Osmotic Heat Engine Using Thermally Responsive Ionic Liquids.

The osmotic heat engine (OHE) is a promising technology for converting low grade heat to electricity. Most of the existing studies have focused on thermolytic salt systems. Herein, for the first time, we proposed to use thermally responsive ionic liquids (TRIL) that have either an upper critical solution temperature (UCST) or lower critical solution temperature (LCST) type of phase behavior as novel thermolytic osmotic agents. Closed-loop TRIL-OHEs were designed based on these unique phase behaviors to convert low grade heat to work or electricity. Experimental studies using two UCST-type TRILs, protonated betaine bis(trifluoromethyl sulfonyl)imide ([Hbet][Tf2N]) and choline bis(trifluoromethylsulfonyl)imide ([choline][Tf2N]) showed that (1) the specific energy of the TRIL-OHE system could reach as high as 4.0 times that of the seawater and river water system, (2) the power density measured from a commercial FO membrane reached up to 2.3 W/m2, and (3) the overall energy efficiency reached up to 2.6% or 18% of the Carnot efficiency at no heat recovery and up to 10.5% or 71% of the Carnet efficiency at 70% heat recovery. All of these results clearly demonstrated the great potential of using TRILs as novel osmotic agents to design high efficient OHEs for recovery of low grade thermal energy to work or electricity.

Using UCST Ionic Liquid as a Draw Solute in Forward Osmosis to Treat High-Salinity Water.

The concept of using a thermoresponsive ionic liquid (IL) with an upper critical solution temperature (UCST) as a draw solute in forward osmosis (FO) was successfully demonstrated here experimentally. A 3.2 M solution of protonated betaine bis(trifluoromethylsulfonyl)imide ([Hbet][Tf2N]) was obtained by heating and maintaining the temperature above 56 °C. This solution successfully drew water from high-salinity water up to 3.0 M through FO. When the IL solution cooled to room temperature, it spontaneously separated into a water-rich phase and an IL-rich phase: the water-rich phase was the produced water that contained a low IL concentration, and the IL-rich phase could be used directly as the draw solution in the next cycle of the FO process. The thermal stability, thermal-responsive solubility, and UV-vis absorption spectra of the IL were also studied in detail.

Collision-Free Formation Control for Heterogeneous Multiagent Systems Under DoS Attacks.

A safe time-varying formation (TVF) control framework is proposed in this article for heterogeneous multiagent systems under the constraints of denial of service (DoS) attacks, noncooperative dynamic obstacles, and input saturation. The framework integrates both the cyber-layer and physical-layer components to address the challenges posed by these adverse conditions. In the cyber-layer, a distributed resilient observer is provided based on a control Lyapunov function (CLF)-quadratic program (QP). This observer estimates a reference exosystem, effectively decoupling heterogeneous dynamics from unsafe networks and optimizing the system resilience against DoS attacks. At the physical-layer, for the first time, a collision-free TVF controller is presented based on the CLF-exponential control barrier function-QP. The controller guarantees high-order heterogeneous agents' operation safety under noncooperative obstacles and input saturation. The effectiveness and advantages of the proposed algorithms are verified through the comparative simulations and experiments conducted on a physical system comprising unmanned aerial vehicles and unmanned ground vehicles.

Distributed Active Fault-Tolerant Cooperative Control for Multiagent Systems With Communication Delays and External Disturbances.

This article investigates the distributed active fault-tolerant cooperative control problem for leader-follower multiagent systems (MASs) in the presence of multiple faults, communication delays, and external disturbances. A new distributed consensus protocol is put forward to ensure the state consensus of MASs, which can be served as a nominal controller in fault-free cases with communication delays and external disturbances. A novel distributed time-delay intermediate observer, which can estimate system states and multiple faults simultaneously, is derived based on the time-delay closed-loop system equation. By integrating a fault compensation mechanism into the nominal controller, a distributed active fault-tolerant consensus controller is constructed for the follower agents to eliminate the adverse effects of multiple faults. Simulation examples are provided to demonstrate the effectiveness of the proposed method.

A self-cleaning underwater superoleophobic mesh for oil-water separation.

Oil-water separation has recently become a global challenging task because of the frequent occurrence of oil spill accidents due to the offshore oil production and transportation, and there is an increasing demand for the development of effective and inexpensive approaches for the cleaning-up of the oily pollution in water system. In this study, a self-cleaning underwater superoleophobic mesh that can be used for oil-water separation is prepared by the layer-by-layer (LbL) assembly of sodium silicate and TiO2 nanoparticles on the stainless steel mesh. The integration of the self-cleaning property into the all-inorganic separation mesh by using TiO2 enables the convenient removal of the contaminants by ultraviolet (UV) illumination, and allows for the facile recovery of the separation ability of the contaminated mesh, making it promising for practial oil-water separation applications.