Kinetics and thermodynamics of bromophenol blue adsorption by a mesoporous hybrid gel derived from tetraethoxysilane and bis(trimethoxysilyl)hexane.
J Colloid Interface Sci
; 300(2): 526-35, 2006 Aug 15.
Article
en En
| MEDLINE
| ID: mdl-16725150
ABSTRACT
A mesoporous hybrid gel is prepared with tetraethoxysilane (TEOS) and bis(trimethoxysilyl)hexane (TSH) as precursors without using any templating agent. Nitrogen sorption, TG-DTA, FTIR, and point of zero charge (PZC) measurement are used to characterize the gel. The gel has a specific surface area of 695 m(2) g(-1) with a pore size of 3.5 nm, a pore volume of 0.564 cm(3) g(-1), and a point of zero charge (PZC) of 6.2. The kinetics and thermodynamics of bromophenol blue (BPB) adsorption by the gel in aqueous solution are investigated comprehensively. The effects of initial BPB concentration, pH, ionic strength, and temperature on the adsorption are investigated. Kinetic studies show that the kinetic data are well described by the pseudo-second-order kinetic model. Initial adsorption rate increases with the increase in initial BPB concentration and temperature. Adsorption activation energy is found to be 62.5-67.5 kJ mol(-1) depending on the initial BPB concentration. Internal diffusion appears to be the rate-limiting step for the adsorption process. The equilibrium adsorption amount increases with the increase in the initial BPB concentration, solution acidity, and ionic strength, but decreases with the increase in temperature. The thermodynamic analysis indicates that the adsorption is spontaneous and exothermic. The adsorption isotherms can be well described with Freundlich equation indicating the heterogeneity of the hybrid gel surface. Electrostatic and hydrophobic interactions are suggested to be the dominant mechanism for adsorption.
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Bases de datos:
MEDLINE
Asunto principal:
Silanos
/
Azul de Bromofenol
/
Hexanos
Idioma:
En
Revista:
J Colloid Interface Sci
Año:
2006
Tipo del documento:
Article