Direct Experimental Characterization of a Bridged Bicyclic Glycosyl Dioxacarbenium Ion by <sup>1</sup> H and <sup>13</sup> CâNMR Spectroscopy: Importance of Conformation on Participation by Distal Esters.

Upadhyaya, Kapil; Subedi, Yagya P; Crich, David

Direct Experimental Characterization of a Bridged Bicyclic Glycosyl Dioxacarbenium Ion by ¹ H and ¹³ CâNMR Spectroscopy: Importance of Conformation on Participation by Distal Esters.

Upadhyaya, Kapil; Subedi, Yagya P; Crich, David.

Afiliación

Upadhyaya K; Department of Pharmaceutical and Biomedical Sciences, University of Georgia, 250 West Green Street, Athens, GA, 30602, USA.
Subedi YP; Department of Pharmaceutical and Biomedical Sciences, University of Georgia, 250 West Green Street, Athens, GA, 30602, USA.
Crich D; Department of Pharmaceutical and Biomedical Sciences, University of Georgia, 250 West Green Street, Athens, GA, 30602, USA.

Angew Chem Int Ed Engl ; 60(48): 25397-25403, 2021 11 22.

Article en En | MEDLINE | ID: mdl-34543505

Asunto(s)

Compuestos Bicíclicos Heterocíclicos con Puentes/química; Ésteres/química; Glicósidos/química; Conformación de Carbohidratos; Espectroscopía de Resonancia Magnética con Carbono-13; Glicosilación; Iones/química; Espectroscopía de Protones por Resonancia Magnética; Estereoisomerismo

Palabras clave

dioxacarbenium ion; distal group participation; glycosylation; variable-temperature NMR

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Texto completo: 1 Bases de datos: MEDLINE Asunto principal: Compuestos Bicíclicos Heterocíclicos con Puentes / Ésteres / Glicósidos Tipo de estudio: Prognostic_studies Idioma: En Revista: Angew Chem Int Ed Engl Año: 2021 Tipo del documento: Article País de afiliación: Estados Unidos

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