Effect of PEDOT Nanofibril Networks on the Conductivity, Flexibility, and Coatability of PEDOT:PSS Films.
ACS Appl Mater Interfaces
; 6(9): 6954-61, 2014 May 14.
Article
en En
| MEDLINE
| ID: mdl-24713072
ABSTRACT
The use of poly(3,4-ethylenedioxythiophene)poly(styrenesulfonate) (PEDOTPSS) in electrodes and electrical circuits presents a number of challenges that are yet to be overcome, foremost amongst which are its relatively low conductivity, low coatability on hydrophobic substrates, and decreased conductivity at large strains. With this in mind, this study suggests a simple way to simultaneously address all of these issues through the addition of a small amount of a nonionic surfactant (Triton X-100) to commercial PEDOTPSS solutions. This surfactant is shown to considerably reduce the surface tension of the PEDOTPSS solution, thus permitting conformal coatings of PEDOTPSS thin film on a diverse range of hydrophobic substrates. Furthermore, this surfactant induces the formation of PEDOT nanofibrils during coating, which led to the high conductivity values and mechanical stability at large strains (ε=10.3%). Taking advantage of the superior characteristics of these PEDOTPSS thin films, a highly flexible polymer solar cell was fabricated. The power conversion efficiency of this solar cell (3.14% at zero strain) was preserved at large strains (ε=7.0%).
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Bases de datos:
MEDLINE
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En
Revista:
ACS Appl Mater Interfaces
Asunto de la revista:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Año:
2014
Tipo del documento:
Article