Regio- and stereoselective C-H functionalization of brassinosteroids.
Steroids
; 146: 92-98, 2019 06.
Article
en En
| MEDLINE
| ID: mdl-30951761
ABSTRACT
Late stage CH functionalization is a powerful tool for modification of natural compounds. Herein we report that the rhodium-catalyzed reaction of brassinosteroids with aryloxysulfonamides proceeds regio- and stereoselectively at C15 position. The derivative obtained from 24-epibrassinolide was easily transformed to the conjugate with a BODIPY dye bearing unaffected functional groups of the native brassinosteroid.
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Bases de datos:
MEDLINE
Asunto principal:
Brasinoesteroides
Idioma:
En
Revista:
Steroids
Año:
2019
Tipo del documento:
Article