A Black Phosphorus-Graphite Composite Anode for Li-/Na-/K-Ion Batteries.
Angew Chem Int Ed Engl
; 59(6): 2318-2322, 2020 Feb 03.
Article
en En
| MEDLINE
| ID: mdl-31750970
ABSTRACT
Black phosphorus (BP) is a desirable anode material for alkali metal ion storage owing to its high electronic/ionic conductivity and theoretical capacity. In-depth understanding of the redox reactions between BP and the alkali metal ions is key to reveal the potential and limitations of BP, and thus to guide the design of BP-based composites for high-performance alkali metal ion batteries. Comparative studies of the electrochemical reactions of Li+ , Na+ , and K+ with BP were performed. Exâ
situ X-ray absorption near-edge spectroscopy combined with theoretical calculation reveal the lowest utilization of BP for K+ storage than for Na+ and Li+ , which is ascribed to the highest formation energy and the lowest ion diffusion coefficient of the final potassiation product K3 P, compared with Li3 P and Na3 P. As a result, restricting the formation of K3 P by limiting the discharge voltage achieves a gravimetric capacity of 1300â
mAh g-1 which retains at 600â
mAh g-1 after 50 cycles at 0.25â
A g-1 .
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MEDLINE
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En
Revista:
Angew Chem Int Ed Engl
Año:
2020
Tipo del documento:
Article
País de afiliación:
China