Hydration-Facilitated Coordination Tuning of Metal-Organic Frameworks toward Water-Responsive Fluorescence and Proton Conduction.
Inorg Chem
; 61(46): 18789-18794, 2022 Nov 21.
Article
en En
| MEDLINE
| ID: mdl-36350982
ABSTRACT
Developing smart stimuli-responsive metal-organic frameworks (MOFs) with diversified induced readable signals is highly desirable; however, reported multimode responsive MOFs are always achieved under strong environmental stimulations, making it difficult to keep MOF structures stable for practical applications. Herein, we reported a hydration-facilitated coordination tuning strategy to achieve the dual-mode water response in fluorescence and proton conduction from a single MOF. The designed MOF permitted reversible single-crystal transformation via the controllable hydration effect on metal nodes. The change in coordination modes leads to the regulation on conformations of optical ligands, contributing to the switch of fluorescence emissions. Moreover, the hydration effect adds additional hydrogen-bond sites in channels and optimizes hydrogen-bond networks, abruptly enhancing the proton conductivity by â¼20 times. These results pave new avenues for the exploitation of smart MOFs with multimode responsive behavior for on-demand sensing/detection applications.
Texto completo:
1
Bases de datos:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Año:
2022
Tipo del documento:
Article
País de afiliación:
China