Facile activation of H-H and Si-H bonds by boranes.
J Am Chem Soc
; 134(12): 5488-91, 2012 Mar 28.
Article
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| MEDLINE
| ID: mdl-22394364
ABSTRACT
The borane B(C(6)F(5))(3) is a precatalyst for H/Dexchange between H(2) and deuterium-labeled silanes (D(3)SiPh, D(2)SiMePh, DSiMe(2)Ph, DSiEt(3)). Experimental and DFT studies reveal that B(C(6)F(5))(3) itself cannot activate dihydrogen but converts to HB(C(6)F(5))(2) under the action of hydrosilane. The latter species easily activates H-H and Si-H bonds by a σ-bond metathesis mechanism, which was further confirmed by the reactions of BD(3)·THF with H(2).
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MEDLINE
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J Am Chem Soc
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2012
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Article
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Canadá