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Hydrogen isotope exchange with highly active iridium(I) NHC/phosphine complexes: a comparative counterion study.
Kerr, William J; Mudd, Richard J; Owens, Philippa K; Reid, Marc; Brown, Jack A; Campos, Sebastien.
Afiliación
  • Kerr WJ; Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, Glasgow, Scotland, UK.
  • Mudd RJ; Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, Glasgow, Scotland, UK.
  • Owens PK; Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, Glasgow, Scotland, UK.
  • Reid M; Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, Glasgow, Scotland, UK.
  • Brown JA; GlaxoSmithKline R&D, Medicines Research Centre, Stevenage, England, UK.
  • Campos S; GlaxoSmithKline R&D, Medicines Research Centre, Stevenage, England, UK.
J Labelled Comp Radiopharm ; 59(14): 601-603, 2016 12.
Article en En | MEDLINE | ID: mdl-27460856
ABSTRACT
Herein, we present a range of substrates that undergo hydrogen isotope exchange with an iridium(I) N-heterocyclic carbene/phosphine complex bearing the less coordinating tetrakis[3,5-bis(trifluoromethyl)phenyl]borate counterion and compare these with labelling using the equivalent, more established hexafluorophosphate complex. The changes in reactivity and selectivity of these complexes in a series of solvents are examined. Copyright © 2016 John Wiley & Sons, Ltd.
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Texto completo: 1 Bases de datos: MEDLINE Asunto principal: Compuestos Organometálicos / Fosfinas / Tritio / Deuterio / Iridio Idioma: En Revista: J Labelled Comp Radiopharm Año: 2016 Tipo del documento: Article País de afiliación: Reino Unido
Texto completo
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XML
PubMed Links
Buscar en Google

Texto completo: 1 Bases de datos: MEDLINE Asunto principal: Compuestos Organometálicos / Fosfinas / Tritio / Deuterio / Iridio Idioma: En Revista: J Labelled Comp Radiopharm Año: 2016 Tipo del documento: Article País de afiliación: Reino Unido