric field (BIEF) is designed and utilized as a cathode catalyst for LOBs at high current density. The driving mechanism of electron pumping/accumulation at heterointerface is studied via experiments and density functional theory (DFT) calculations, elucidating the growth mechanism of discharge products. The results show that BIEF induced by work function difference optimizes the affinity for LiO2 and promotes the formation of nano-flocculent Li2O2, thus improving LOBs performance at high current density. Specifically, NiCo2O4-CeO2 cathode exhibits a large discharge capacity (9546 mAh g-1 at 4000 mA g-1) and high stability (>430 cycles at 4000 mA g-1), which are better than the majority of previously reported metal-based catalysts. This work provides a new method for tuning the nucleation and decomposition of Li2O2 and inspires the design of ideal catalysts for LOBs to operate at high current density.

Interface Engineering of PtZn Alloy and Nb2O5 for Promoting Ammonia Oxidation Reaction and Hydrogen Evolution Reaction.

Ammonia electrolysis is a promising technology to obtain green hydrogen with zero-carbon emission, in which ammonia oxidation reaction (AOR) and hydrogen evolution reaction (HER) occur at the anode and cathode, respectively. However, the lack of efficient catalysts hinders its practical application. Herein, PtZn alloy is combined with Nb2O5 to construct a bifunctional heterostructure catalyst (PtZn-Nb2O5/C). The optimal sample with Nb2O5 content of 7.05 wt % demonstrates the best performance with a peak current density of 304.1 mA mg-1Pt for AOR, and it is only reduced by 17.0% after 4000 cycles of durability tests. For HER, it has a low overpotential of 34 mV at -10 mA cm-2 under the alkaline condition. This can be ascribed to the interfacial interaction between the PtZn alloy and Nb2O5, which adjusts the adsorption behavior of OHad to concurrently promote AOR and HER activity. This work thus proposes a viable strategy to design an efficient bifunctional catalyst for hydrogen generation from ammonia electrolysis.

Geometric Phase Effects in the H + H2+ Reaction on the Lowest Triplet Ground State.

To our knowledge, this is the first time geometric phase (GP) effects in the H + H2+ reaction on its lowest triplet ground state with collision energies lower than 1.85 eV have been studied using the quantum wave packet method and vector potential approach. We obtained the total reaction probabilities including and not including GP (NGP) effects for J ≤ 4. Visible GP effects could be seen at the lower energy regime but are tiny at the higher one. Moreover, they are more obvious in the product rovibrational state-resolved reaction probabilities, and the relative resonance magnitudes between GP and NGP results change with product rotational state values alternatively. The main reasons are the interferences between the one- and two-transition-state (1-TS and 2-TS) reaction paths, in that at the lower energy regime, the reaction probabilities from the 2-TS pathway show peaks of comparable probabilities compared with that of the 1-TS pathway. In addition, the "out-of-phase" trend observed in the H + H2 reaction does not exist rigorously in this system. Importantly, the visible GP effects exist in this H3+ system, which makes it a very useful candidate reaction for nonadiabatic investigations in both theory and experiment.

Tuning d-Band Center of Pt by PtCo-PtSn Heterostructure for Enhanced Oxygen Reduction Reaction Performance.

The development of efficient and stable Pt-based catalysts is significant but challenging for fuel cells. Herein, Sn and Co elements are introduced into Pt to form PtCo-PtSn/C heterostructure for enhancing the oxygen reduction reaction (ORR). Electrochemical results indicate that it has remarkable ORR intrinsic activity with a high mass activity (1,158 mA mg-1 Pt) at 0.9 V in HClO4 solution, which is 2.18-, 6.81-, and 9.98-fold higher than that of PtCo/C, PtSn/C, and Pt/C. More importantly, the catalytic activity attenuation for PtCo-PtSn/C is only 27.4% after 30 000 potential cycles, showing high stability. Furthermore, theoretical calculations reveal that the enhancement is attributed to charge transfer and the unique structure of PtCo-PtSn/C heterostructure, which regulate the d-band center of Pt and prevent non-noble metals from further dissolution. This work thus opens a way to design and prepare highly efficient Pt-based alloy catalysts for proton exchange membrane fuel cells.

Iron-Doped Cobalt Phosphide Nanohoops for Electroreduction of Nitrate to Ammonia.

Heteroatom doping can effectively tune the electronic structure of an electrocatalyst to accelerate the adsorption/desorption of reaction intermediates, which sharply increases their intrinsic electroactivity. Herein, we successfully prepare iron (Fe)-doped cobalt phosphide (CoP) nanohoops (Fe/CoP NHs) with different Fe/Co atomic ratios as highly active electrocatalysts for the nitrate electrocatalytic reduction reaction (NIT-ERR). Electrochemical measurements reveal that appropriate Fe doping can improve the electroactivity of cobalt phosphide nanohoops for the NIT-ERR. In a 1 M KOH electrolyte, the Fe/CoP NHs with the optimized chemical composition can achieve an efficient ammonia (NH3) generation rate of 27.6 mg h-1 mgcat-1 for the conversion of NO3- into NH3 and a Faradaic efficiency of 93.3% at a -0.25 V potential, which exceed the values of various previously reported nanomaterials in an alkaline electrolyte.

A Novel Semi-Supervised Feature Extraction Method and Its Application in Automotive Assembly Fault Diagnosis Based on Vision Sensor Data.

The fault diagnosis of dimensional variation plays an essential role in the production of an automotive body. However, it is difficult to identify faults based on small labeled sample data using traditional supervised learning methods. The present study proposed a novel feature extraction method named, semi-supervised complete kernel Fisher discriminant (SS-CKFDA), and a new fault diagnosis flow for automotive assembly was introduced based on this method. SS-CKFDA is a combination of traditional complete kernel Fisher discriminant (CKFDA) and semi-supervised learning. It adjusts the Fisher criterion with the data global structure extracted from large unlabeled samples. When the number of labeled samples is small, the global structure that exists in the measured data can effectively improve the extraction effects of the projected vector. The experimental results on Tennessee Eastman Process (TEP) data demonstrated that the proposed method can improve diagnostic performance, when compared to other Fisher discriminant algorithms. Finally, the experimental results on the optical coordinate data proves that the method can be applied in the automotive assembly process, and achieve a better performance.

Rapid Global Calibration Technology for Hybrid Visual Inspection System.

Vision-based methods for product quality inspection are playing an increasingly important role in modern industries for their good performance and high efficiency. A hybrid visual inspection system, which consists of an industrial robot with a flexible sensor and several stationary sensors, has been widely applied in mass production, especially in automobile manufacturing. In this paper, a rapid global calibration method for the hybrid visual inspection system is proposed. Global calibration of a flexible sensor is performed first based on the robot kinematic. Then, with the aid of the calibrated flexible sensor, stationary sensors are calibrated globally one by one based on homography. Only a standard sphere and an auxiliary target with a 2D planar pattern are applied during the system global calibration, and the calibration process can be easily re-performed during the system's periodical maintenance. An error compensation method is proposed for the hybrid inspection system, and the final accuracy of the hybrid system is evaluated with the deviation and correlation coefficient between the measured results of the hybrid system and Coordinate Measuring Machine (CMM). An accuracy verification experiment shows that deviation of over 95% of featured points are less than ±0.3 mm, and the correlation coefficients of over 85% of points are larger than 0.7.

Monocular-Based 6-Degree of Freedom Pose Estimation Technology for Robotic Intelligent Grasping Systems.

Industrial robots are expected to undertake ever more advanced tasks in the modern manufacturing industry, such as intelligent grasping, in which robots should be capable of recognizing the position and orientation of a part before grasping it. In this paper, a monocular-based 6-degree of freedom (DOF) pose estimation technology to enable robots to grasp large-size parts at informal poses is proposed. A camera was mounted on the robot end-flange and oriented to measure several featured points on the part before the robot moved to grasp it. In order to estimate the part pose, a nonlinear optimization model based on the camera object space collinearity error in different poses is established, and the initial iteration value is estimated with the differential transformation. Measuring poses of the camera are optimized based on uncertainty analysis. Also, the principle of the robotic intelligent grasping system was developed, with which the robot could adjust its pose to grasp the part. In experimental tests, the part poses estimated with the method described in this paper were compared with those produced by a laser tracker, and results show the RMS angle and position error are about 0.0228° and 0.4603 mm. Robotic intelligent grasping tests were also successfully performed in the experiments.

Built-in electric field in NiO-CuO heterostructures to regulate the hydroxide adsorption sites for 5-hydroxymethylfurfural electrooxidation assisted hydrogen production.

The development of catalysts with suitable adsorption behavior for the reaction molecules and the elucidation of their internal structure-adsorption-catalytic activity relationships are crucial for the electrooxidation of 5-hydroxymethylfurfural (HMF). In this work, NiO-CuO heterostructures with a spontaneous built-in electric field (BEF) are specifically designed and used to regulate the OH- adsorption site for freeing up the active site of HMF for the HMF oxidation reaction (HMFOR). The mechanism driving electron pumping/accumulation of the BEF is examined by X-ray photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS). Electrochemical data and theoretical calculations show that BEF modulates the adsorption energy and adsorption site of substrate molecules, thereby enhancing the performance of HMFOR and hydrogen evolution reaction (HER). Notably, the NiO-CuO electrode demonstrates high 2,5-Furandicarboxylic acid (FDCA) selectivity (99.76 %) and generation rate (13.79 mmol gcat-1 h-1). It only requires 1.33 V to obtain a current density of 10 mA cm-2 for HMFOR-coupled H2 evolution. This research introduces a novel approach by regulating the adsorption of reactive molecules for HMFOR-assisted H2 evolution.

Tailoring competitive adsorption sites of hydroxide ion to enhance urea oxidation-assisted hydrogen production.

Alloys with bimetallic electron modulation effect are promising catalysts for the electrooxidation of urea. However, the side reaction oxygen evolution reaction (OER) originating from the competitive adsorption of OH- and urea severely limited the urea oxidation reaction (UOR) activity on the alloy catalysts. This work successfully constructs the defect-rich NiCo alloy with lattice strain (PMo-NiCo/NF) by rapid pyrolysis and co-doping. By taking advantage of the compressive strain, the d-band center of NiCo is shifted downward, inhibiting OH- from adsorbing on the NiCo site and avoiding the detrimental OER. Meanwhile, the oxygenophilic P/Mo tailored specific adsorption sites to adsorb OH- preferentially, which further released the NiCo sites to ensure the enriched adsorption of urea, thus improving the UOR efficiency. As a result, PMo-NiCo/NF only requires 1.27 V and -57 mV to drive a current density of ±10 mA cm-2 for UOR and hydrogen evolution reaction (HER), respectively. With the guidance of this work, reactant competing adsorption sites could be tailored for effective electrocatalytic performance.

Agglomeration inhibition engineering of nickel-cobalt alloys by a sacrificial template for efficient urea electrolysis.

Designing efficient non-precious metal-based catalysts for urea oxidation reaction (UOR) is essential for achieving energy-saving hydrogen production and the treatment of wastewater containing ammonia. In this study, sodium dodecyl sulfate (SDS) is employed as a sacrificial template to synthesize NiCo alloy nanowires (NiCo(SDS)/CC), and the instinct formation mechanism is investigated. It is found that SDS can inhibit the Ostwald ripening during hydrothermal and calcination processes, which could release abundant active cobalt, thereby modulating the electronic structure to promote the catalytic reaction. Moreover, SDS as a sacrificial template can induce the deposition of metal atoms and increase the specific surface area of the catalyst, providing abundant active sites to accelerate the reaction kinetics. As expected, the NiCo(SDS)/CC exhibits good activity for both UOR and hydrogen evolution reactions (HER) and it requires only 1.31 V and -86 mV to obtain a current density of ±10 mA cm-2, respectively. This work provides a new strategy for reducing the agglomeration of transition metals to design high-performance composite catalysts for urea oxidation.

Anthraquinone-based polymer modified BiVO4 photoanode with strong electron-withdrawing functional groups for boasting photoelectrochemical water oxidation.

The photoelectrochemical (PEC) performance ofBiVO4 is limited by sluggish water oxidation kinetics and severe carrier recombination. Herein, a novel high-performance BiVO4/NiFe-NOAQ photoanode is prepared by a simple one-step hydrothermal method, using BiVO4 and 1-Nitroanthraquinone (NOAQ) as raw materials. The BiVO4/NiFe-NOAQ photoanode has an excellent photocurrent density of 5.675 mA cm-2 at 1.23 VRHE, which is 3.35 times higher than that of the pure BiVO4 (1.693 mA cm-2) photoanode. The BiVO4/NiFe-NOAQ shows a significant improvement in charge separation efficiency (86.12 %) and charge injection efficiency (87.86 %). The improvement is ascribable to the NiFe-NOAQ form a type II heterojunction with BiVO4 to inhibit carrier recombination. More importantly, the kinetic isotope experiment suggests that the proton-coupled electron transfer (PCET) process can enhance the charge transfer of BiVO4/NiFe-NOAQ. The contact angle measurements show that modifying functional groups enhanced the hydrophilicity of BiVO4/NiFe-NOAQ, which can further accelerate the PCET process. The XPS and PL results as well as the tauc plot indicate that the strong electron-withdrawing ability of -NO2 which can promote the extension of π conjugation, results in more π electron delocalization and produces more efficient active sites, thus achieving efficient photoelectrochemical water oxidation.

A vision-based self-calibration method for robotic visual inspection systems.

A vision-based robot self-calibration method is proposed in this paper to evaluate the kinematic parameter errors of a robot using a visual sensor mounted on its end-effector. This approach could be performed in the industrial field without external, expensive apparatus or an elaborate setup. A robot Tool Center Point (TCP) is defined in the structural model of a line-structured laser sensor, and aligned to a reference point fixed in the robot workspace. A mathematical model is established to formulate the misalignment errors with kinematic parameter errors and TCP position errors. Based on the fixed point constraints, the kinematic parameter errors and TCP position errors are identified with an iterative algorithm. Compared to the conventional methods, this proposed method eliminates the need for a robot-based-frame and hand-to-eye calibrations, shortens the error propagation chain, and makes the calibration process more accurate and convenient. A validation experiment is performed on an ABB IRB2400 robot. An optimal configuration on the number and distribution of fixed points in the robot workspace is obtained based on the experimental results. Comparative experiments reveal that there is a significant improvement of the measuring accuracy of the robotic visual inspection system.

Surface unsaturated WOx activating PtNi alloy nanowires for oxygen reduction reaction.

PtNi alloy nanoparticles display promising catalytic activity for oxygen reduction reaction (ORR), while the Ostwald ripening of particles and the dissolution/migration of surface atoms greatly affect its stability thus restricting the application. Herein, the WOx-surface modified PtNi alloy nanowires (WOx-PtNi NWs) exhibiting enhanced ORR catalytic property is reported, which has high aspect ratio with the diameter of only 2 âˆ¼ 3 nm. It is found that the WOx-PtNi NWs shows a volcano relationship between the ORR activity and the content of WOx. The WOx-(0.25)-PtNi NWs has the best performance among all the synthesized catalysts. Its mass activity (0.85 A mg-1Pt) is reduced by only 23.89% after 30k cycles durability test, which is much more stable than that of PtNi NWs (0.33 A mg-1Pt, 45.94%) and Pt/C (0.14 A mg-1Pt, 57.79%). Hence this work achieves an effective regulation of the ORR activity for PtNi alloy NWs by the synergistic effect of WOx on Pt.

Hexagonal WO3/3D Porous Graphene as a Novel Zinc Intercalation Anode for Aqueous Zinc-Ion Batteries.

Aqueous Zn-ion batteries (ZIBs) have acquired great attention because of their high safety and environmentally friendly properties. However, the uncontrollable Zn dendrites and the irreversibility of electrodes seriously affect their practical application. Herein, hexagonal WO3/three-dimensional porous graphene (h-WO3/3DG) is investigated as an intercalation anode for ZIBs. As a result, the h-WO3/3DG//Zn half-battery shows excellent electrochemical performance with a high capacity of 115.6 mAh g-1 at 0.1 A g-1 and 89% capacity retention at 2.0 A g-1 after 10 000 cycles. The reason could be that the crystalline structure of WO3, which has hexagonal channels, with a diameter of 5.36 Å, much higher than the diameter of Zn2+ (0.73 Å), accelerating the insertion/extraction of Zn ions. A zinc metal-free full battery using h-WO3/3DG as the anode and ZnMn2O4/carbon black (ZnMn2O4/CB) as the cathode is constructed, exhibiting an initial capacity of 66.8 mAh g-1 at 0.1 A g-1 corresponding to an energy density of 73.5 W h kg-1 (based on the total mass of anode and cathode-active materials) and a capacity retention of 76.6% after 1000 cycles at 0.5 A g-1. This work demonstrates the high potential of hexagonal WO3 as an advanced intercalation anode material for Zn metal-free batteries and may inspire new ideas for the development of other intercalation anode hosts for ZIBs.

Crystalline-Amorphous Ni3S2-NiMoO4 Heterostructure for Durable Urea Electrolysis-Assisted Hydrogen Production at High Current Density.

Developing bifunctional catalysts with good performance at a high current density for the urea oxidation reaction (UOR) and the hydrogen evolution reaction (HER) can effectively relieve the severe environmental and energy pressures. Herein, amorphous NiMoO4 decorated Ni3S2 grown on nickel foam (Ni3S2-NiMoO4/NF) is prepared to accelerate UOR and HER. The crystalline-amorphous heterostructure could regulate the interfacial electron structure to reduce the electron density near Ni3S2 for optimizing UOR and HER. The decoration of NiMoO4 enhances its anti-poisoning ability for CO-intermediate species to show good stability at high current densities. Meanwhile, the nano-/microstructure with high hydrophilicity improves mass transfer and the accessibility of electrolyte. Driving high current densities of ±1000 mA cm-2, it merely needs 1.38 V (UOR) and -263 mV (HER). For urea electrolysis, it can deliver 1000 mA cm-2 at 1.73 V and stably operate at 500 mA cm-2 for 120 h. Therefore, this study provides new ideas for durable urea electrolysis-assisted H2 production.

Heterointerface and Defect Dual Engineering in a Superhydrophilic Ni2P/WO2.83 Microsphere for Boosting Alkaline Hydrogen Evolution Reaction at High Current Density.

Developing a high-performance electrocatalyst for hydrogen evolution reaction (HER) requires a comprehensive consideration of the three key factors, that is, intrinsic activity, electric conductivity, and active site number. Herein, we report the facile synthesis of a self-supported Ni2P/WO2.83 heterointerface microsphere as a highly active and low-cost catalyst for alkaline HER, which has simultaneously addressed these key issues by a joint application of heterointerface construction and defect and architecture engineering strategies. Our density functional theory calculations revealed Ni2P and WO2.83 optimized by the interface coupling effect work in concert to improve the intrinsic activity of the catalyst. Importantly, the metalloid Ni2P in an intimate combination with the oxygen-defect-rich WO2.83 species endowed the electrocatalyst with high conductivity. Furthermore, the Ni2P/WO2.83 electrocatalyst presented a superhydrophilic nanostructure, ensuring abundant active sites and their accessibility. Benefiting from these attributes, the obtained Ni2P/WO2.83 heterointerface electrocatalyst exhibited excellent activity along with favorable stability for alkaline HER, especially at high current density, surpassing the most reported non-precious catalysts.

N-Doped Graphene-Decorated NiCo Alloy Coupled with Mesoporous NiCoMoO Nano-sheet Heterojunction for Enhanced Water Electrolysis Activity at High Current Density.

Developing highly effective and stable non-noble metal-based bifunctional catalyst working at high current density is an urgent issue for water electrolysis (WE). Herein, we prepare the N-doped graphene-decorated NiCo alloy coupled with mesoporous NiCoMoO nano-sheet grown on 3D nickel foam (NiCo@C-NiCoMoO/NF) for water splitting. NiCo@C-NiCoMoO/NF exhibits outstanding activity with low overpotentials for hydrogen and oxygen evolution reaction (HER: 39/266 mV; OER: 260/390 mV) at ± 10 and ± 1000 mA cm-2. More importantly, in 6.0 M KOH solution at 60 °C for WE, it only requires 1.90 V to reach 1000 mA cm-2 and shows excellent stability for 43 h, exhibiting the potential for actual application. The good performance can be assigned to N-doped graphene-decorated NiCo alloy and mesoporous NiCoMoO nano-sheet, which not only increase the intrinsic activity and expose abundant catalytic activity sites, but also enhance its chemical and mechanical stability. This work thus could provide a promising material for industrial hydrogen production.

Three-Phase Heterojunction NiMo-Based Nano-Needle for Water Splitting at Industrial Alkaline Condition.

Constructing heterojunction is an effective strategy to develop high-performance non-precious-metal-based catalysts for electrochemical water splitting (WS). Herein, we design and prepare an N-doped-carbon-encapsulated Ni/MoO2 nano-needle with three-phase heterojunction (Ni/MoO2@CN) for accelerating the WS under industrial alkaline condition. Density functional theory calculations reveal that the electrons are redistributed at the three-phase heterojunction interface, which optimizes the adsorption energy of H- and O-containing intermediates to obtain the best ΔGH* for hydrogen evolution reaction (HER) and decrease the ΔG value of rate-determining step for oxygen evolution reaction (OER), thus enhancing the HER/OER catalytic activity. Electrochemical results confirm that Ni/MoO2@CN exhibits good activity for HER (ƞ-10 = 33 mV, ƞ-1000 = 267 mV) and OER (ƞ10 = 250 mV, ƞ1000 = 420 mV). It shows a low potential of 1.86 V at 1000 mA cm-2 for WS in 6.0 M KOH solution at 60 °C and can steadily operate for 330 h. This good HER/OER performance can be attributed to the three-phase heterojunction with high intrinsic activity and the self-supporting nano-needle with more active sites, faster mass diffusion, and bubbles release. This work provides a unique idea for designing high efficiency catalytic materials for WS.