Thermoresponsive Polyphosphazene-Based Molecular Brushes by Living Cationic Polymerization.

ABSTRACT

A series of polyphosphazenes with molecular brush type structures have been prepared with controlled molecular weights and narrow polydispersities. The polymers show lower critical solution temperatures (LCST) between 18 and 90 °C, which can be easily tailored by choice of side-substituent to suit the required application. A temperature triggered self-assembly is observed to give stable colloidal aggregates with dimensions in the region of 100-300 nm.