A Smart Route for Encapsulating Pd Nanoparticles into a ZIF-8 Hollow Microsphere and Their Superior Catalytic Properties.
Langmuir
; 36(8): 2037-2043, 2020 Mar 03.
Article
en En
| MEDLINE
| ID: mdl-32036667
ABSTRACT
The encapsulation of catalytically active noble metal nanoparticles (NM NPs) into metal-organic frameworks (MOFs) represents an effective strategy for enhancing their catalytic performance. Despite a myriad of reports on the nanocomposites consisting of NM NPs and MOFs, it remains challenging to develop a sustainable and convenient method for realizing confined integration of NM NPs within a porous and hollow zinc-based MOF. Herein, a simple and well-designed approach is reported to the fabrication of Pd@ZIF-8 hollow microspheres with a number of Pd nanoparticles immobilized on the inner surface. This method capitalized on the use of polyvinylpyrrolidone (PVP)-stabilized polystyrene (PS) microspheres as templates, to harness the dual functions of PVP for reducing PdCl2 to generate Pd NPs and coordinating with zinc ions to grow ZIF-8 shells. Consequently, it avoids the complicated protocols involving surface treatment of template microspheres that conventionally adopts hazardous or costly agents. The obtained Pd@ZIF-8 hollow microspheres exhibit outstanding catalytic activity, size selectivity, and stability in the hydrogenation of alkenes. This study presents both the advances in the green synthesis and great potential of Pd@ZIF-8 hollow microspheres for catalytic applications.
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Bases de datos:
MEDLINE
Tipo de estudio:
Guideline
Idioma:
En
Revista:
Langmuir
Asunto de la revista:
QUIMICA
Año:
2020
Tipo del documento:
Article
País de afiliación:
China