THz-Pulse-Induced Selective Catalytic CO Oxidation on Ru.
Phys Rev Lett
; 115(3): 036103, 2015 Jul 17.
Article
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| MEDLINE
| ID: mdl-26230806
ABSTRACT
We demonstrate the use of intense, quasi-half-cycle THz pulses, with an associated electric field component comparable to intramolecular electric fields, to direct the reaction coordinate of a chemical reaction by stimulating the nuclear motions of the reactants. Using a strong electric field from a THz pulse generated via coherent transition radiation from an ultrashort electron bunch, we present evidence that CO oxidation on Ru(0001) is selectively induced, while not promoting the thermally induced CO desorption process. The reaction is initiated by the motion of the O atoms on the surface driven by the electric field component of the THz pulse, rather than thermal heating of the surface.
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Bases de datos:
MEDLINE
Idioma:
En
Revista:
Phys Rev Lett
Año:
2015
Tipo del documento:
Article
País de afiliación:
Estados Unidos