Electrochemical Hydroboration of Alkynes.
Chemistry
; 27(32): 8277-8282, 2021 Jun 04.
Article
en En
| MEDLINE
| ID: mdl-33945175
Herein we reported the electrochemical hydroboration of alkynes by using B2 Pin2 as the boron source. This unprecedented reaction manifold was applied to a broad range of alkynes, giving the hydroboration products in good to excellent yields without the need of a metal catalyst or a hydride source. This transformation relied on the possible electrochemical oxidation of an inâ
situ formed borate. This anodic oxidation performed in an undivided cell allowed the formation of a putative boryl radical, which reacted on the alkyne.
Texto completo:
1
Bases de datos:
MEDLINE
Idioma:
En
Revista:
Chemistry
Asunto de la revista:
QUIMICA
Año:
2021
Tipo del documento:
Article
País de afiliación:
Francia