Minimization of organocuprate complexity through self-organization: remarkable orientation effect in mixed cuprate π complexes.
Angew Chem Int Ed Engl
; 51(11): 2681-5, 2012 Mar 12.
Article
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| MEDLINE
| ID: mdl-22298492
ABSTRACT
They "know" where to go a powerful orientation effect has been observed in complexes of mixed organocuprates [R(T)R(NT)CuLi] and substrates with C-C, C-N, and C-S double bonds (see scheme; Th=thienyl). The preferred geometry of the intermediate complex sets up the facile addition of R(T) to the double bond, rather than addition of the "dummy ligand", R(NT) .
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Bases de datos:
MEDLINE
Tipo de estudio:
Clinical_trials
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2012
Tipo del documento:
Article
País de afiliación:
Estados Unidos