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Effect of Multiplicity Fluctuation in Cobalt Ions on Crystal Structure, Magnetic and Electrical Properties of NdCoO3 and SmCoO3.
Dudnikov, Vyacheslav A; Orlov, Yuri S; Solovyov, Leonid A; Vereshchagin, Sergey N; Gavrilkin, Sergey Yu; Tsvetkov, Alexey Yu; Velikanov, Dmitriy A; Gorev, Michael V; Novikov, Sergey V; Ovchinnikov, Sergey G.
Afiliación
  • Dudnikov VA; Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia.
  • Orlov YS; Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia.
  • Solovyov LA; Institute of Engineering Physics and Radio Electronics, Siberian Federal University, 660041 Krasnoyarsk, Russia.
  • Vereshchagin SN; Institute of Chemistry and Chemical Technology, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia.
  • Gavrilkin SY; Institute of Chemistry and Chemical Technology, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia.
  • Tsvetkov AY; Lebedev Physical Institute of the Russian Academy of Sciences, 119991, Moscow, Russia.
  • Velikanov DA; Lebedev Physical Institute of the Russian Academy of Sciences, 119991, Moscow, Russia.
  • Gorev MV; Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia.
  • Novikov SV; Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia.
  • Ovchinnikov SG; Institute of Engineering Physics and Radio Electronics, Siberian Federal University, 660041 Krasnoyarsk, Russia.
Molecules ; 25(6)2020 Mar 12.
Article en En | MEDLINE | ID: mdl-32178469
ABSTRACT
The structural, magnetic, electrical, and dilatation properties of the rare-earth NdCoO3 and SmCoO3 cobaltites were investigated. Their comparative analysis was carried out and the effect of multiplicity fluctuations on physical properties of the studied cobaltites was considered. Correlations between the spin state change of cobalt ions and the temperature dependence anomalies of the lattice parameters, magnetic susceptibility, volume thermal expansion coefficient, and electrical resistance have been revealed. A comparison of the results with well-studied GdCoO3 allows one to single out both the general tendencies inherent in all rare-earth cobaltites taking into account the lanthanide contraction and peculiar properties of the samples containing Nd and Sm.
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Texto completo: 1 Bases de datos: MEDLINE Asunto principal: Óxidos / Samario / Estructura Molecular / Cobalto / Neodimio Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2020 Tipo del documento: Article País de afiliación: Rusia

Texto completo: 1 Bases de datos: MEDLINE Asunto principal: Óxidos / Samario / Estructura Molecular / Cobalto / Neodimio Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2020 Tipo del documento: Article País de afiliación: Rusia