[White light upconversion luminescence and its mechanism of Yb3+/Ho3+/Tm3+ co-doped tellurite glass].

ABSTRACT

Yb3+ /Ho3+, Yb3+ /Tm3+ and Yb3+ /Ho3+ /Tm3+ co-doped tellurite glasses were prepared by melt-quenching method. Under the excitation of 980 nm laser, Yb3+ /Ho3+/Tm3+ co-doped glass sample shows strong blue, green and red emissions, corresponding to the transitions 1G4 --> 3H6 of Tm3+, 5F4 (5S2) --> 5 I8 of Ho3+, as well as 5F5 -->5 I8 of Ho3+ and 1G4 --> 3F4 of Tm3+ ions, respectively. It was found that the integrated emission intensity ratio of the red to green in Yb3+/Ho3+ /Tm3+ co-doped sample (3.95) is greater than that in Yb3+/Ho3+ co-doped sample (1.69) due to the cross-relaxation between Ho3+ and Tm3+ ions 3H4 (Tm3+) + 5 I6 (Ho3+) -->3F4 (Tm3+) + 5F5 (Ho3+), and 3F4 (Tm3+ ) + 5 I8 (Ho3+) --> 3H6 (Tm3+) +5 I7 (Ho3+). When the pump power density is 8.2 W x cm(-2), the calculated color coordinates of Yb3+ /Ho3+ /Tm3+ co-doped sample are x = 0.345, y = 0.338, which is very close to the equal energy white light (x = 0.333, y = 0.333).