Distinctive Three-Step Hysteretic Sorption of Ethane with In Situ Crystallographic Visualization of the Pore Forms in a Soft Porous Crystal.
J Am Chem Soc
; 140(6): 2145-2150, 2018 02 14.
Article
en En
| MEDLINE
| ID: mdl-29195271
ABSTRACT
A soft porous Zn(II)-MOF (1) displays distinctive three-step hysteretic breathing behavior under ethane gas pressure at ambient temperatures. In situ single-crystal X-ray diffraction analysis was carried out at 298 K using an environmental gas cell in order to elucidate the different porous forms of the breathing framework under ethane gas. The three different phases were further characterized by pressure-gradient differential scanning calorimetry and variable pressure powder X-ray diffraction analysis.
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Bases de datos:
MEDLINE
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En
Revista:
J Am Chem Soc
Año:
2018
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Article
País de afiliación:
Sudáfrica