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A Highly Conductive n-Type Coordination Complex with Thieno[3,2-b]thiophene Units: Facile Synthesis, Orientation, and Thermoelectric Properties.
Ueda, Kazuki; Fukuzaki, Riku; Ito, Takumu; Toyama, Nana; Muraoka, Masahiro; Terao, Toshiki; Manabe, Kei; Hirai, Tomoyasu; Wu, Ching-Ju; Chuang, Shih-Ching; Kawano, Shintaro; Murata, Michihisa.
Afiliación
  • Ueda K; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan.
  • Fukuzaki R; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan.
  • Ito T; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan.
  • Toyama N; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan.
  • Muraoka M; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan.
  • Terao T; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan.
  • Manabe K; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan.
  • Hirai T; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan.
  • Wu CJ; Department of Applied Chemistry, National Yang Ming Chiao Tung University, 30010 Hsinchu, Taiwan.
  • Chuang SC; Department of Applied Chemistry, National Yang Ming Chiao Tung University, 30010 Hsinchu, Taiwan.
  • Kawano S; Osaka Research Institute of Industrial Science and Technology, 1-6-50 Morinomiya, Joto-ku, Osaka 536-8553, Japan.
  • Murata M; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan.
J Am Chem Soc ; 144(41): 18744-18749, 2022 Oct 19.
Article en En | MEDLINE | ID: mdl-36166343
ABSTRACT
An organometallic nickel complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and polyvinylidene difluoride, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm-1). Moreover, the thermoelectric power factor of the n-type composite film was proven to be air stable. A grazing-incidence wide-angle X-ray diffraction analysis indicated a significant impact of introducing the thieno[3,2-b]thiophene core into the backbone of the nickel complex on the orientation within the composite films.
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Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2022 Tipo del documento: Article País de afiliación: Japón
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Bases de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2022 Tipo del documento: Article País de afiliación: Japón