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A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands.
Ohki, Yasuhiro; Ishihara, Kodai; Yaoi, Moeko; Tada, Mizuki; Sameera, W M C; Cramer, Roger E.
Afiliación
  • Ohki Y; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan. ohki@chem.nagoya-u.ac.jp.
  • Ishihara K; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan. ohki@chem.nagoya-u.ac.jp.
  • Yaoi M; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan. ohki@chem.nagoya-u.ac.jp.
  • Tada M; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan. ohki@chem.nagoya-u.ac.jp and Integrated Research Consortium on Chemical Sciences (IRCCS), Nagoya University, Japan.
  • Sameera WMC; Institute of Low Temperature Science, Hokkaido University, Sapporo, Japan.
  • Cramer RE; Department of Chemistry, University of Hawaii, Manoa, 2545 McCarthy Mall, Honolulu, Hawaii 96822-2275, USA.
Chem Commun (Camb) ; 56(58): 8035-8038, 2020 Jul 21.
Article en En | MEDLINE | ID: mdl-32691780
ABSTRACT
Hydride-bridged transition metal complexes have been found to serve as suitable precursors for the activation of small molecules without the use of reducing agents. In this study, we synthesized a dinuclear Mo2H8 complex supported by bulky C5H2tBu3 (Cp‡) ligands, Cp‡2Mo2H8 (1), from the reaction of Cp‡MoCl4 with KC8 under H2. The hydrides of complex 1 can be replaced with benzene at 60 °C to afford a µ-benzene complex Cp‡2Mo2H2(µ-C6H6) (2).
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Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Japón
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Japón