Photo-activation of d(0) niobium imido azides: en route to nitrido complexes.
Chem Commun (Camb)
; 52(32): 5538-41, 2016 Apr 25.
Article
en En
| MEDLINE
| ID: mdl-27033145
ABSTRACT
We report the synthesis and photo-reactivity of d(0) niobium imido azido complexes supported by ß-diketiminate ligands, which leads to the unprecedented formation of nitrides through a photo-assisted intramolecular rearrangement. This provides a new entry to metal nitrides that does not require low-valent metal centers and is a rare example in which the metal-imido moiety in group 5 complexes participates in reactivity.
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Bases de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2016
Tipo del documento:
Article
País de afiliación:
Francia