Effects of incineration and pyrolysis on removal of organics and liberation of cathode active materials derived from spent ternary lithium-ion batteries.
Waste Manag
; 169: 342-350, 2023 Sep 01.
Article
en En
| MEDLINE
| ID: mdl-37517305
ABSTRACT
Removing organics via thermal treatment to liberate active materials from spent cathode sheets is essential for recovering lithium-ion batteries. In this study, the effects of incineration, N2 pyrolysis, and CO2 pyrolysis on the removal of organics and liberation of ternary cathode active materials (CAMs) were compared. The results indicated that the organics in the spent ternary cathode sheets comprised a residual electrolyte and polyvinylidene fluoride (PVDF) binder. Moreover, the organics could be removed to promote the liberation of CAMs via incineration, N2 pyrolysis, and CO2 pyrolysis. When the temperature was <200 °C, the chemical properties of the volatilized ester electrolyte remained unchanged during both N2 and CO2 pyrolysis, indicating that the electrolyte can be collected by controlling the pyrolysis temperature and condensation. Furthermore, PVDF binder decomposition occurred at 200-600 °C. The optimal temperatures of incineration, N2 pyrolysis, and CO2 pyrolysis were 550, 500, and 450 °C, respectively, and these treatments increased the liberation efficiency of CAMs from 81.49 % to 98.75 %, 99.26 %, and 97.98 %, respectively. In addition, heat-treated CAMs required less time to achieve adequate liberation. Following three thermal treatment processes, the sizes of the CAM particles were mainly concentrated in the ranges of 0.075-0.1 mm and <0.075 mm. Furthermore, for all types of CAMs examined, the Al concentration decreased from 1.09 % to <0.35 %, which increased the separation efficiency and improved the chemical metallurgical performance.
Palabras clave
Texto completo:
1
Bases de datos:
MEDLINE
Asunto principal:
Pirólisis
/
Litio
Idioma:
En
Revista:
Waste Manag
Asunto de la revista:
SAUDE AMBIENTAL
/
TOXICOLOGIA
Año:
2023
Tipo del documento:
Article
País de afiliación:
China