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Functional Mononitrosyl Diiron(II) Complex Mediates the Reduction of NO to N2O with Relevance for Flavodiiron NO Reductases.
Jana, Manish; Pal, Nabhendu; White, Corey J; Kupper, Claudia; Meyer, Franc; Lehnert, Nicolai; Majumdar, Amit.
Afiliación
  • Jana M; Department of Inorganic Chemistry, Indian Association for the Cultivation of Science , 2A & 2B Raja S. C. Mullick Road, Jadavpur, Kolkata 700032, West Bengal, India.
  • Pal N; Department of Inorganic Chemistry, Indian Association for the Cultivation of Science , 2A & 2B Raja S. C. Mullick Road, Jadavpur, Kolkata 700032, West Bengal, India.
  • White CJ; Department of Chemistry, The University of Michigan , 930 N. University Ave., Ann Arbor, Michigan 48109, United States.
  • Kupper C; Institute of Inorganic Chemistry, University of Goettingen , Tammannstraße 4, 37077 Göttingen, Germany.
  • Meyer F; Institute of Inorganic Chemistry, University of Goettingen , Tammannstraße 4, 37077 Göttingen, Germany.
  • Lehnert N; Department of Chemistry, The University of Michigan , 930 N. University Ave., Ann Arbor, Michigan 48109, United States.
  • Majumdar A; Department of Inorganic Chemistry, Indian Association for the Cultivation of Science , 2A & 2B Raja S. C. Mullick Road, Jadavpur, Kolkata 700032, West Bengal, India.
J Am Chem Soc ; 139(41): 14380-14383, 2017 10 18.
Article en En | MEDLINE | ID: mdl-28953388
ABSTRACT
Reaction of [Fe2(N-Et-HPTB)(CH3COS)](BF4)2 (1) with (NO)(BF4) produces a nonheme mononitrosyl diiron(II) complex, [Fe2(N-Et-HPTB)(NO)(DMF)3](BF4)3 (2). Complex 2 is the first example of a [FeII{Fe(NO)}7] species and is also the first example of a mononitrosyl diiron(II) complex that mediates the reduction of NO to N2O. This work describes the selective synthesis, detailed characterization and NO reduction activity of 2 and thus provides new insights regarding the mechanism of flavodiiron nitric oxide reductases.
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Texto completo: 1 Bases de datos: MEDLINE Asunto principal: Oxidorreductasas / Óxido Nítrico / Óxido Nitroso Idioma: En Revista: J Am Chem Soc Año: 2017 Tipo del documento: Article País de afiliación: India
Texto completo
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Texto completo: 1 Bases de datos: MEDLINE Asunto principal: Oxidorreductasas / Óxido Nítrico / Óxido Nitroso Idioma: En Revista: J Am Chem Soc Año: 2017 Tipo del documento: Article País de afiliación: India