Optimized preparation of spruce kraft lignin/ZnO composites and their performance analysis in polyurethane films.

ABSTRACT

Spruce kraft lignin (SKL) has received considerable attention in recent years for its application in the field of polymer materials. However, its structural complexity and polydispersity pose significant challenges for commercial applications. In this study, molecular structure models of acetone soluble kraft lignin (ASKL) and acetone insoluble kraft lignin (AIKL) were proposed based on quantitative calculations of the connection mode of functional groups and structural units. The lignin was modified by quaternization and synthesized in situ as lignin/ZnO composites. Based on the detailed characterization of the micromorphology and structure of the composites, waterborne polyurethane (WPU) films were optimally prepared using 0.6 wt% of the composites. The results showed that the composite films prepared from ASKL have the best UV-blocking performance and mechanical properties. The highest UVA and UVB blocking rates were 98% and 100%, respectively, and the highest tensile strength and elongation at break were 31.2 MPa and 732%, respectively. The differences in the structure and functional groups of the different types of SKL were accurately identified. ASKL is advantageous for the development of UV-blocking films because of its low molecular weight and the presence of abundant phenolic hydroxyl groups, which facilitate the formation of hydrogen bonds, improve the compatibility, and ensure uniform dispersibility. The results of this study are of practical importance in the field of nano-functional materials for the high-value application of industrial lignin.