Efficient removal of tetracycline hydrochloride through novel Fe/BiOBr/Bi2WO6 photocatalyst prepared by dual-strategy under visible-light irradiation.

It is important to investigate whether combining two modification strategies has a synergistic effect on the activity of photocatalysts. In this manuscript, Fe-doped BiOBr/Bi2WO6 heterojunctions were synthesized by a one-pot solvothermal method, and excellent photocatalytic performance was obtained for the degradation of tetracycline hydrochloride (TCH) in water without the addition of surfactant. Combining experiments and characterization, the synergistic effect between Fe ion doping and the BiOBr/Bi2WO6 heterojunction was elucidated. The Fe/BiOBr/Bi2WO6 composite photocatalyst had a beneficial void structure, enhanced visible light response, and could inhibit the recombination of photogenerated support well, which improved the photocatalytic activity. The presented experiments demonstrate that Fe/BiOBr/Bi2WO6 removes 97% of TCH from aqueous solution, while pure BiOBr and Bi2WO6 only remove 56% and 65% of TCH, respectively. Finally, the separation and transfer mechanisms of photoexcited carriers were determined in conjunction with the experimental results. This study provides a new direction for the design of efficient photocatalysts through the use of a dual co-modification strategy.

Removal of oxytetracycline from water by S-doped MIL-53(Fe): Synergistic effect of surface adsorption and persulfate activation.

In this study, a novel catalyst based on MIL-53(Fe) was synthesized and modified through sublimed sulfur (S-MIL-53(Fe)) to induce a synergistic effect of surface adsorption and persulfate activation. The S-doped modification not only increased the surface area but also accelerated the electron transfer process of the iron cycle. The performance of the newly synthesized S-MIL-53(Fe) adsorptive catalyst was evaluated by chemical adsorption and peroxydisulfate (PDS) activated removal of an emerging pollutants, oxytetracycline (OTC). The S-MIL-53(Fe) adsorptive catalyst was able to adsorb 61.7% of OTC after 120 min, and the removal efficiency reached 84.8% within 5 min after PDS dosing. The boosting effect of sulfur on the system was confirmed by characterization analysis and experimental testing. Even after 7 cycles, the removal efficiency of S-MIL-53(Fe) (69.0%) for OTC remained superior to that of pure MIL-53(Fe) (25.1%). Additionally, the adsorption kinetics and adsorption isotherm model of the material were investigated. The possible OTC degrading process was proposed based on radical quenching and electron paramagnetic resonance (EPR). This study provides a feasible way to fabricate an S-doped MIL-53(Fe) adsorptive catalyst for the remediation of antibiotics-containing wastewater.

Highly efficient removal of oxytetracycline using activated magnetic MIL-101(Fe)/γ-Fe2O3 heterojunction catalyst.

A novel magnetic nanocomposite MIL-101(Fe)/γ-Fe2O3 was synthesized by hydrothermal method. The physical structure and chemical property of the as-obtained magnetic nanocomposite was characterized. The ability of MIL-101(Fe)/γ-Fe2O3 to promote photo-assisted peroxydisulfate (PDS) activation was investigated by using oxytetracycline (OTC) as the target pollutant. The results showed that the composite with a FeCl3•6H2O: γ-Fe2O3 mass ratio of 10:1 exhibited the highest degradation efficiency (up to 91.2%). Influencing factors such as pH, catalyst dosage, PDS concentration and OTC concentration on the catalytic performance of MIL-101(Fe)/γ-Fe2O3 were also investigated to determine the optimum conditions. More importantly, the MIL-101(Fe)/γ-Fe2O3 can be magnetically recovered and reused for 4 cycles. Based on radical quenching and electron spin resonance (ESR), the possible degradation mechanism of OTC in photo-assisted PDS activation (PPA) system was proposed. This research provided novel insights for the design and preparation of a new type of magnetic Fe-MOFs for environmental remediation.

Construction of Z-scheme g-C3N4 / MnO2 /GO ternary photocatalyst with enhanced photodegradation ability of tetracycline hydrochloride under visible light radiation.

A facile wet-chemical method was adopted to synthesize g-C3N4/MnO2/GO heterojunction photocatalyst for visible-light photodegradation of tetracycline hydrochloride (TC). The addition of MnO2 and GO increased the absorption of visible light and the specific surface area of the photocatalyst. The results of photoluminescence, electrochemical impedance spectroscopy, and photocurrent response indicated that CMG-10 had the lowest electron-hole recombination probability, which was beneficial for the photocatalytic reaction. The ternary photocatalyst exhibited enhanced photoelectric performance and superior photocatalytic activity with 91.4% removal of TC (10 mg/L) under a mere 60 min visible light illumination, which showed enhanced photocatalytic degradation when compared with binary (CM, 77.95%; CG, 78.83%) and single (C3N4, 55.5%; MnO2, 36.41%) photocatalysts. A pH of 6 was optimal for the CMG-10 photocatalytic degradation of TC, and the optimal photocatalyst dosage was 0.5 g/L. Common coexisting ions influenced the removal of TC by influencing the production of active species. The catalyst is stable and reusable with only a 10% reduction in removal efficiency after four cycles. According to the active species analysis, the Z-scheme mechanism was a charge transfer behavior in the composite photocatalyst, which could prevent the recombination of photogenerated carriers. This study presents a photocatalytic approach to the effective removal of TC from water bodies, which provides practical implications to advance the use of photocatalytic technology in the restoration of aqueous environmental pollution.

Enhancing autotrophic nitrogen removal with a novel dissolved oxygen-differentiated airlift internal circulation reactor: Long-term operational performance and microbial characteristics.

Autotrophic nitrogen removal (ANR) processes have not been widely applied in wastewater treatment due to their long start-up time and unstable performance. In this study, a novel dissolved oxygen-differentiated airlift internal circulation reactor was developed to enhance ANR from wastewater. During 200 days of continuous operation, the reactor start-up was achieved within 30 days; a high total nitrogen removal efficiency of 80% was achieved and stably maintained under an aeration rate of 0.90 L/min and hydraulic retention time of 6 h. Additionally, the color of sludge went from a light yellow to dark red, and the amount and size of the micro-granules increased obviously. Medium-sized (1.0-2.5 mm) micro-granules accounted for 72.4% on day 190. The specific anammox activity increased from 0.53 to 1.43 g-N/g-VSS/d, while the SNOA decreased from 0.93 to 0.08 g-N/g-VSS/d. Furthermore, the microbial analysis showed that the Nitrosomonas (4.2%) and Candidatus Brocadia (22.6%) were enriched and formed the micro-granules after the reactor's long-term operation. The results indicate that novel configuration realizes the partitioning of dissolved oxygen (DO), optimizes nitritation and anammox reactions, and accelerates biochemical reactions, thereby enhancing ANR performance. This study provides a practical alternative to enhance ANR performance and a scientific basis for the development and application of novel nitrogen removal reactors.

A review on the removal of heavy metals and metalloids by constructed wetlands: bibliometric, removal pathways, and key factors.

Heavy metals and metalloids (HMMs) pose a serious threat to both environmental and human health. The unique characteristics and environmental toxicity of HMMs make their removal from the environment a major challenge. Constructed wetlands (CWs) are increasingly being used as an eco-friendly system for the removal of HMMs from aqueous environments. In this review, bibliometric analysis was performed using the Scopus database using VOSviewer software to assess the developing use of CWs in recent years. Heavy metal and metalloid (HMM) removal pathways were reviewed (such as precipitation, co-precipitation, adsorption and ion exchange, plant action and microbial action) along with the impact of key factors (pH, chemical oxygen demand, dissolved oxygen, HMM concentration, and temperature). This review aimed to establish the connections between published results, to help effectively optimize the use of CWs for the removal of HMMs and identify the most critical factors for their effective removal. Important aspects that require further research include assessing the synergistic toxicity between different pollutants and combining the use of CWs with other technologies to optimize pollutant remediation efficiency.

Wet flue gas desulfurization wastewater treatment with reclaimed water treatment plant sludge: a case study.

To upgrade a wet flue gas desulfurization (FGD) wastewater treatment process in a typical thermal power plant (TPP) in Hunan province, China, a new concept for reusing polyaluminum chloride (PAC)-based water treatment plant sludge (WTPS) as a coagulant is proposed. Results show that, for an optimal WTPS dosage of 1,000 mg/L, the corresponding removal capacities for suspended solids (SS) and chemical oxygen demand (COD) from the practical FGD wastewater were 58.3% and 40.3%, respectively. Through an advanced treatment with a dosage of 50 mg/L of PAC, pH of 9, and stirring of 150 r/min for 60 s and 50 r/min for 15 min, the total removal efficiencies of SS, COD, and total cadmium (Cd) from the FGD wastewater were 93.7%, 88.8%, and 84.6%, respectively. Therefore, a new modification process (that involves mixing with WTPS - slag cleaner - neutralization - coagulation - sedimentation) was proposed. The proposed process is economically superior, and the average cost for the FGD wastewater treatment was only 1.08 USD/t. This could provide a cost-effective alternative process for upgrading FGD wastewater treatment facilities of TPPs.

Cadmium removal by constructed wetlands containing different substrates: performance, microorganisms and mechanisms.

This study compared the cadmium (Cd) removal performance of constructed wetlands (CWs), including gravel (G-CW), magnetite (M-CW), coconut shell (C-CW) and biochar (B-CW). C-CW exhibited superior removal efficiencies for Cd compared to other CWs, with efficiencies of 93.18 %.C-CW benefited from the rich organic matter of coconut shells and enhanced DO consumption levels, which facilitated microbial and plant removal of Cd. The total accumulation of Cd in the substrate increased from 9.16 mg/kg to 30.66 mg/kg. Concurrently, the percentage of Cd in the organic matter-bound and residue states increased from 20.52 % to 37.56 %, which effectively reduced the bioavailability of Cd. All CWs can ensure that the plant antioxidant system is not subjected to Cd stress. Saccharimonadales and Micropruina became the dominant genera in all CWs, exhibiting a high tolerance to Cd. This study provides new understanding and theoretical support for selecting substrates to effectively treat heavy metals wastewater with CWs.

Biochar from phytoremediation plant residues: a review of its characteristics and potential applications.

Phytoremediation is a cost-effective and eco-friendly plant-based approach promising technique to repair heavy metal-contaminated soils. However, a significant quantity of plant residues needs to be properly treated and utilized. Pyrolysis is an effective technology for converting residues to biochar, which can solve the problem and avoid secondary contamination. This paper reviews the generation, and physicochemical properties of biochar from phytoremediation residues, and its application in soil improvement, environmental remediation, and carbon sequestration. In spite of this, it is important to be aware of the potential toxicity of heavy metals in biochar and the environmental risks of biochar before applying it to practical applications. Future challenges in the production and application of residue-derived biochar include the rational selection of pyrolysis parameters and proper handling of potentially hazardous components in the biochar.

Insights into the enhanced effect of biochar on cadmium removal in vertical flow constructed wetlands.

Biochar has been increasingly applied in constructed wetlands (CWs) to remediate heavy metal (HM)-polluted water. Nevertheless, only few studies have elucidated the enhanced mechanism and potential synergies related to the HM removal from biochar-based CWs (BC-CWs) for HMs removal. This study used cadmium (Cd) as the target HM and added biochar into CWs to monitor physicochemical parameters, plant' physiological responses, substrate accumulation, and microbial metabolites and taxa. In comparison with the biochar-free CW (as CWC), a maximum Cd2+ removal of 99.7% was achieved in the BC-CWs, associated with stable physicochemical parameters. Biochar preferentially adsorbed the available Cd2+ and significantly accumulated Fe/Mn oxides-bond and the exchangeable Cd fraction. Moreover, biochar alleviated the lipid peroxidation (decreased by 36.4%) of plants, resulting in improved growth. In addition, extracellular polymeric substances were increased by 376.9-396.8 mg/L in BC-CWs than compared to CWC, and N and C cycling was enhanced through interspecific positive connectivity. In summary, this study explored comprehensively the performance and mechanism of BC-CWs in the treatment of Cd2+-polluted water, suggesting a promising approach to promote the plant-microbe-substrate synergies under HM toxicity.

Typical layered structure bismuth-based photocatalysts for photocatalytic nitrogen oxides oxidation.

Traditional NOx treatment methods require external reducing reagents and harsh reaction conditions, which is not conducive to effectively eliminate NOx at low concentration, especially at ppb levels. Fortunately, low concentration NOx can be removed by photocatalytic oxidation under mild reaction conditions. Bismuth (Bi)-based photocatalysts with the layered structure have obtained considerable concerns of photocatalytic NOx oxidation. This review focused on typical layered Bi-based photocatalysts (Bi2WO6, Bi2O2CO3, BiOY (YCl, Br, and I), BiOIO3, and BiOCOOH) with the structure of [Bi2O2]2+ layer for photocatalytic NOx oxidation. The strategies (morphological control, defect engineering, heterostructure construction, etc.) to improve photocatalytic oxidation activity were summarized. Furthermore, the mechanism involving various free radicals (hydroxyl radical, superoxide radical, etc.) of photocatalytic oxidation of NOx was proposed. In addition, the non-NO2 selectivity was also illuminated. Lastly, the current drawbacks and further research directions for photocatalytic NOx oxidation were elaborated. The development of photocatalysts with high photocatalytic activity, wide light absorption range, and non-NO2 selectivity is the focus of future research. This review aims to provide a pandect and theoretical guidance for the practical application of photocatalytic oxidation of NOx.

Recent advances in constructed wetlands methane reduction: Mechanisms and methods.

Constructed wetlands (CWs) are artificial systems that use natural processes to treat wastewater containing organic pollutants. This approach has been widely applied in both developing and developed countries worldwide, providing a cost-effective method for industrial wastewater treatment and the improvement of environmental water quality. However, due to the large organic carbon inputs, CWs is produced in varying amounts of CH4 and have the potential to become an important contributor to global climate change. Subsequently, research on the mitigation of CH4 emissions by CWs is key to achieving sustainable, low-carbon dependency wastewater treatment systems. This review evaluates the current research on CH4 emissions from CWs through bibliometric analysis, summarizing the reported mechanisms of CH4 generation, transfer and oxidation in CWs. Furthermore, the important environmental factors driving CH4 generation in CW systems are summarized, including: temperature, water table position, oxidation reduction potential, and the effects of CW characteristics such as wetland type, plant species composition, substrate type, CW-coupled microbial fuel cell, oxygen supply, available carbon source, and salinity. This review provides guidance and novel perspectives for sustainable and effective CW management, as well as for future studies on CH4 reduction in CWs.

Reutilization of manganese enriched biochar derived from Phytolacca acinosa Roxb. residue after phytoremediation for lead and tetracycline removal.

This study aimed to evaluate the chemical form variation of Mn in Phytolacca acinosa Roxb. residue under different pyrolysis temperatures and its contribution to decontamination efficacy of lead (Pb(II)) and tetracycline (TC). The results illuminated that pyrolysis temperature is a crucial factor of fraction and bioavailability of Mn and other heavy metals in the resultant biochar and pyrolysis temperature under 450 °C may be most suitable for reutilization without potential risk. The Mn-enriched phytolaccaceae biochar (PSB450) exhibited more preferential sorption toward Pb(II) (279.33 mg/g) and TC (47.51 mg/g) than pristine phytolaccaceae biochar in the single system, mainly due to the formation of MnOx and Mn minerals via pyrolysis. Binary adsorption showed that Pb(II) would serve as a bridge between PSB450 and TC by complexation within a limited concentration range, thus facilitating their joint decontamination. This study provided an efficient alternative approach for reutilization of Mn-contaminated biomass.

Insights into highly effective catalytic persulfate activation on oxygen-functionalized mesoporous carbon for ciprofloxacin degradation.

Nanocarbons have been demonstrated as promising carbon catalysts for substituting metal-based catalysts for the green treatment of wastewater. In this study, oxygen-functionalized mesoporous carbon (OCMK-3) was prepared by wet oxidation and exhibited high catalytic performance against ciprofloxacin (CIP) by activation of persulfate. The effects of environmental parameters (pH, temperature, coexisting ions) and process parameters (temperature, sodium persulfate concentration, catalyst agent dosage, initial concentration) on the removal of CIP were investigated. Compared with the pristine ordered mesoporous carbon (CMK-3), the removal efficiency of CIP by OCMK-3 was increased by 32% under optimal conditions. This rise in activity was attributed to the increase in oxygen-containing functional groups, porosity, and specific surface area of OCMK-3 with improved structural defects and electron transfer efficiency. Furthermore, based on active species scavenging experiments, a dual-pathway mechanism of the radical and nonradical pathways was discovered. The rational degradation pathway of CIP was investigated based on liquid chromatography-mass spectrometry (LC-MS). In addition, the OCMK-3/PS system exhibited high decomposition efficiency in pharmaceutical wastewater treatment. This study provides an in-depth mechanism for the degradation of organic pollutants by carbon-based PS-AOPs and provides theoretical support for further studies.

Enhanced removal of heavy metals and metalloids by constructed wetlands: A review of approaches and mechanisms.

Constructed wetlands (CWs) are increasingly employed to remediate heavy metal and metalloid (HMM)-polluted water. However, the disadvantages of HMM removal by conventional CWs (without enhancement), such as an unstable and unpredictable removal efficiency, hinder the reliability of this technology. The objective of this study was to review research on enhanced CWs for HMM removal. In particular, we performed a bibliometric analysis to evaluate research trends, critical literature, and keyword evolution in recent years. Subsequently, we reviewed various enhanced approaches for the application of CWs for the removal of HMMs, including the use of improved substrates, aquatic macrophytes, microorganisms, bioelectrochemical coupling systems, hybrid CW, external additives, and operation parameters. Furthermore, the main mechanisms underlying HMM removal by these approaches are summarized. Our review clearly reveals that research on the remediation of HMM-polluted water via CW technology is receiving increased attention, with no apparent trends in topics. The selection of appropriate enhanced approaches or operation parameters as well as methodological improvements should be based on the dominant environmental conditions of the CW column and removal mechanisms for the targeted HMMs. Based on the established literature, several suggestions are proposed to guide the optimization of the design and operation of efficient CWs for the treatment of HMM-polluted water.

Applying fulvic acid for sediment metals remediation: Mechanism, factors, and prospect.

Fulvic acid (FA) has been shown to play a decisive role in controlling the environmental geochemical behavior of metals. As a green and natural microbial metabolite, FA is widely used in environmental remediation because of its good adsorption complexation and redox ability. This paper introduces the reaction mechanism and properties of FA with metals, and reviews the progress of research on the remediation of metal pollutant by FA through physicochemical remediation and bioremediation. FA can control the biotoxicity and migration ability of some metals, such as Pb, Cr, Hg, Cd, and As, through adsorption complexation and redox reactions. The concentration, molecular weight, and source are the main factors that determine the remediation ability of FA. In addition, the ambient pH, temperature, metal ion concentrations, and competing components in sediment environments have significant effects on the extent and rate of a reaction between metals and FA during the remediation process. Finally, we summarize the challenges that this promising environmental remediation tool may face. The research directions of FA in the field of metals ecological remediation are also prospected. This review can provide new ideas and directions for the research of remediation of metals contaminants in sediments.

A Review on Microorganisms in Constructed Wetlands for Typical Pollutant Removal: Species, Function, and Diversity.

Constructed wetlands (CWs) have been proven as a reliable alternative to traditional wastewater treatment technologies. Microorganisms in CWs, as an important component, play a key role in processes such as pollutant degradation and nutrient transformation. Therefore, an in-depth analysis of the community structure and diversity of microorganisms, especially for functional microorganisms, in CWs is important to understand its performance patterns and explore optimized strategies. With advances in molecular biotechnology, it is now possible to analyze and study microbial communities and species composition in complex environments. This review performed bibliometric analysis of microbial studies in CWs to evaluate research trends and identify the most studied pollutants. On this basis, the main functional microorganisms of CWs involved in the removal of these pollutants are summarized, and the effects of these pollutants on microbial diversity are investigated. The result showed that the main phylum involved in functional microorganisms in CWs include Proteobacteria, Bacteroidetes, Actinobacteria and Firmicutes. These functional microorganisms can remove pollutants from CWs by catalyzing chemical reactions, biodegradation, biosorption, and supporting plant growth, etc. Regarding microbial alpha diversity, heavy metals and high concentrations of nitrogen and phosphorus significantly reduce microbial richness and diversity, whereas antibiotics can cause large fluctuations in alpha diversity. Overall, this review can provide new ideas and directions for the research of microorganisms in CWs.

Laboratory-scale study of a biodegradable microplastic polylactic acid stabilizing aerobic granular sludge system.

The effects of microplastics on aerobic granular sludge technology are an emerging issue, although the impact of degradable microplastics (DMPs) on the aerobic granular system is still unexplored. In this study, degradable microplastic polylactic acid (DMP-PLA) was added at three concentrations (5, 15, 40 mg/L), which strengthened the granular stability and consequently stabilized pollutant removal compared to the control (without DMP-PLA). The experiment showed that adding DMP-PLA made cells secrete more extracellular polymeric substances [64.8 mg/g MLVSS (mixed liquor suspended solids)], particularly retaining ß-D-glucopyranose polysaccharides in experimental group. In addition, abundant hydrogen bonds were also maintained. The reactor under the stress of DMP-PLA exhibited high pollutant removal efficiency (COD>88%, TP>91%, TIN>86%), indicating high performance of the microbes. Microbial analysis at the genus level indicated that Defuviicoccus and Candidatus_Competibacter were dominant after DMP-PLA addition, which identified denitrifying glycogen-accumulating organisms as beneficial for nitrogenous compound removal. Redundancy analysis showed that the abundance of Candidatus_Competibacter was positively related to the addition of DMP-PLA. This study demonstrated that DMP-PLA was feasibly employed in the aerobic granular water treatment process, and presents a new method to optimize the stability and extracellular secretion of the microbial community.

Enhanced photocatalytic activity of 3D hierarchical RP/BP/BiOCOOH via oxygen vacancies and double heterojunctions.

A 3D hierarchical RP/BP/BiOCOOH double heterostructures with abundant oxygen vacancies (OVs) was obtained by hydrothermal process and its photocatalytic activity was investigated by degradation of TC-HCl with different light sources and various natural water. The physicochemical characteristics of RP/BP/BiOCOOH heterojunctions were systematically characterized via TEM, XPS, EPR, EIS et al. Compared with BiOCOOH, the photocatalytic activity of RP/BP/BiOCOOH was obviously enhanced. Under simulated solar light irradiation, 60.5% of TC-HCl was removed by 3%RP/BP/BiOCOOH. And the rate constant of 3%RP/BP/BiOCOOH was 2.95 times than that of BiOCOOH. Traces of small molecular organics were beneficial to improve photocatalytic efficiency. The process of photocatalytic degradation and the cytotoxicity of intermedia products of TC-HCl were discussed via HPLC-MS, 3D-EEM, and antibacterial properties test. Based on the results of trapping experiments and ESR tests, •OH and •O2- were the most significant reactive oxygen species. The enhanced photocatalytic activity was ascribed to two reasons: 1 double heterojunctions structure enhanced the separation efficiency of carriers, 2 the introduction of OVs and BP/RP expanded the response range of light. This work provides a feasible strategy that non-metallic element semiconductor is used to modify the wide band gap semiconductor to enhance the photocatalytic efficiency.

Degradation of oxytetracycline by magnetic MOFs heterojunction photocatalyst with persulfate: high stability and wide range.

Photocatalysis with persulfate (PS) is an effective method for the degradation of degrading organic pollutants. In this study, Fe3O4/MIL-101(Fe), a magnetic heterojunction photocatalyst, was produced using a hydrothermal method. The material coupled with PS exhibited excellent removal efficiency for oxytetracycline (OTC) (87.1%, 1 h). And it has a wide range of applications, with good removal efficiency for OTC concentrations of 30 to 70 mg/L and pH values of 3 to 9. •SO4- and •OH played a major role in the OTC removal reaction and there was an Fe(III)/Fe(II) cycle during the reaction. With excellent stability and recoverability, the OTC removal efficiency decreased by only 4.29% after four cycles, and the Fe leaching did not exceed 0.035 mg/L per cycle. This study provides significant insights into the removal of organic pollutants from water bodies.