Ultrahigh Flux Thin Film Boiling Heat Transfer Through Nanoporous Membranes.

Phase change heat transfer is fundamentally important for thermal energy conversion and management, such as in electronics with power density over 1 kW/cm2. The critical heat flux (CHF) of phase change heat transfer, either evaporation or boiling, is limited by vapor flux from the liquid-vapor interface, known as the upper limit of heat flux. This limit could in theory be greater than 1 kW/cm2 on a planar surface, but its experimental realization has remained elusive. Here, we utilized nanoporous membranes to realize a new "thin film boiling" regime that resulted in an unprecedentedly high CHF of over 1.2 kW/cm2 on a planar surface, which is within a factor of 4 of the theoretical limit, and can be increased to a higher value if mechanical strength of the membranes can be improved (demonstrated with 1.85 kW/cm2 CHF in this work). The liquid supply is achieved through a simple nanoporous membrane that supports the liquid film where its thickness automatically decreases as heat flux increases. The thin film configuration reduces the conductive thermal resistance, leads to high frequency bubble departure, and provides separate liquid-vapor pathways, therefore significantly enhances the heat transfer. Our work provides a new nanostructuring approach to achieve ultrahigh heat flux in phase change heat transfer and will benefit both theoretical understanding and application in thermal management of high power devices of boiling heat transfer.

Ultrafast Diameter-Dependent Water Evaporation from Nanopores.

Evaporation from nanopores plays an important role in various natural and industrial processes that require efficient heat and mass transfer. The ultimate performance of nanopore-evaporation-based processes is dictated by evaporation kinetics at the liquid-vapor interface, which has yet to be experimentally studied down to the single nanopore level. Here we report unambiguous measurements of kinetically limited intense evaporation from individual hydrophilic nanopores with both hydrophilic and hydrophobic top outer surfaces at 22 °C using nanochannel-connected nanopore devices. Our results show that the evaporation fluxes of nanopores with hydrophilic outer surfaces show a strong diameter dependence with an exponent of nearly -1.5, reaching up to 11-fold of the maximum theoretical predication provided by the classical Hertz-Knudsen relation at a pore diameter of 27 nm. Differently, the evaporation fluxes of nanopores with hydrophobic outer surfaces show a different diameter dependence with an exponent of -0.66, achieving 66% of the maximum theoretical predication at a pore diameter of 28 nm. We discover that the ultrafast diameter-dependent evaporation from nanopores with hydrophilic outer surfaces mainly stems from evaporating water thin films outside of the nanopores. In contrast, the diameter-dependent evaporation from nanopores with hydrophobic outer surfaces is governed by evaporation kinetics inside the nanopores, which indicates that the evaporation coefficient varies in different nanoscale confinements, possibly due to surface-charge-induced concentration changes of hydronium ions. This study enhances our understanding of evaporation at the nanoscale and demonstrates great potential of evaporation from nanopores.