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Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction.
Kamada, Kenji; Jung, Jieun; Kametani, Yohei; Wakabayashi, Taku; Shiota, Yoshihito; Yoshizawa, Kazunari; Bae, Seong Hee; Muraki, Manami; Naruto, Masayuki; Sekizawa, Keita; Sato, Shunsuke; Morikawa, Takeshi; Saito, Susumu.
Afiliación
  • Kamada K; Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. jieun@chem.nagoya-u.ac.jp.
  • Jung J; Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. jieun@chem.nagoya-u.ac.jp.
  • Kametani Y; Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, Japan.
  • Wakabayashi T; Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. jieun@chem.nagoya-u.ac.jp.
  • Shiota Y; Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, Japan.
  • Yoshizawa K; Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, Japan.
  • Bae SH; Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. jieun@chem.nagoya-u.ac.jp.
  • Muraki M; Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. jieun@chem.nagoya-u.ac.jp.
  • Naruto M; Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. jieun@chem.nagoya-u.ac.jp.
  • Sekizawa K; Toyota Central R&D Laboratories, Inc., Nagakute 480-1192, Japan.
  • Sato S; Toyota Central R&D Laboratories, Inc., Nagakute 480-1192, Japan.
  • Morikawa T; Toyota Central R&D Laboratories, Inc., Nagakute 480-1192, Japan.
  • Saito S; Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. jieun@chem.nagoya-u.ac.jp.
Chem Commun (Camb) ; 58(66): 9218-9221, 2022 Aug 16.
Article en En | MEDLINE | ID: mdl-35899606
ABSTRACT
A series of Ir complexes has been developed as multifunctional photocatalysts for CO2 reduction to give HCO2H selectively. The catalytic activities and photophysical properties vary widely across the series, and the bulky group insertion resulted in the formation of HCO2H and CO with the catalyst turnover number of >10 400.

Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Japón

Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Japón