The fluoride-free transmetalation of organosilanes to gold.
Chemistry
; 18(47): 14923-8, 2012 Nov 19.
Article
en En
| MEDLINE
| ID: mdl-23065969
ABSTRACT
Golden transfer The versatile gold(I) complex [Au(IPr)(OH)] permits very straightforward access to a series of aryl-, vinyl- and alkylgold silanolates by reaction with the appropriate silane reagent. These silanolate compounds are key intermediates in a fluoride-free process that results in the net transmetalation of organosilanes to gold.
Texto completo:
1
Bases de datos:
MEDLINE
Asunto principal:
Silanos
/
Compuestos Orgánicos de Oro
/
Oro
Idioma:
En
Revista:
Chemistry
Asunto de la revista:
QUIMICA
Año:
2012
Tipo del documento:
Article
País de afiliación:
Reino Unido