Designed post-self-assembly structural and functional modifications of a truncated tetrahedron.
J Am Chem Soc
; 133(42): 17045-55, 2011 Oct 26.
Article
en En
| MEDLINE
| ID: mdl-21973048
ABSTRACT
Post-self-assembly modifications of a discrete metal-organic supramolecular structure have been developed. Such modifications allow the properties of the self-assembled supramolecular species to be changed in a simple and efficient manner (>90% yield). Initiated by the application of chemical stimuli, the post-self-assembly modifications described herein result in three distinct changes to the supramolecular system an individual building-block component change, an overall structural modification, and a functional evolution of a [6+4] metal-organic supramolecular structure. The three modifications have been carefully examined by a range of characterization methods, including NMR and UV-vis spectroscopy, electrospray ionization mass spectrometry, pulsed field gradient spin echo NMR measurements, electrochemical analysis, and computational simulations.
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1
Bases de datos:
MEDLINE
Asunto principal:
Compuestos Organometálicos
Idioma:
En
Revista:
J Am Chem Soc
Año:
2011
Tipo del documento:
Article
País de afiliación:
Estados Unidos