Crystal structure of 4,5,6,7,8,8-hexa-chloro-2-(3,4-di-meth-oxy-pheneth-yl)-3a,4,7,7a-tetra-hydro-1H-4,7-methano-iso-indole-1,3(2H)-dione [+solvent].
Acta Crystallogr E Crystallogr Commun
; 75(Pt 5): 562-564, 2019 May 01.
Article
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| ID: mdl-31110786
ABSTRACT
In the title compound, C19H15Cl6NO4 [+solvent], the six-membered ring of the norbornene moiety adopts a boat conformation and the two five-membered rings have envelope conformations. The pyrrolidine ring makes a dihedral angle of 14.83â
(12)° with the 3,4-di-meth-oxy-phenyl ring, which are attached to each other by an extended N-CH2-CH2-Car bridge. In the crystal, the structure features C-Hâ¯O inter-molecular hydrogen bonds, an offset π-π inter-action [inter-centroid distance = 3.564â
(1)â
Å] and a C-Clâ¯π inter-action. The contribution of some disordered solvent to the scattering was removed using the SQUEEZE routine [Spek (2015 â¸). Acta Cryst. C71, 9-18] of PLATON. The solvent contribution was not included in the reported mol-ecular weight and density.
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MEDLINE
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En
Revista:
Acta Crystallogr E Crystallogr Commun
Año:
2019
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Article
País de afiliación:
India