Chiral Deep Eutectic Solvents Enable Full-Color and White Circularly Polarized Luminescence from Achiral Luminophores.

ABSTRACT

Herein, chiral deep eutectic solvents (DES) are prepared by lauric acid as hydrogen bond donors (HBD) and chiral menthol as hydrogen bond acceptors (HBA). When achiral fluorescent molecules are dopedin the menthol-based chiral DES, they emit circularly polarized luminescence (CPL) with handedness controlled by the molecular chirality (l or d) of menthol. Remarkably, the strategy is universal and a series of achiral fluorescent molecules can be endowed with CPL activity, showing a full-color and white CPL upon appropriate mixing, which paves the way to prepare white CPL materials. Interestingly, CPL appears only in a certain temperature range in the DES. Variable-temperature spectra and other characterization methods reveal that the H-bond network in the chiral DES plays an important role in inducing CPL. This work unveils how the interior structure as well as the hydrogen-bond network of a chiral DES can transfer its chirality to achiral luminophores for the first time and realizes a full-color and white CPL in a DES.